File name: Pandora67s1_Cologne_20210826_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T115938.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210826_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210826T065902.1Z 7908.290996 269 1 15.53 2 68.67 100.18 73.73 254.74 0.00 1 0.00 1 0 17 3.895e-02 8.439e-03 3.327e-02 5.603e-03 3.596725e-01 2.880443e-03 4.530752e-03 -6.000000e+00 2.278871e-02 231.19 -2.00 3.80 -2.00 318.27 0.00e+00 1.129551e-03 5.452355e-04 4.426433e-04 -6.000000e+00 9.900777e-04 282.70 -2.00 20.00 -2.00 317.55 0.00e+00 2.723 0.000 302.00 328.00 3 5.0861e+00 7.8145e-03 3.3919e-02 -6.0000e+00 5.7080e-02 6.3103e-02 8.8585e-03 2.0241e-02 -6.0000e+00 6.1722e-02 -4.7210e-04 5.8418e-03 9.9599e-03 -6.0000e+00 3.6671e-02 -7.2720e-03 3.0199e-03 2.9834e-03 -6.0000e+00 1.5503e-02 1.3681e-04 1.4929e-03 1.6345e-04 3.0962e-05 -6.0000e+00 1.0792e-03 -8.9382e-03 2.8251e-04 12 9 1 12 9 1 99.37 21.31 0.28 -0.00894 0.00228 3 3 1 5 0 3840.820 25.47 20.00 21.31 22.26 32.8 959.36 -9437 -8274 -22760 -12499 2598 -15344 -9376 -8854 -865 564 7261 -4896 8941 -10907 378 -324 -586 -5879 -4491 -530 10313 6536 3160 -8307 -2588 2153 -3341 870 -484 3538 2527 27 5958 -1471 1270 -2605 197 -1794 8254 -3437 -2568 315 -888 -478 679 -796 -1754 -573 1429 3211 -794 108 600 -150 890 688 -162 617 -1242 1871 1109 1317 2836 1248 -220 1710 -79 -432 1176 744 -839 1227 1242 346 -714 528 -677 -768 -1403 -1474 -1466 -1581 -1267 -1097 -1457 -1104 -300 565 944 -96 427 -499 495 -417 -108 186 729 1609 -59 -1096 -943 -1179 -1452 119 -644 -169 -859 291 47 435 502 764 491 828 -489 1206 -180 195 -304 417 -510 544 90 377 531 195 -16 -63 -95 -907 550 133 -956 -302 662 -88 189 246 7 287 -126 -337 -652 -479 -457 -1517 -724 118 -803 -504 -519 -52 36 443 -352 650 -1122 41 -39 -76 -852 -678 -80 1428 937 486 -1509 -466 392 -642 154 -82 595 464 6 1264 -351 279 -587 48 -505 2493 -1324 -1069 134 -397 -217 305 -364 -805 -257 637 1436 -385 56 327 -87 524 415 -101 380 -762 1119 681 859 1973 931 -168 1217 -55 -300 840 590 -727 1077 1089 297 -589 396 -476 -526 -1008 -1173 -1275 -1501 -1264 -1134 -1585 -1255 -352 670 1124 -113 476 -527 493 -408 -111 204 866 2059 -79 -1474 -1221 -1461 -1712 140 -808 -219 -1147 402 67 657 787 1215 770 1258 -710 1668 -251 278 -450 638 -796 835 137 560 760 270 -22 -85 -134 -1358 856 214 -1564 -504 1141 -158 345 455 14 525 -225 -588 -1118 SS 20210826T070342.0Z 7908.294236 272 1 48.57 2 67.94 101.14 74.41 255.69 0.00 1 0.00 1 0 17 2.708e-02 5.818e-03 9.934e-03 1.467e-03 3.516253e-01 7.536512e-04 4.489042e-03 -6.000000e+00 1.581680e-02 231.19 -2.00 3.80 -2.00 318.62 0.00e+00 4.104523e-04 1.559471e-04 1.683264e-04 -6.000000e+00 6.884397e-04 282.70 -2.00 20.00 -2.00 317.89 0.00e+00 2.640 0.000 302.00 328.00 3 3.7766e+00 2.0633e-03 3.3114e-02 -6.0000e+00 3.9614e-02 4.9852e-03 2.3529e-03 2.0029e-02 -6.0000e+00 4.2861e-02 1.1743e-02 1.5997e-03 9.7828e-03 -6.0000e+00 2.5464e-02 -8.7254e-03 8.3084e-04 2.7287e-03 -6.0000e+00 1.0748e-02 5.7154e-04 -2.9183e-04 4.3298e-05 3.0188e-05 -6.0000e+00 7.5090e-04 -4.9819e-03 -3.2749e-05 10 0 0 10 0 0 99.99 21.31 0.14 -0.00498 -0.00717 198 46 1 5 0 245.270 25.47 20.00 21.31 22.32 32.9 960.60 -9270 -1686 -11469 -830 -13221 1056 -9391 4248 -13925 3808 -9022 2179 -6451 2562 -2753 766 1245 607 425 -974 2316 -804 1759 -1241 1841 -1866 2241 -3950 3564 -440 2450 -1678 2546 -1433 -585 -2460 -2917 -781 1257 -838 -2159 -593 -1431 -205 -1128 146 -862 -119 -1310 827 52 1238 970 816 558 1107 888 348 712 185 1707 930 2568 822 124 -48 538 -289 1494 415 485 188 -50 8 -101 -25 35 -61 -19 -749 -1191 -684 -2183 -964 -1195 -710 -517 110 53 380 373 693 251 605 647 101 660 826 -130 -310 -138 -922 -173 68 -987 -1157 -328 -664 -120 124 416 176 50 131 -30 575 145 659 -237 185 -758 254 -200 368 348 618 108 1402 299 90 0 -17 -375 112 -116 -108 93 327 -293 -190 110 -591 -71 -420 -79 -597 -38 -613 42 -446 197 -869 213 -578 132 -480 204 -270 82 141 71 53 -128 300 -107 239 -186 282 -311 362 -643 521 -68 392 -306 492 -300 -115 -488 -644 -190 362 -284 -817 -232 -588 -85 -470 60 -357 -48 -538 340 23 572 478 431 300 606 498 196 392 105 955 565 1683 577 88 -32 349 -187 1010 313 393 160 -43 7 -79 -17 23 -38 -12 -557 -984 -611 -2137 -956 -1275 -790 -588 128 63 441 401 700 243 568 643 109 781 1044 -173 -418 -176 -1121 -199 79 -1229 -1491 -439 -922 -176 191 665 283 80 204 -44 807 202 930 -352 291 -1202 402 -311 547 499 866 146 1915 433 137 -1 -28 -631 191 -205 -198 176 629 -561 -360 204 -1063 -126 SS 20210826T073456.1Z 7908.315927 287 1 48.59 2 63.19 107.77 79.02 261.89 0.00 1 0.00 1 0 17 1.144e-02 5.546e-03 4.716e-03 1.309e-03 2.962093e-01 6.728029e-04 3.804143e-03 -6.000000e+00 6.683331e-03 231.19 -2.00 3.80 -2.00 317.50 0.00e+00 4.339748e-04 1.013597e-04 1.006762e-04 -6.000000e+00 2.907979e-04 282.69 -2.00 20.00 -2.00 316.77 0.00e+00 2.204 0.000 302.00 328.00 3 4.2947e+00 1.7930e-03 2.7686e-02 -6.0000e+00 1.6739e-02 1.9405e-02 2.0128e-03 1.6736e-02 -6.0000e+00 1.8108e-02 2.3933e-03 1.2277e-03 8.1409e-03 -6.0000e+00 1.0758e-02 -4.4220e-03 6.0977e-04 2.2680e-03 -6.0000e+00 4.5427e-03 5.5869e-04 1.8810e-04 3.8262e-05 2.5804e-05 -6.0000e+00 3.1708e-04 -6.1801e-03 4.4122e-05 10 0 0 10 0 0 99.98 21.36 0.16 -0.00618 -0.00477 74 17 1 5 0 656.500 25.58 20.00 21.36 23.33 33.0 965.70 -394 -1683 -784 -6494 -5401 -944 221 -4031 -2026 -784 -2693 -276 336 397 -1432 -16 72 1386 -761 562 19 1626 203 351 705 629 -824 -1486 639 563 935 136 2275 -2059 -994 -1773 -1596 -779 1728 -1056 -1345 -436 -598 -954 -190 -495 -315 -369 -1040 514 502 672 654 1135 461 1345 308 472 253 412 951 1253 1796 1277 48 18 -35 -329 1065 578 455 55 61 151 132 -337 -286 -553 -12 -949 -742 -1204 -2173 -1128 -828 -807 -342 211 191 333 601 444 -168 527 221 219 506 813 -385 -339 -218 -645 -365 299 -897 -1007 -492 -557 79 225 412 241 222 128 69 423 177 261 8 -131 -480 108 109 382 499 331 134 1122 186 304 51 -61 -317 264 -175 -73 -57 662 -216 -81 -163 -541 -442 -35 -166 -79 -648 -475 -80 20 -406 -223 -90 -315 -33 45 60 -253 -3 14 284 -167 126 4 366 48 88 184 171 -229 -392 153 136 242 38 683 -651 -300 -532 -513 -279 707 -511 -699 -235 -334 -541 -107 -279 -175 -201 -563 277 287 403 415 744 316 932 215 328 177 286 677 933 1417 1062 40 14 -27 -250 822 496 412 53 58 139 115 -277 -218 -413 -9 -799 -673 -1170 -2245 -1210 -914 -937 -407 259 236 404 684 483 -173 531 230 242 601 1035 -519 -450 -278 -796 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