File name: Pandora67s1_Cologne_20210924_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T121218.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20210924_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20210924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210924T074935.8Z 7937.326109 302 1 11.81 2 68.56 120.12 80.85 277.97 0.00 1 0.00 1 0 25 1.340e-02 5.759e-03 7.690e-03 1.611e-03 3.259647e-01 8.176924e-04 4.200684e-03 -6.000000e+00 7.726749e-03 227.55 -2.00 3.80 -2.00 318.01 0.00e+00 4.879453e-04 1.413062e-04 1.010578e-04 -6.000000e+00 3.364019e-04 279.59 -2.00 20.00 -2.00 317.33 0.00e+00 2.710 0.000 302.00 328.00 3 2.7562e+00 2.1902e-03 3.2442e-02 -6.0000e+00 1.9204e-02 1.1572e-02 2.4741e-03 1.8206e-02 -6.0000e+00 2.0842e-02 2.3816e-03 1.5928e-03 8.9613e-03 -6.0000e+00 1.2396e-02 -6.5770e-03 8.1856e-04 2.5747e-03 -6.0000e+00 5.2595e-03 1.5630e-03 1.6074e-05 4.7349e-05 2.9018e-05 -6.0000e+00 3.7120e-04 -6.6924e-03 3.2972e-05 12 1 1 12 1 1 99.99 21.51 0.30 -0.00669 -0.00657 68 67 1 5 0 168.600 25.68 20.00 21.51 25.99 32.9 1017.32 -3336 -2748 -3224 -7269 -2760 -4133 -114 -2886 232 -3731 -1435 -4203 -1157 -1579 -54 -681 1298 459 343 291 -591 753 -310 1796 -880 788 -1160 -928 -1304 2636 1762 1648 1315 -1948 -2171 -1075 -2324 -576 678 -675 -1203 -1687 -727 -1060 765 -724 -302 -1037 -276 540 768 311 1082 1205 851 872 572 541 611 871 1200 1563 1428 1424 -192 279 188 -103 581 836 90 437 116 363 -592 -28 -492 -874 -30 -577 -829 -1313 -2141 -1487 -1120 -837 -320 169 232 343 690 728 181 626 729 246 561 771 -253 -399 -283 -594 -350 449 -967 -988 -650 -403 -262 403 152 73 94 162 17 656 473 264 -52 -64 -603 78 -5 163 431 489 267 1352 473 6 99 -293 -209 274 20 86 -107 366 -304 -141 -204 -339 -316 -216 -196 -240 -531 -172 -256 -7 -211 18 -329 -124 -393 -121 -177 -7 -98 195 73 58 51 -106 133 -57 348 -184 169 -257 -194 -256 503 368 376 330 -526 -554 -268 -648 -183 236 -281 -556 -822 -364 -502 383 -369 -152 -518 -136 268 407 166 608 720 532 557 374 354 391 553 784 1095 1022 1099 -152 205 130 -71 420 682 76 388 103 311 -507 -21 -370 -632 -23 -461 -752 -1249 -2213 -1510 -1215 -972 -366 200 276 393 772 749 185 617 758 269 684 992 -332 -519 -367 -716 -416 537 -1201 -1298 -893 -553 -378 589 238 117 146 239 24 877 663 365 -77 -97 -928 119 -8 244 608 696 365 1828 654 9 149 -463 -339 457 34 153 -196 654 -554 -262 -363 -585 -531 SS 20210924T075924.7Z 7937.332925 308 1 48.44 2 67.24 122.35 82.31 279.81 0.00 1 0.00 1 0 25 1.349e-02 5.217e-03 6.158e-03 1.208e-03 3.097327e-01 6.121725e-04 3.998601e-03 -6.000000e+00 7.774866e-03 227.55 -2.00 3.80 -2.00 318.25 0.00e+00 3.610955e-04 1.126664e-04 1.220805e-04 -6.000000e+00 3.384870e-04 279.59 -2.00 20.00 -2.00 317.57 0.00e+00 2.564 0.000 302.00 328.00 3 3.4818e+00 1.6464e-03 3.0755e-02 -6.0000e+00 1.9323e-02 6.7131e-03 1.8673e-03 1.7338e-02 -6.0000e+00 2.0971e-02 1.0763e-02 1.2179e-03 8.5500e-03 -6.0000e+00 1.2474e-02 -9.0044e-03 6.2697e-04 2.4419e-03 -6.0000e+00 5.2924e-03 8.9047e-04 4.0275e-05 3.5887e-05 2.7606e-05 -6.0000e+00 3.7349e-04 -6.6965e-03 4.1489e-05 10 0 0 10 0 0 99.99 21.53 0.10 -0.00670 -0.00639 369 87 1 5 0 131.240 25.68 20.00 21.53 26.30 33.1 1017.48 -3209 -3047 -2911 -6564 -4041 -2060 -3274 -2494 -3678 -4868 -4102 -1167 -2764 783 -1460 -409 -462 100 197 112 -184 1089 1436 831 -197 481 -578 -1298 19 1873 1496 1508 1775 -1420 -2052 -1545 -1333 -442 1002 -772 -1610 -794 -964 -1160 -271 -607 -797 -344 -799 570 1043 619 1001 1035 616 861 613 440 541 355 1406 1394 1578 974 -124 147 147 -221 1514 536 143 198 183 40 -46 -125 86 -362 235 -398 -943 -1129 -1923 -1135 -934 -749 -367 25 80 211 553 657 179 895 560 123 448 648 -257 -394 -290 -793 -269 401 -977 -901 -716 -490 -114 272 78 143 237 145 -73 373 391 437 73 -155 -518 106 118 287 507 293 352 1230 211 283 81 -75 -302 233 -171 -31 -11 481 -239 -217 -51 -507 -262 -194 -203 -201 -441 -237 -120 -200 -168 -281 -401 -335 -97 -267 85 -180 -56 -67 15 31 18 -31 180 245 152 -38 97 -119 -254 3 334 290 316 407 -349 -478 -353 -336 -123 331 -297 -688 -353 -445 -544 -126 -283 -368 -155 -360 257 498 310 530 583 363 516 376 270 325 213 860 917 1096 732 -95 104 98 -151 1040 420 121 175 161 34 -36 -92 59 -240 162 -302 -788 -1051 -1887 -1161 -993 -853 -426 30 97 246 609 683 173 856 550 135 531 833 -346 -525 -375 -957 -309 465 -1213 -1183 -958 -690 -164 417 125 233 376 223 -106 506 525 610 106 -241 -809 166 181 424 726 401 473 1638 296 424 125 -119 -491 390 -297 -56 -20 901 -456 -403 -93 -901 -451 SS 20210924T090838.0Z 7937.380996 347 1 48.46 2 59.01 139.46 92.28 292.84 0.00 1 0.00 1 0 25 7.829e-03 5.321e-03 1.335e-03 5.002e-04 2.349500e-01 2.538002e-04 3.068697e-03 -6.000000e+00 4.514536e-03 227.54 -2.00 3.80 -2.00 316.96 0.00e+00 2.854837e-04 3.299744e-05 5.579789e-05 -6.000000e+00 1.965107e-04 279.58 -2.00 20.00 -2.00 316.29 0.00e+00 1.935 0.000 302.00 328.00 3 2.5940e+00 6.6568e-04 2.3225e-02 -6.0000e+00 1.1220e-02 5.9105e-03 7.4651e-04 1.3088e-02 -6.0000e+00 1.2176e-02 8.1825e-03 4.4218e-04 6.4309e-03 -6.0000e+00 7.2424e-03 -7.8328e-03 2.1324e-04 1.8195e-03 -6.0000e+00 3.0735e-03 4.4701e-03 2.1175e-04 1.4678e-05 2.1628e-05 -6.0000e+00 2.1682e-04 -7.5080e-03 6.3968e-05 10 0 0 10 0 0 100.00 21.64 0.20 -0.00751 -0.00592 1200 281 1 5 0 40.010 25.79 20.00 21.64 25.99 33.2 1012.93 -537 -1195 -1017 -3629 -2082 -1040 -493 -45 301 -1151 -1899 -572 -636 245 271 -211 -355 593 518 833 247 591 1152 671 137 490 -511 -651 -100 983 1038 1168 1807 -1015 -1634 -1117 -1342 -571 193 -640 -1152 -792 -574 -886 -99 -664 -671 -626 -750 242 688 554 875 983 581 1053 625 492 572 681 1119 1236 1396 1144 -312 -37 -172 -203 972 434 166 174 78 172 -92 -158 -41 -408 249 -700 -786 -1096 -2044 -1226 -831 -732 -425 55 94 105 446 532 168 809 689 289 592 644 -319 -313 -200 -740 -256 428 -839 -811 -596 -582 -201 260 171 104 56 112 18 438 448 340 186 -10 -529 76 101 234 559 420 311 1186 336 191 63 -110 -274 306 -134 -62 -73 415 -322 -96 -107 -434 -335 -69 -169 -147 -501 -273 -131 -66 -7 49 -183 -327 -99 -113 49 61 -53 -92 158 143 238 72 170 339 210 45 165 -175 -209 -30 284 316 377 625 -372 -563 -376 -497 -241 89 -350 -692 -494 -368 -576 -63 -428 -423 -384 -450 144 428 368 610 671 412 754 457 360 410 486 819 966 1179 1031 -283 -31 -134 -154 762 385 151 166 75 160 -86 -133 -31 -316 198 -580 -730 -1053 -2122 -1323 -957 -848 -516 69 119 128 533 582 170 829 687 317 720 814 -433 -418 -252 -874 -301 511 -1032 -1056 -810 -831 -283 384 266 164 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