File name: Pandora67s1_Cologne_20200912_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T095518.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20200912_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20200912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200912T062815.3Z 7560.269622 261 1 48.62 2 77.50 99.24 27.60 165.64 0.00 1 0.00 1 0 25 1.680e-01 7.113e-03 6.104e-02 2.714e-03 5.309491e-01 1.415922e-03 6.637468e-03 -6.000000e+00 9.727956e-02 229.06 -2.00 3.80 -2.00 320.15 0.00e+00 2.018845e-03 4.818719e-04 4.356326e-04 -6.000000e+00 4.238435e-03 280.98 -2.00 20.00 -2.00 319.53 0.00e+00 4.491 0.002 302.00 328.00 3 3.0621e+00 4.1866e-03 5.3845e-02 -6.0000e+00 2.4253e-01 6.3823e-02 5.1421e-03 3.0474e-02 -6.0000e+00 2.6295e-01 -5.9659e-02 4.5697e-03 1.5436e-02 -6.0000e+00 1.5634e-01 1.7430e-02 2.3351e-03 4.9815e-03 -6.0000e+00 6.6138e-02 1.6256e-04 -7.0437e-04 7.8608e-05 5.4816e-05 -6.0000e+00 4.6554e-03 -1.3738e-03 -3.0546e-05 11 8 0 10 0 0 84.50 21.45 0.43 -0.00137 -0.00667 51 12 1 5 0 953.170 25.58 20.00 21.45 24.53 25.6 1012.84 -65393 -12778 -43030 -66220 -76919 -48175 -26273 -73973 -64447 -49750 -2044 -53692 -20684 -35286 -20992 -6520 -4145 -8049 -7823 -5070 -5694 4007 -4003 -2853 -12283 3752 -5809 -10153 -3217 9715 -6275 8782 -6644 -1905 -7633 -6167 -10457 2825 17831 -816 -1785 894 1236 630 1234 -12627 782 -866 1912 3911 2051 1138 2822 1153 2635 885 -210 -371 888 390 2064 2636 3048 2751 1467 575 719 963 525 1365 1628 366 359 402 -801 -669 -1055 -665 -631 -1485 -509 -1318 -2227 -1225 -370 -1030 -267 -274 615 531 668 880 483 514 257 -359 299 679 -98 -289 -203 -803 -570 76 -1876 -830 -772 -617 14 314 -19 454 -131 213 -29 241 454 130 226 -231 -600 217 372 247 666 437 479 982 300 -40 184 -201 -264 228 54 -158 73 255 -443 85 -28 -313 -304 -917 -122 -592 -1104 -1303 -612 -292 -1488 -1331 -961 -25 -1251 -427 -1046 -661 -209 -144 -317 -331 -220 -255 163 -187 -143 -719 198 -344 -605 -173 491 -432 597 -547 -159 -645 -513 -1014 281 1862 -123 -304 158 229 121 237 -2841 156 -179 395 836 492 304 805 362 864 306 -75 -133 308 134 726 1007 1192 1197 668 254 311 423 251 741 975 232 227 242 -449 -337 -494 -308 -319 -884 -347 -948 -1763 -1017 -327 -981 -265 -280 628 523 610 746 391 418 229 -366 322 831 -131 -385 -255 -932 -606 80 -2187 -1012 -992 -789 19 471 -30 732 -211 349 -45 353 664 199 366 -371 -973 362 604 387 988 626 662 1380 468 -65 322 -376 -516 436 110 -343 154 546 -961 187 -59 -629 -591 SS 20200912T063402.2Z 7560.273637 264 1 48.48 2 76.61 100.39 27.40 168.39 0.00 1 0.00 1 0 17 3.508e-01 2.624e-02 2.491e-01 1.315e-02 4.800932e-01 6.862012e-03 6.031910e-03 -6.000000e+00 2.034856e-01 229.06 -2.00 3.80 -2.00 319.91 0.00e+00 7.036095e-03 2.070225e-03 1.049897e-03 -6.000000e+00 8.855795e-03 280.98 -2.00 20.00 -2.00 319.26 0.00e+00 4.211 0.002 302.00 328.00 3 5.3509e+00 1.9841e-02 4.9711e-02 -6.0000e+00 5.0732e-01 3.2218e-01 2.3533e-02 2.7243e-02 -6.0000e+00 5.4977e-01 -1.5397e-01 1.8893e-02 1.5457e-02 -6.0000e+00 3.2688e-01 4.9380e-02 9.7927e-03 8.4543e-03 -6.0000e+00 1.3846e-01 1.9599e-05 -1.4216e-04 3.8809e-04 8.8851e-05 -6.0000e+00 9.7170e-03 -3.5370e-03 2.6271e-04 12 9 8 11 8 0 99.88 21.46 0.18 -0.00354 -0.00461 24 6 1 5 0 2019.430 25.68 20.01 