File name: Pandora67s1_Cologne_20210802_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T114824.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210802_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210802T094715.3Z 7884.407816 392 1 5.08 2 39.95 136.23 48.73 246.77 0.00 1 0.00 1 0 17 7.910e-03 5.970e-03 4.153e-03 2.574e-03 2.020860e-01 1.351350e-03 2.615128e-03 -6.000000e+00 4.654889e-03 233.05 -2.00 3.80 -2.00 315.36 0.00e+00 2.657759e-04 1.226453e-04 4.289480e-05 -6.000000e+00 2.018934e-04 283.60 -2.00 20.00 -2.00 314.71 0.00e+00 1.303 0.000 302.00 328.00 3 4.3933e+00 3.5135e-03 1.7448e-02 -6.0000e+00 1.1709e-02 1.8065e-02 3.8908e-03 1.1382e-02 -6.0000e+00 1.2646e-02 -2.5304e-03 2.2230e-03 5.5158e-03 -6.0000e+00 7.5053e-03 -2.2406e-03 9.8631e-04 1.5094e-03 -6.0000e+00 3.1604e-03 1.4185e-03 1.8633e-04 7.4072e-05 1.9659e-05 -6.0000e+00 2.1939e-04 -8.0032e-03 3.8165e-05 12 1 1 12 1 1 97.04 21.42 0.12 -0.00800 -0.00660 5 14 1 5 0 816.680 25.58 20.00 21.42 24.40 32.5 969.10 -1598 222 -2254 -1231 -2074 1124 2055 441 448 120 -295 786 218 268 938 -414 204 -853 344 476 294 314 2046 173 153 720 -223 -1726 -788 371 1461 878 1572 -1385 -2318 -424 -1805 -484 522 -341 -1206 -951 -412 -868 -165 -228 -562 -565 -298 181 747 371 793 674 -59 1138 1106 211 396 413 1097 1005 1741 1344 -54 222 -396 -610 809 469 347 277 -32 400 -289 -65 -434 -321 403 -853 -983 -831 -2128 -930 -892 -790 -775 143 -33 -183 44 405 441 1038 136 191 258 580 -534 -303 344 -193 -311 313 -629 -1021 -535 -690 -74 457 284 60 75 278 121 417 400 336 77 200 -301 408 -173 266 584 336 227 1134 -92 235 249 -101 -321 210 -432 256 -45 291 0 -364 -99 -726 -235 -444 64 -679 -345 -531 273 522 121 134 37 -91 244 73 97 369 -177 88 -382 155 221 138 146 955 85 77 368 -115 -865 -368 170 683 428 803 -727 -1172 -208 -961 -281 335 -244 -917 -740 -324 -692 -129 -178 -435 -431 -222 133 566 293 646 566 -51 972 959 184 342 355 955 915 1646 1311 -53 206 -352 -536 723 450 353 290 -33 409 -285 -60 -381 -270 344 -777 -961 -861 -2297 -1028 -1019 -945 -951 179 -42 -226 51 450 468 1066 143 212 303 719 -686 -385 424 -229 -357 361 -769 -1285 -688 -918 -101 636 406 87 106 377 156 516 492 422 100 271 -417 563 -237 358 756 425 280 1382 -115 305 332 -137 -439 290 -619 379 -67 442 0 -555 -148 -1066 -341 SS 20210802T095207.4Z 7884.411196 395 1 48.31 2 39.42 137.85 49.41 247.95 0.00 1 0.00 1 0 17 7.752e-03 5.868e-03 8.064e-04 4.395e-04 1.993487e-01 2.293494e-04 2.585936e-03 -6.000000e+00 4.561866e-03 233.05 -2.00 3.80 -2.00 315.85 0.00e+00 2.500663e-04 2.312929e-05 4.212093e-05 -6.000000e+00 1.978673e-04 283.60 -2.00 20.00 -2.00 315.17 0.00e+00 1.293 0.000 302.00 328.00 3 3.1761e+00 5.9981e-04 1.7300e-02 -6.0000e+00 1.1475e-02 6.1223e-03 6.6558e-04 1.1280e-02 -6.0000e+00 1.2393e-02 2.4646e-03 3.8095e-04 5.4635e-03 -6.0000e+00 7.3554e-03 -4.2529e-03 1.7249e-04 1.4949e-03 -6.0000e+00 3.0971e-03 4.8792e-03 2.3186e-04 1.2731e-05 1.9129e-05 -6.0000e+00 2.1502e-04 -7.3434e-03 4.8847e-05 10 0 0 10 0 0 99.96 21.43 0.18 -0.00734 -0.00560 659 155 1 5 0 73.290 25.58 20.01 21.43 24.70 32.7 971.58 -889 -974 -1483 -3278 -1966 -960 211 526 817 -817 -999 74 -180 76 645 -384 -131 249 557 784 324 678 1322 472 236 373 -258 -588 -12 1197 1274 1341 1510 -1180 -1576 -566 -1455 -417 -12 -616 -1255 -722 -827 -900 -290 -661 -768 -650 -850 311 791 634 1080 1019 640 1105 694 537 601 630 1197 1213 1491 1032 -384 -19 -108 -97 1099 534 90 166 -62 189 -277 -104 -23 -271 233 -673 -959 -1195 -2128 -1182 -949 -866 -502 -5 8 10 305 433 204 768 641 156 575 567 -325 -416 -154 -656 -206 389 -829 -734 -520 -595 -157 402 222 113 81 231 128 573 392 453 241 -22 -552 176 118 252 636 498 347 1273 368 167 105 -75 -181 291 -180 -116 -106 362 -347 -251 -140 -514 -385 -196 -232 -360 -750 -426 -199 46 125 196 -209 -250 19 -50 24 222 -145 -51 99 228 330 139 286 567 198 103 167 -116 -248 -5 484 537 593 713 -540 -730 -254 -667 -217 -7 -414 -923 -548 -603 -662 -211 -479 -582 -475 -604 217 574 488 810 803 522 908 581 449 493 514 1002 1083 1339 984 -367 -18 -93 -81 942 484 90 174 -66 192 -264 -95 -19 -225 197 -595 -948 -1221 -2343 -1268 -1089 -1065 -611 -6 11 12 363 470 216 765 661 177 673 694 -425 -535 -187 -791 -232 446 -1047 -925 -684 -820 -214 572 331 171 118 312 167 734 496 562 321 -31 -778 244 162 349 827 653 434 1558 478 217 143 -106 -259 424 -265 -180 -160 560 -548 -387 -219 -788 -575 SS 20210802T100505.0Z 7884.420197 404 1 34.82 2 38.12 142.32 51.26 251.00 0.00 1 0.00 1 0 17 7.628e-03 5.785e-03 1.267e-03 7.472e-04 1.963776e-01 3.905088e-04 2.544219e-03 -6.000000e+00 4.489066e-03 233.05 -2.00 3.80 -2.00 315.55 0.00e+00 3.561852e-04 3.671316e-05 2.905727e-05 -6.000000e+00 1.947058e-04 283.60 -2.00 20.00 -2.00 314.88 0.00e+00 1.270 0.000 302.00 328.00 3 4.0160e+00 1.0176e-03 1.6995e-02 -6.0000e+00 1.1292e-02 1.3561e-02 1.1285e-03 1.1091e-02 -6.0000e+00 1.2195e-02 8.5115e-04 6.4507e-04 5.3709e-03 -6.0000e+00 7.2380e-03 -4.2999e-03 2.8781e-04 1.4803e-03 -6.0000e+00 3.0477e-03 2.1619e-03 1.9980e-04 2.1572e-05 1.9050e-05 -6.0000e+00 2.1158e-04 -7.5951e-03 4.6132e-05 12 1 1 12 1 1 99.99 21.47 0.23 -0.00760 -0.00609 123 41 1 5 0 279.390 25.68 20.00 21.47 25.99 32.7 978.27 -959 -576 -1373 -3482 -1939 -566 -324 243 943 -592 -579 -176 127 59 808 -267 14 162 557 768 393 773 1518 468 129 605 -274 -492 -145 1222 1222 1428 1623 -991 -1757 -524 -1529 -468 -11 -583 -1200 -741 -656 -948 -309 -671 -728 -639 -686 173 885 555 1163 921 653 989 513 374 465 544 1086 1045 1338 1008 -235 93 -182 -139 905 502 107 228 -36 92 -216 37 -81 -341 159 -907 -1006 -1230 -2118 -1267 -813 -832 -393 -63 -55 98 357 337 230 694 581 224 533 649 -193 -393 -118 -560 -247 396 -776 -784 -540 -564 -184 373 180 260 28 167 -24 449 335 432 272 78 -493 162 97 344 656 491 387 1157 346 225 57 -101 -218 295 -78 -132 -149 396 -367 -118 -150 -487 -503 -245 -158 -384 -920 -444 -134 -74 61 259 -173 -166 -51 40 21 293 -106 6 68 240 340 177 342 681 223 63 306 -140 -235 -63 516 538 659 798 -511 -849 -245 -791 -255 -7 -412 -868 -553 -503 -735 -236 -511 -542 -489 -509 127 671 419 914 762 558 852 450 328 400 466 953 920 1264 1010 -235 85 -163 -120 810 476 106 235 -37 92 -215 33 -70 -276 130 -835 -973 -1238 -2294 -1423 -922 -1013 -476 -79 -70 119 420 383 238 718 622 248 617 788 -250 -502 -150 -665 -291 448 -966 -982 -704 -771 -249 528 256 372 40 225 -30 566 417 557 358 105 -690 224 131 471 843 633 475 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