File name: Pandora67s1_Cologne_20200715_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T092357.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200715_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200715T050026.9Z 7501.208644 208 1 9.72 2 79.17 69.21 45.31 135.19 0.00 1 0.00 1 0 17 5.548e-01 1.868e-02 3.411e-01 1.198e-02 7.423230e-01 6.600042e-03 9.396018e-03 -6.000000e+00 3.271051e-01 233.85 -2.00 3.80 -2.00 321.08 0.00e+00 6.860636e-03 3.009585e-03 4.357335e-03 -6.000000e+00 1.436025e-02 283.51 -2.00 20.00 -2.00 320.50 0.00e+00 5.123 0.003 302.00 328.00 3 3.0402e+00 2.1845e-02 6.9090e-02 -6.0000e+00 8.2432e-01 3.9158e-01 2.8749e-02 4.7460e-02 -6.0000e+00 8.9016e-01 -3.9789e-01 2.7120e-02 2.6887e-02 -6.0000e+00 5.2825e-01 1.4663e-01 1.3065e-02 9.9828e-03 -6.0000e+00 2.2194e-01 6.3035e-05 1.5906e-04 3.2730e-04 1.6056e-04 -6.0000e+00 1.5464e-02 6.3961e-03 2.3111e-04 12 9 9 12 1 1 0.20 21.28 0.29 0.00640 0.00759 4 6 1 5 0 1909.440 25.47 19.99 21.28 20.20 25.4 979.84 -176988 290490 -166045 22015 -142053 -123177 -222160 -183369 -109100 26553 -95221 -126773 900000 900000 -51452 196885 8201 -62330 -25336 -30068 28964 140209 -42705 -58511 -10426 -55303 16507 5107 83333 -40360 -41174 -36281 -27812 41918 23195 -32238 -32545 -16147 116671 6154 -1446 13038 -6149 6107 -8468 -37654 19223 -2036 22272 25096 6074 13194 21368 6030 20143 5086 10995 4438 8921 15572 5996 5036 13464 8933 4952 6371 1797 8170 1390 9219 11036 476 -1641 1338 -673 2416 -11489 -6077 -3951 -1712 602 -330 -2368 -3871 -3838 -1216 1060 -620 2560 -375 64 581 1017 -1438 709 -2645 -397 142 -626 -1879 534 -1583 -417 -2361 -1069 -1675 -360 -1017 326 931 -102 422 67 -116 -1261 876 -287 417 96 3 1448 1372 189 1990 518 -868 1039 1197 234 -725 429 190 -867 235 520 -460 -127 1255 -322 -97 328 -796 -1307 -3068 3394 -3223 257 -1904 -1439 -6674 -4112 -1317 310 -1131 -2370 900000 900000 -992 2300 122 -2017 -622 -795 442 1638 -1325 -2264 -264 -2245 343 115 974 -1569 -1987 -1962 -1609 1353 845 -1968 -2208 -1083 2679 475 -132 1120 -664 599 -977 -5884 1807 -243 2241 2653 858 1908 3162 1116 3423 1020 2156 904 1705 2743 1207 1114 3131 2427 1474 1838 546 2430 479 3374 4368 214 -740 556 -258 818 -4206 -2163 -1540 -768 305 -191 -1518 -2667 -2788 -916 813 -489 1986 -288 46 396 671 -995 534 -2338 -396 158 -748 -2267 608 -1690 -408 -2307 -1102 -1806 -406 -1215 417 1299 -156 680 110 -185 -1957 1294 -432 644 155 4 2356 2169 295 2965 748 -1246 1443 1711 373 -1270 803 377 -1797 505 1166 -1085 -302 2990 -778 -226 732 -1712 -2745 SS 20200715T050627.4Z 7501.212817 211 1 48.81 2 78.29 70.31 44.65 136.99 0.00 1 0.00 1 0 25 4.316e-01 7.090e-03 9.038e-02 2.126e-03 7.141703e-01 1.161536e-03 8.658040e-03 -6.000000e+00 2.541175e-01 233.85 -2.00 3.80 -2.00 320.94 0.00e+00 3.317730e-03 5.181215e-04 8.455459e-04 -6.000000e+00 1.099964e-02 283.51 -2.00 20.00 -2.00 320.36 0.00e+00 4.766 0.002 302.00 328.00 3 2.0393e+00 3.7779e-03 6.3695e-02 -6.0000e+00 6.4053e-01 1.1472e-01 5.0987e-03 4.2343e-02 -6.0000e+00 6.9185e-01 -1.1644e-01 5.1278e-03 2.2114e-02 -6.0000e+00 4.1030e-01 3.7639e-02 2.4695e-03 7.8339e-03 -6.0000e+00 1.7208e-01 2.6978e-04 -8.7594e-04 5.8048e-05 9.0480e-05 -6.0000e+00 1.1979e-02 4.0948e-03 -8.1751e-05 11 8 0 10 0 0 98.36 21.28 0.22 0.00409 -0.00249 115 27 1 5 0 420.740 25.47 19.98 21.28 20.14 25.4 979.91 -157170 -160112 -171658 -95555 -121173 -128751 -166448 -161474 -139425 -124161 -108959 -98783 -25065 -55319 -69221 -28222 -31972 -59342 -36806 -18635 -22722 -18284 -10276 -43608 -17912 -33927 -14739 -28436 -2099 -8621 -20510 -6492 -10964 -2242 -9163 -11902 -13333 -637 20561 -4318 -4024 2378 1373 1933 -2871 -12709 -656 846 743 4368 4425 4047 7458 3144 5471 4326 2124 1963 2082 -4 2704 1916 4403 3077 1796 2842 197 1453 1890 2283 1194 687 229 386 -351 -575 -2048 -994 -489 -587 -647 -648 -2122 -982 -1222 -757 -466 -100 383 584 900 267 -167 -197 373 -16 259 542 -22 -776 -57 -690 -424 -236 -1258 -1492 -752 -298 5 220 -55 179 354 145 -50 404 307 394 -146 7 -385 466 379 456 410 162 208 727 33 101 98 20 -358 153 -244 -237 160 207 -322 -72 32 5 -234 -1206 -1494 -1957 -495 -754 -881 -1829 -1908 -1503 -1261 -1016 -983 -156 -608 -1119 -369 -497 -1241 -740 -332 -433 -337 -187 -1220 -416 -985 -364 -784 -44 -220 -657 -217 -448 -90 -382 -516 -661 -33 1062 -346 -363 217 134 193 -307 -1547 -73 97 91 558 639 659 1293 574 1042 869 450 415 428 -1 568 449 1151 924 575 886 64 484 693 961 562 313 112 178 -149 -219 -745 -366 -202 -290 -347 -399 -1459 -709 -949 -580 -372 -82 313 457 704 198 -120 -147 311 -15 271 610 -27 -959 -65 -783 -435 -240 -1388 -1624 -858 -365 7 309 -86 298 595 236 -77 600 459 614 -242 11 -657 758 597 688 591 241 302 1089 53 170 183 40 -721 324 -528 -540 372 490 -765 -162 71 11 -478 SS 20200715T051148.6Z 7501.216535 214 1 49.20 2 77.49 71.29 44.08 138.62 0.00 1 0.00 1 0 25 3.754e-01 6.130e-03 4.949e-02 1.317e-03 6.813366e-01 7.115706e-04 8.245195e-03 -6.000000e+00 2.210369e-01 233.85 -2.00 3.80 -2.00 320.74 0.00e+00 2.957378e-03 2.988190e-04 6.266024e-04 -6.000000e+00 9.567856e-03 283.51 -2.00 20.00 -2.00 320.13 0.00e+00 4.485 0.002 302.00 328.00 3 1.4612e+00 2.2536e-03 6.0220e-02 -6.0000e+00 5.5715e-01 6.8787e-02 2.9721e-03 4.0156e-02 -6.0000e+00 6.0180e-01 -7.0852e-02 2.9317e-03 2.0659e-02 -6.0000e+00 3.5689e-01 1.9619e-02 1.4342e-03 7.1697e-03 -6.0000e+00 1.4968e-01 6.5619e-04 -8.3570e-04 3.6195e-05 7.6578e-05 -6.0000e+00 1.0421e-02 4.1637e-03 -9.1931e-05 10 0 0 10 0 0 98.54 21.28 0.27 0.00416 -0.00212 259 61 1 5 0 187.740 25.47 20.00 21.28 20.27 25.4 980.98 -137522 -130687 -109394 -141794 -133903 -122404 -129064 -137719 -96251 -103393 -87666 -104487 -57507 -45429 -54798 -25980 -26917 -33488 -26352 -24848 -22607 -18427 -12069 -24539 -21567 -21303 -17090 -23169 -14136 -11799 -14175 -47 -6505 -4935 -9169 -8531 -5290 -624 3795 -68 -1184 746 -120 337 -57 -5064 956 1399 1824 2390 4129 3312 3586 3024 2396 1948 815 799 436 -304 1868 1915 2667 2498 1319 2020 617 1279 2193 1510 1420 439 -26 434 -256 -941 -825 -927 -371 -1031 -957 -947 -1949 -1469 -707 -810 -337 196 639 292 771 355 344 19 222 34 517 549 -240 -396 -113 -834 -460 -13 -1270 -1100 -665 -466 -324 253 55 262 171 244 85 238 436 489 -199 -187 -336 361 213 335 369 183 371 886 102 -33 -36 76 -185 129 -326 -228 37 372 -220 -194 101 -233 -21 -1059 -1107 -815 -1420 -1152 -959 -1193 -1574 -828 -1049 -810 -1341 -598 -542 -915 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