21.46 24.76 25.6 1012.65 104137 93309 -25618 -55281 -26226 15839 28700 -48139 116446 -50345 119319 -34986 230764 -29979 23535 -25826 78052 52427 22803 -21976 -15728 73908 3892 -2974 -28413 4276 20222 -18889 25902 97529 3491 26368 -4412 8140 8975 -5755 -12984 33323 140362 13080 6067 11987 380 7101 6965 -46243 -3637 3202 5896 17052 8119 6714 13044 5294 10059 858 -4694 -1578 -2235 174 1430 2878 8326 5996 -1246 4565 -1835 1421 1508 7463 4736 626 2172 75 -2091 -4410 -3148 -2374 -55 -2732 -1532 -7952 -3054 -1670 -1483 -1544 2622 -568 3236 1434 3439 -1850 768 -1884 -1148 -1129 -3498 1664 1946 357 74 -1411 -3529 453 -2133 439 1013 900 -574 738 -845 1878 480 1251 -1245 -740 504 702 -865 -864 -608 1113 806 1291 1274 -725 950 -412 1997 -2287 -224 -1092 -3225 37 2903 1181 445 436 -486 365 -1517 310 -405 1335 1196 -757 -2064 -679 273 453 -1631 1493 -1959 1530 -1306 2959 -1564 911 -1818 2335 2113 1293 -1930 -1336 2705 277 -237 -2896 336 1396 -1794 1573 3303 318 2174 -539 945 977 -710 -1851 3543 6532 2268 1248 2454 90 1643 1634 -17917 -958 808 1472 3946 2189 2002 3908 1834 3463 324 -1903 -615 -868 66 550 1187 3563 2894 -666 2194 -906 681 769 4058 2871 413 1401 47 -1250 -2420 -1592 -1166 -28 -1649 -1032 -6431 -2513 -1424 -1347 -1498 2555 -580 3250 1415 3078 -1636 622 -1549 -1010 -1105 -3930 2015 2500 463 92 -1640 -3895 479 -2487 527 1248 1181 -806 1113 -1385 3120 799 1999 -1904 -1079 720 1040 -1360 -1430 -1013 1780 1257 1952 1825 -1031 1277 -567 2882 -3718 -384 -2002 -6165 71 5774 2481 965 964 -1092 783 -3203 614 -791 SS 20200912T065312.6Z 7560.286951 270 1 49.19 2 73.66 104.29 27.04 177.70 0.00 1 0.00 1 0 25 4.448e-02 5.399e-03 1.123e-02 1.068e-03 4.248694e-01 5.483052e-04 5.373311e-03 -6.000000e+00 2.576215e-02 229.06 -2.00 3.80 -2.00 319.12 0.00e+00 9.449586e-04 1.337701e-04 1.946922e-04 -6.000000e+00 1.122389e-03 280.98 -2.00 20.00 -2.00 318.44 0.00e+00 3.496 0.001 302.00 328.00 3 2.4858e+00 1.5198e-03 4.2186e-02 -6.0000e+00 6.4227e-02 1.1982e-02 1.7590e-03 2.4042e-02 -6.0000e+00 6.9632e-02 -5.4958e-03 1.3209e-03 1.1860e-02 -6.0000e+00 4.1400e-02 -4.7282e-03 6.9513e-04 3.4832e-03 -6.0000e+00 1.7517e-02 8.4826e-04 -3.9975e-04 3.1254e-05 3.8542e-05 -6.0000e+00 1.2326e-03 -1.9545e-03 -1.7909e-05 10 0 0 10 0 0 99.79 21.49 0.25 -0.00195 -0.00496 174 41 1 5 0 279.430 25.68 20.00 21.49 24.27 25.5 1008.26 -18809 -12909 -20408 -11373 -16839 -4629 -20405 -8816 -17658 -8638 -14985 -8012 -4753 -1340 -4195 -875 -657 505 -23 -1445 998 -119 1451 -1451 -249 -1952 -414 -3706 -1064 271 981 880 1722 -1344 -1735 -2815 -2085 -366 1824 -573 -1737 -665 -873 -480 -385 -2006 -694 -219 -499 1304 863 1294 1342 1125 724 1052 59 190 207 455 1556 1345 2156 1344 306 294 505 151 1174 687 491 215 391 59 -263 -385 -279 -431 -143 -705 -779 -1358 -2373 -1205 -896 -709 -307 178 258 464 545 547 433 792 651 242 443 522 -449 -488 -183 -770 -78 219 -933 -1128 -513 -609 -52 228 160 225 126 189 30 569 355 384 17 -231 -774 132 -49 386 532 324 288 1126 110 15 73 15 -179 312 -131 -131 13 343 -289 -207 -19 -293 -222 -521 -381 -620 -331 -468 -113 -636 -275 -677 -326 -615 -333 -207 -68 -260 -60 -49 40 -2 -130 90 -11 137 -152 -27 -229 -49 -429 -114 30 121 121 263 -222 -274 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