File name: Pandora67s1_Cologne_20201120_L2Fit_fwvt1c2d20200629p1-8.txt File generation date: 20250409T102349.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v4d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20201120_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20201120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 1702 1852 Nominal wavelengths inside fitting window [nm]: 492.0797 492.2003 492.3208 492.4414 492.5619 492.6824 492.8029 492.9234 493.0438 493.1642 493.2847 493.4051 493.5255 493.6458 493.7662 493.8865 494.0068 494.1271 494.2474 494.3677 494.4879 494.6082 494.7284 494.8486 494.9688 495.0890 495.2091 495.3292 495.4494 495.5695 495.6895 495.8096 495.9297 496.0497 496.1697 496.2897 496.4097 496.5297 496.6496 496.7696 496.8895 497.0094 497.1293 497.2491 497.3690 497.4888 497.6086 497.7284 497.8482 497.9680 498.0877 498.2074 498.3272 498.4469 498.5665 498.6862 498.8058 498.9255 499.0451 499.1647 499.2843 499.4038 499.5234 499.6429 499.7624 499.8819 500.0014 500.1208 500.2403 500.3597 500.4791 500.5985 500.7179 500.8372 500.9566 501.0759 501.1952 501.3145 501.4338 501.5530 501.6723 501.7915 501.9107 502.0299 502.1490 502.2682 502.3873 502.5064 502.6255 502.7446 502.8637 502.9827 503.1018 503.2208 503.3398 503.4588 503.5777 503.6967 503.8156 503.9345 504.0534 504.1723 504.2911 504.4100 504.5288 504.6476 504.7664 504.8852 505.0039 505.1227 505.2414 505.3601 505.4788 505.5974 505.7161 505.8347 505.9533 506.0719 506.1905 506.3091 506.4276 506.5462 506.6647 506.7832 506.9017 507.0201 507.1386 507.2570 507.3754 507.4938 507.6121 507.7305 507.8488 507.9672 508.0855 508.2037 508.3220 508.4403 508.5585 508.6767 508.7949 508.9131 509.0312 509.1494 509.2675 509.3856 509.5037 509.6218 509.7398 509.8579 509.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20201120T084353.3Z 7629.363811 108 1 48.54 2 78.42 143.31 121.97 87.59 0.00 1 0.00 1 0 15 1.963e-03 1.960e-03 6.151e-04 6.143e-04 2.180240e+03 3.463959e+01 1.655500e+02 -6.000000e+00 1.029554e+02 271.87 -2.00 20.00 -2.00 505.28 0.00e+00 2.323509e-03 1.633790e-05 1.262726e-04 -6.000000e+00 5.325590e-05 271.87 -2.00 20.00 -2.00 500.49 0.00e+00 4.121315e-01 1.198575e-02 2.522630e-02 -6.000000e+00 3.847105e-02 220.99 -2.00 3.80 -2.00 502.08 0.00e+00 4.823 0.002 489.00 513.00 1 6.8869e+00 9.1522e-04 7.7550e-03 -6.0000e+00 2.9387e-03 1.9809e-02 2.3707e-04 5.8987e-04 -6.0000e+00 7.6493e-04 9.4853e-04 2.1783e-04 5.8624e-05 4.9187e-05 -6.0000e+00 1.9175e-04 -5.8325e-03 -1.0434e-04 10 0 0 10 0 0 99.06 20.56 1.67 -0.00583 -0.00432 38 9 1 4 0 1277.060 24.86 20.00 20.56 14.23 29.5 943.82 -452 -170 -267 57 107 342 311 346 256 430 82 -47 -93 -67 -205 -42 76 54 133 146 208 155 233 188 362 194 282 -110 -60 -74 -189 -172 -169 -5 -234 11 -41 -99 -190 -141 -142 -118 -88 201 70 112 110 126 -118 -79 -204 -342 -362 -350 -151 -247 -84 -28 37 227 157 87 199 137 137 73 128 -178 -105 -257 -167 -220 -152 85 -123 -101 57 -50 -52 -49 -172 -233 -232 -191 -62 -144 -171 -45 -207 -85 -69 135 53 36 347 73 -56 -82 -14 -292 -384 -245 -337 -212 -169 -211 -145 -183 -73 -118 -127 -6 88 277 310 481 408 328 297 244 -61 142 233 176 308 206 72 106 286 152 -139 82 -171 -351 -60 3 36 -94 61 175 9 119 189 1 265 238 -171 -115 -158 -242 -227 -433 -164 -267 57 110 351 325 365 269 445 84 -48 -94 -67 -205 -42 77 54 138 153 219 163 245 194 374 201 292 -113 -61 -75 -189 -173 -167 -5 -241 12 -42 -101 -197 -144 -146 -122 -90 207 73 117 115 130 -120 -80 -201 -339 -354 -343 -148 -249 -84 -28 38 