File name: Pandora67s1_Cologne_20220407_L2Fit_fout2c2d20200629p1-8.txt File generation date: 20250409T130604.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 67 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora67_OF_v5d20191001.txt Instrument calibration file used: Pandora67s1_CF_v2d20200629.txt Level 1 file used: Pandora67s1_Cologne_20220407_L1_smca1c2d20200629p1-8.txt Full location name: Cologne Short location name: Cologne Country of location: Germany Location latitude [deg]: 50.9389 Location longitude [deg]: 6.9787 Location altitude [m]: 50 Local noon date: 20220407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1.8 data preparation: field calibration First and last pixel inside fitting window: 277 419 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2151 305.3558 305.4964 305.6371 305.7777 305.9183 306.0589 306.1995 306.3401 306.4807 306.6212 306.7618 306.9023 307.0429 307.1834 307.3239 307.4644 307.6048 307.7453 307.8858 308.0262 308.1666 308.3071 308.4475 308.5879 308.7283 308.8686 309.0090 309.1494 309.2897 309.4300 309.5704 309.7107 309.8510 309.9912 310.1315 310.2718 310.4120 310.5523 310.6925 310.8327 310.9729 311.1131 311.2533 311.3934 311.5336 311.6737 311.8139 311.9540 312.0941 312.2342 312.3743 312.5144 312.6544 312.7945 312.9345 313.0745 313.2146 313.3546 313.4946 313.6345 313.7745 313.9145 314.0544 314.1943 314.3343 314.4742 314.6141 314.7540 314.8938 315.0337 315.1736 315.3134 315.4532 315.5930 315.7328 315.8726 316.0124 316.1522 316.2920 316.4317 316.5714 316.7112 316.8509 316.9906 317.1303 317.2699 317.4096 317.5493 317.6889 317.8285 317.9681 318.1077 318.2473 318.3869 318.5265 318.6660 318.8056 318.9451 319.0846 319.2242 319.3637 319.5031 319.6426 319.7821 319.9215 320.0610 320.2004 320.3398 320.4792 320.6186 320.7580 320.8974 321.0367 321.1761 321.3154 321.4547 321.5940 321.7333 321.8726 322.0119 322.1512 322.2904 322.4296 322.5689 322.7081 322.8473 322.9865 323.1257 323.2648 323.4040 323.5431 323.6822 323.8214 323.9605 324.0996 324.2387 324.3777 324.5168 324.6558 324.7949 324.9339 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220407T092442.7Z 8132.392161 230 1 11.35 2 51.58 137.25 78.24 63.59 0.00 1 0.00 1 0 17 1.747e-02 8.157e-03 1.200e-02 4.467e-03 2.610344e-01 2.269753e-03 3.386095e-03 -6.000000e+00 1.007000e-02 227.08 -2.00 3.80 -2.00 316.86 0.00e+00 6.604704e-04 2.834553e-04 1.368065e-04 -6.000000e+00 4.258524e-04 272.58 -2.00 20.00 -2.00 316.33 0.00e+00 1.606 0.000 302.00 328.00 3 5.6991e+00 5.9332e-03 2.1595e-02 -6.0000e+00 2.5063e-02 3.8676e-02 6.6370e-03 1.4333e-02 -6.0000e+00 2.7220e-02 -1.7326e-03 3.9470e-03 7.1088e-03 -6.0000e+00 1.6129e-02 -3.7850e-03 1.9131e-03 2.0641e-03 -6.0000e+00 6.8269e-03 2.5495e-04 2.1955e-04 1.2980e-04 2.3591e-05 -6.0000e+00 