File name: Pandora67s1_Cologne_20200911_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T095520.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200911_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200911T055754.1Z 7559.248543 233 1 48.24 2 82.01 92.93 27.67 177.08 0.00 1 0.00 1 0 17 4.899e-01 2.539e-02 2.584e-01 9.781e-03 7.477600e-01 5.434220e-03 9.566417e-03 -6.000000e+00 2.855003e-01 229.18 -2.00 3.80 -2.00 321.50 0.00e+00 1.739125e-02 2.621604e-03 1.820797e-03 -6.000000e+00 1.246871e-02 281.08 -2.00 20.00 -2.00 320.96 0.00e+00 6.722 0.006 302.00 328.00 3 2.4381e+00 1.8719e-02 7.9969e-02 -6.0000e+00 7.1303e-01 8.1516e-01 2.4134e-02 4.7001e-02 -6.0000e+00 7.7429e-01 -8.8217e-01 2.1617e-02 2.6659e-02 -6.0000e+00 4.6016e-01 3.3507e-01 1.0406e-02 1.9459e-02 -6.0000e+00 1.9518e-01 2.4101e-05 -1.8426e-03 2.7489e-04 2.4723e-04 -6.0000e+00 1.3972e-02 -2.4889e-04 -8.6637e-05 12 8 8 10 0 0 0.16 21.00 0.74 -0.00025 -0.01409 23 5 1 5 0 2096.680 25.28 20.00 21.00 17.85 24.9 1010.52 900000 -5814 244413 -149559 -98591 -66764 -113612 -110373 45283 -94162 -80812 -125782 -10510 -29225 -54771 3228 -27030 900000 2242 25096 51428 286963 -29378 -12936 -32459 48076 27372 -29295 8252 150087 -1110 54069 33909 41893 51999 -4499 10145 122059 900000 10474 44872 25408 22687 17202 14003 -72883 8201 10468 42929 44790 36870 44311 32278 25135 24760 22450 -6664 15571 6743 7341 11030 10904 18085 15338 13523 16990 9268 8783 3533 15125 15946 8861 8890 -1660 -8274 -9426 -900 -6878 -931 -2650 952 -3017 -2241 -1471 -1766 -3736 -2128 -411 2715 1562 618 -1234 -4390 -1340 -931 -3511 -3864 532 -735 -468 -9 -1131 -4229 -63 -1209 1420 -2156 -1218 279 -1741 -951 184 -84 791 -350 473 810 -676 -263 378 -323 1309 2218 1320 1850 1486 552 1075 1199 544 536 -400 -1548 902 425 -116 170 678 -353 95 -1315 -349 -744 900000 -72 2330 -7282 -2576 -1155 -3009 -2767 432 -1995 -1541 -4130 -150 -675 -2031 84 -1031 900000 76 690 1056 2736 -1239 -455 -1345 881 612 -1117 218 1431 -46 1546 1368 1644 1785 -251 521 2374 900000 795 2633 1901 1830 1514 1299 -16007 857 1113 3463 3777 3718 4566 4036 3613 3695 3441 -1313 2484 1127 1203 1816 1991 3521 3363 3194 3809 2242 2202 1012 4385 5022 3091 3029 -585 -2808 -2886 -237 -1972 -286 -997 407 -1484 -1202 -826 -1057 -2423 -1416 -276 1773 996 370 -704 -2502 -767 -598 -2721 -3416 525 -810 -516 -10 -1079 -3871 -54 -1121 1308 -2180 -1324 329 -2292 -1398 287 -134 1220 -522 673 1158 -1027 -421 626 -533 2042 3312 1914 2554 2067 756 1524 1862 936 1027 -813 -3379 2034 1002 -290 434 1748 -920 236 -3198 -791 -1620 SS 20200911T060903.1Z 7559.256286 236 1 48.26 2 80.26 95.11 27.66 182.46 0.00 1 0.00 1 0 25 3.972e-01 1.046e-02 1.752e-01 4.171e-03 6.755932e-01 2.254070e-03 8.267610e-03 -6.000000e+00 2.300686e-01 229.18 -2.00 3.80 -2.00 321.11 0.00e+00 3.447208e-03 1.028864e-03 1.680018e-03 -6.000000e+00 1.002480e-02 281.08 -2.00 20.00 -2.00 320.55 0.00e+00 5.642 0.004 302.00 328.00 3 2.3916e+00 7.4046e-03 6.8416e-02 -6.0000e+00 5.7373e-01 1.9593e-01 9.9508e-03 4.0083e-02 -6.0000e+00 6.2204e-01 -2.2022e-01 9.9424e-03 2.1561e-02 -6.0000e+00 3.6982e-01 7.8003e-02 4.7894e-03 7.3144e-03 -6.0000e+00 1.5638e-01 9.0496e-05 -9.5811e-04 1.1845e-04 9.6142e-05 -6.0000e+00 1.1011e-02 -7.0106e-05 -6.4084e-05 12 8 8 10 0 0 24.97 21.02 0.38 -0.00007 -0.00727 58 14 1 5 0 831.860 25.28 19.99 21.02 17.77 24.9 1009.44 -108909 -113619 -114941 -109957 -109333 -4263 -196644 -127364 -166115 -48033 -74752 -106727 -106861 15732 -85302 -14526 -69930 -32918 -55496 -28695 -5775 46099 -39948 -32860 -2958 -39167 20382 -59191 36449 2150 4525 -22679 -1168 -13940 19300 -21865 -3047 9189 81336 1134 5932 13379 -737 14021 -936 -22061 -5791 6812 3404 15146 2902 10607 4532 8292 5784 8632 -1840 1882 2194 3571 3539 2783 7524 5062 4566 3072 3913 1466 1744 1618 4267 197 3560 205 -1560 -2601 -887 -1228 -1144 -968 -1128 -1303 -2593 -451 -512 -1634 -1831 473 92 1797 -556 1277 -1564 -966 -1108 -446 -245 274 65 -540 -306 -1106 -1023 -614 -731 -1485 -79 -445 -49 -344 649 134 218 -163 581 696 424 551 -250 221 -492 577 68 1279 73 353 134 754 347 133 48 -119 -562 21 46 -284 27 485 -230 -241 61 -408 -33 -797 -1017 -1122 -984 -889 -17 -3781 -1502 -2948 -313 -669 -1519 -1956 109 -2047 -207 -1963 -710 -1625 -677 -110 525 -1137 -949 -67 -1354 398 -2480 578 53 133 -1033 -50 -726 691 -1183 -152 478 2514 86 480 1078 -72 1218 -96 -2863 -655 705 384 1635 397 1502 747 1441 1097 1653 -403 395 446 707 726 634 1861 1450 1383 926 1170 467 608 595 1692 85 1470 82 -637 -964 -303 -427 -446 -410 -561 -746 -1654 -299 -365 -1257 -1476 383 76 1393 -411 868 -1058 -669 -858 -398 -234 300 78 -650 -348 -1155 -970 -576 -737 -1595 -89 -539 -65 -473 985 218 356 -260 874 1002 615 832 -403 369 -824 923 106 1896 104 527 195 1128 544 234 93 -234 -1169 46 109 -661 64 1170 -561 -562 143 -909 -70 SS 20200911T061700.6Z 7559.261813 240 1 49.26 2 79.01 96.69 27.74 186.29 0.00 1 0.00 1 0 17 3.313e-01 8.072e-03 7.979e-02 2.678e-03 6.139529e-01 1.418161e-03 7.533300e-03 -6.000000e+00 1.918663e-01 229.18 -2.00 3.80 -2.00 320.74 0.00e+00 3.854284e-03 5.853476e-04 6.913640e-04 -6.000000e+00 8.360570e-03 281.08 -2.00 20.00 -2.00 320.16 0.00e+00 5.057 0.003 302.00 328.00 3 2.3158e+00 4.4467e-03 6.1317e-02 -6.0000e+00 4.7846e-01 9.4630e-02 5.7728e-03 3.5674e-02 -6.0000e+00 5.1877e-01 -1.0452e-01 5.6214e-03 1.8867e-02 -6.0000e+00 3.0842e-01 3.2003e-02 2.7742e-03 7.1913e-03 -6.0000e+00 1.3041e-01 1.8325e-04 -9.1109e-04 7.6096e-05 7.8294e-05 -6.0000e+00 9.1836e-03 -2.6915e-04 -9.2576e-05 11 8 0 10 0 0 3.26 21.05 0.43 -0.00027 -0.00712 88 21 1 5 0 553.360 25.28 20.01 21.05 17.99 25.3 1010.26 -70043 -96524 -98971 -147559 -92653 -135664 -115578 -114389 -106287 -96261 -83743 -91461 -63967 -54797 -24537 -33283 -25810 -24001 -10542 -14326 -8967 3367 -24083 -14204 -20759 -9805 -22397 -19188 -14057 3586 -11401 -1636 -3509 -2224 -5530 -9992 -6280 2593 21031 -46 -213 -1089 3039 -179 2112 -14620 1728 -2327 3312 3976 4025 4725 2570 4022 4232 5240 650 682 877 2277 686 2717 2828 4771 1585 3484 375 1317 1447 1526 1242 1469 220 771 -635 -1754 -461 -1657 -1199 -1871 156 -1652 -2198 -1906 -871 -963 -377 424 673 791 1023 689 -471 -132 -536 -77 126 910 -151 59 -395 -1023 -984 -169 -1354 -1175 -469 -638 -338 279 20 400 128 347 -93 400 267 247 -145 -8 -544 336 558 275 887 20 573 871 358 24 16 -173 -403 198 -179 21 99 570 -557 -24 -231 -159 -194 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