231 160 89 205 141 140 74 131 -179 -104 -252 -162 -214 -148 84 -123 -100 56 -49 -51 -48 -168 -224 -224 -186 -61 -142 -170 -45 -205 -85 -68 132 53 36 347 72 -55 -80 -13 -277 -362 -233 -320 -207 -166 -210 -143 -178 -72 -116 -123 -6 89 275 310 483 412 333 300 243 -60 141 228 173 305 205 71 105 283 150 -137 80 -165 -333 -58 3 34 -92 59 172 9 118 189 1 267 239 -170 -112 -154 -232 -218 SQ 20201120T100910.3Z 7629.423035 156 1 6.51 2 72.37 163.07 109.09 102.95 0.00 1 0.00 1 0 15 2.186e-03 2.184e-03 1.134e-03 1.132e-03 1.450223e+03 6.207112e+01 1.113227e+02 -6.000000e+00 1.146243e+02 271.86 -2.00 20.00 -2.00 505.27 0.00e+00 1.389094e-03 3.009277e-05 7.634842e-05 -6.000000e+00 5.929803e-05 271.86 -2.00 20.00 -2.00 500.49 0.00e+00 2.355307e-01 2.202921e-02 1.603909e-02 -6.000000e+00 4.285059e-02 220.99 -2.00 3.80 -2.00 502.08 0.00e+00 3.257 0.001 489.00 513.00 1 6.2027e+00 1.6827e-03 5.1328e-03 -6.0000e+00 3.2730e-03 1.0537e-02 4.3689e-04 3.9336e-04 -6.0000e+00 8.5239e-04 2.4115e-03 9.5907e-04 1.0803e-04 3.0526e-05 -6.0000e+00 2.1348e-04 -6.5541e-03 -1.3197e-04 12 1 1 12 1 1 57.49 20.64 1.75 -0.00655 0.00010 6 13 1 4 0 903.730 24.96 20.00 20.64 14.61 29.4 945.84 -322 -218 -173 -241 132 314 397 359 306 309 105 16 -60 -89 18 -189 -38 20 202 194 204 127 124 285 227 210 340 -203 -164 -131 -635 -178 -42 -142 49 75 93 -220 -196 2 -59 19 95 58 191 103 293 140 91 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-181 101 85 31 -102 -102 -61 91 327 165 83 125 -278 -35 -353 -166 -249 SQ 20201120T114949.7Z 7629.492937 218 1 49.45 2 71.14 187.95 94.85 120.67 0.00 1 0.00 1 0 15 2.352e-03 2.349e-03 8.349e-04 8.336e-04 1.534319e+03 4.599965e+01 1.179244e+02 -6.000000e+00 1.233266e+02 271.86 -2.00 20.00 -2.00 505.27 0.00e+00 1.520536e-03 2.215768e-05 8.174289e-05 -6.000000e+00 6.379250e-05 271.86 -2.00 20.00 -2.00 500.49 0.00e+00 1.898320e-01 1.626405e-02 1.693898e-02 -6.000000e+00 4.607775e-02 220.99 -2.00 3.80 -2.00 502.07 0.00e+00 3.057 0.001 489.00 513.00 1 7.7839e+00 1.2417e-03 4.9503e-03 -6.0000e+00 3.5199e-03 1.4658e-02 3.2220e-04 3.9594e-04 -6.0000e+00 9.1602e-04 5.1098e-04 2.3484e-04 7.9675e-05 3.2564e-05 -6.0000e+00 2.2969e-04 -7.6589e-03 -8.0599e-05 10 0 0 10 0 0 97.22 20.68 1.74 -0.00766 -0.00603 14 3 1 4 0 3531.720 24.96 20.00 20.68 14.79 29.4 947.60 -575 -192 -326 -137 216 230 381 370 269 108 74 -39 -283 -27 -159 -76 241 -30 93 170 162 302 255 325 413 218 358 -228 86 -139 -292 56 -160 -119 -340 -71 122 -110 -360 -150 -271 76 -134 245 168 209 350 146 -80 -331 -390 -208 -621 -474 -24 -207 1 74 250 151 236 -8 337 379 -11 0 100 -95 -247 -184 -77 -57 -121 105 -69 -147 17 -26 -46 -21 -201 -189 -283 -184 -25 -259 -277 -46 -242 -79 21 169 288 -200 339 60 40 -52 184 -324 -412 -127 -483 -332 -176 -192 -22 -91 -272 -47 10 146 -27 450 283 465 331 344 248 155 3 81 243 232 160 215 160 109 113 6 -45 59 -128 -642 -48 -96 274 -154 -37 60 -62 69 149 -49 254 479 -93 15 -13 -391 -417 -559 -188 -321 -140 220 239 402 384 278 113 77 -40 -285 -27 -161 -77 241 -31 98 176 168 313 264 338 431 228 373 -236 89 -139 -288 55 -161 -123 -354 -75 127 -113 -368 -151 -274 77 -138 253 176 219 365 151 -82 -338 -387 -206 -611 -468 -24 -209 1 75 255 154 240 -9 346 388 -11 0 99 -96 -245 -180 -75 -56 -119 104 -69 -147 17 -26 -44 -20 -191 -181 -275 -180 -25 -258 -270 -46 -235 -77 20 168 289 -204 342 60 39 -51 176 -303 -394 -119 -464 -321 -175 -192 -22 -89 -263 -46 10 146 -26 448 285 469 336 351 251 155 3 80 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