4.8323e-04 -2.3063e-02 8.8262e-05 12 9 1 12 1 1 99.99 21.00 0.22 -0.02306 -0.02141 6 7 1 5 0 1596.580 25.28 20.00 21.00 18.27 34.2 1016.13 -295 -3223 -5339 -6788 5187 -8762 -2346 -1338 5134 -1078 -2163 -3472 -602 -1461 2061 793 -562 1690 -100 4124 155 2858 -2336 619 -2081 3337 -2290 -712 -2219 2275 451 -412 -141 -403 -3584 -1418 -2649 -896 2252 -850 -819 -1219 -69 -631 223 -74 -29 -984 -283 -580 152 1117 1666 757 2185 1004 -90 647 497 688 915 2159 1948 1909 247 320 -48 -42 1122 97 320 373 1251 326 -632 -140 -88 -1531 -910 -1750 -788 -1941 -2576 -1978 -904 -1434 37 109 192 161 544 219 -585 378 -526 104 -412 1562 -444 295 -352 -529 -1197 554 -1163 -667 -270 -740 -9 860 617 494 150 -514 542 71 545 251 278 286 -183 132 892 375 535 766 20 282 580 -346 -196 -42 -503 343 560 241 -243 642 -711 -22 42 -910 -644 -38 -470 -808 -1000 609 -1129 -299 -185 740 -173 -348 -577 -109 -299 464 198 -149 454 -28 1164 46 823 -712 193 -695 1095 -791 -232 -690 665 142 -138 -51 -150 -1312 -491 -1010 -372 1061 -466 -488 -752 -43 -405 141 -47 -18 -612 -174 -357 96 736 1152 542 1603 757 -69 497 375 513 698 1710 1632 1691 224 273 -39 -33 910 85 304 368 1231 317 -588 -121 -71 -1189 -719 -1489 -727 -1956 -2742 -2163 -1019 -1703 44 136 242 199 635 244 -617 380 -544 114 -493 1971 -593 392 -451 -654 -1402 648 -1446 -866 -360 -1021 -12 1254 935 758 227 -750 744 93 705 333 383 413 -271 195 1289 536 736 1012 26 360 768 -476 -282 -61 -752 517 878 393 -400 1074 -1213 -37 69 -1463 -1023 SS 20220407T092943.1Z 8132.395637 233 1 47.71 2 51.05 138.69 77.55 64.45 0.00 1 0.00 1 0 17 8.536e-03 5.243e-03 2.554e-03 8.223e-04 2.561388e-01 4.169253e-04 3.333613e-03 -6.000000e+00 4.920571e-03 227.08 -2.00 3.80 -2.00 317.26 0.00e+00 2.305969e-04 5.691076e-05 6.884544e-05 -6.000000e+00 2.080833e-04 272.58 -2.00 20.00 -2.00 316.71 0.00e+00 1.587 0.000 302.00 328.00 3 3.6653e+00 1.0956e-03 2.1315e-02 -6.0000e+00 1.2247e-02 1.0762e-02 1.2298e-03 1.4126e-02 -6.0000e+00 1.3301e-02 7.4545e-03 7.4101e-04 7.0239e-03 -6.0000e+00 7.8812e-03 -7.0458e-03 3.6504e-04 2.0178e-03 -6.0000e+00 3.3359e-03 2.0241e-03 2.6609e-04 2.4161e-05 2.3201e-05 -6.0000e+00 2.3612e-04 -2.3152e-02 9.0520e-05 10 0 0 10 0 0 99.99 21.01 0.18 -0.02315 -0.02115 865 203 1 5 0 55.080 25.28 20.00 21.01 18.73 34.3 1018.96 -1693 -1363 -2496 -3042 -3979 -484 -438 786 -90 -545 -1514 -432 -238 -536 643 -408 345 -391 660 424 915 598 1534 31 597 11 186 -1278 1 814 1401 1267 1660 -541 -1692 -460 -1733 -204 -205 -575 -1512 -616 -872 -812 -381 -571 -954 -567 -710 146 872 417 957 780 711 805 795 435 652 296 1189 1061 1537 1227 -59 -84 73 -363 915 844 43 261 -130 431 -196 166 -191 -193 84 -336 -788 -1048 -2018 -1237 -924 -718 -579 31 130 -1 341 427 287 550 872 248 673 640 -218 -418 -76 -636 -187 456 -606 -886 -555 -563 -291 304 69 149 -75 233 -27 430 402 510 150 143 -616 101 51 153 454 499 170 1172 464 86 80 -263 -173 163 -80 -135 -124 424 -203 -130 55 -423 -341 -188 -165 -316 -366 -428 -48 -46 90 -11 -75 -209 -60 -37 -95 127 -91 80 -94 164 109 239 155 404 9 175 3 58 -379 0 214 387 374 527 -183 -546 -142 -589 -78 -86 -287 -841 -355 -521 -491 -228 -342 -564 -325 -400 81 506 260 625 540 474 546 549 301 476 215 876 775 1211 1038 -51 -67 54 -263 678 702 40 254 -128 408 -175 133 -149 -142 63 -261 -691 -1020 -2135 -1268 -1008 -840 -713 39 167 -1 391 481 297 539 881 276 773 819 -301 -574 -98 -773 -211 513 -747 -1163 -759 -758 -410 450 108 239 -117 342 -38 573 525 687 216 207 -928 150 75 215 640 670 217 1466 616 122 120 -386 -258 249 -129 -232 -219 716 -350 -233 94 -710 -557 SS 20220407T093846.0Z 8132.401921 239 1 48.34 2 50.13 141.35 76.29 66.00 0.00 1 0.00 1 0 17 9.357e-03 5.477e-03 3.850e-03 1.436e-03 2.539986e-01 7.296999e-04 3.315406e-03 -6.000000e+00 5.393649e-03 227.08 -2.00 3.80 -2.00 316.88 0.00e+00 3.834460e-04 9.145593e-05 5.424398e-05 -6.000000e+00 2.280863e-04 272.58 -2.00 20.00 -2.00 316.35 0.00e+00 1.557 0.000 302.00 328.00 3 5.0502e+00 1.9084e-03 2.1020e-02 -6.0000e+00 1.3424e-02 2.9991e-02 2.1358e-03 1.4022e-02 -6.0000e+00 1.4579e-02 1.4508e-03 1.2701e-03 6.9534e-03 -6.0000e+00 8.6389e-03 -4.2436e-03 6.1516e-04 2.0006e-03 -6.0000e+00 3.6567e-03 5.1960e-04 2.2330e-04 4.1886e-05 2.3451e-05 -6.0000e+00 2.5882e-04 -2.3238e-02 9.1300e-05 10 0 0 10 0 0 100.00 21.04 0.10 -0.02324 -0.02156 102 24 1 5 0 473.810 25.28 20.01 21.04 19.40 34.2 1021.55 -997 -228 -3573 -3359 -2359 -823 -2965 441 -1108 -50 -2959 -897 -783 22 1128 -87 -224 569 1012 596 1138 840 1398 121 748 468 -417 -658 -404 821 935 1374 2202 -1199 -1120 -1117 -2907 168 1297 60 -1542 -485 -704 -844 -704 -444 -666 -544 -773 169 738 512 601 753 388 741 748 288 476 354 1216 1034 1499 1158 -332 -119 6 -569 884 596 184 525 -79 508 -132 -206 -172 -640 -89 -487 -920 -747 -2067 -1464 -1036 -429 -621 -31 405 179 550 742 -25 380 557 -45 484 782 89 -430 -20 -581 -347 183 -650 -898 -484 -522 -168 391 321 177 -32 288 86 422 74 279 22 45 -641 133 133 354 409 374 -100 969 448 304 94 -219 -305 12 -88 47 28 479 -187 -90 88 -618 -435 -130 -32 -543 -481 -301 -99 -383 61 -172 -8 -484 -149 -142 4 255 -22 -58 152 281 172 332 243 411 38 244 156 -141 -215 -124 244 293 448 768 -443 -396 -382 -1100 69 606 33 -917 -298 -448 -545 -451 -283 -419 -338 -471 101 463 338 411 543 287 554 569 220 356 262 915 818 1258 1027 -301 -101 5 -453 717 526 175 516 -79 494 -122 -178 -136 -486 -69 -412 -850 -741 -2169 -1598 -1167 -508 -766 -39 511 223 650 823 -26 379 573 -50 572 996 118 -573 -25 -713 -407 215 -809 -1157 -648 -716 -237 573 491 274 -48 422 119 557 96 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