File name: Pandora124s1_ComodoroRivadavia_20190224_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T081339.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190224_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190224T100447.0Z 6994.419988 180 1 32.00 2 89.78 103.45 39.42 330.86 0.00 1 0.00 1 0 29 1.649e-01 1.506e-01 1.494e-01 1.398e-01 9.227650e+03 1.014094e+04 4.613823e+02 -6.000000e+00 8.844747e+03 280.45 -2.00 20.00 -2.00 505.34 0.00e+00 -4.920735e-03 3.915323e-03 5.064642e-04 -6.000000e+00 4.550032e-03 280.45 -2.00 20.00 -2.00 499.70 0.00e+00 1.952292e+00 2.845612e+00 1.443385e-01 -6.000000e+00 3.250901e+00 230.09 -2.00 3.76 -2.00 501.44 0.00e+00 20.130 0.096 489.00 513.00 1 8.9350e+00 2.2070e-01 3.5514e-02 -6.0000e+00 2.4831e-01 1.4852e-01 5.4546e-02 2.9234e-03 -6.0000e+00 6.5428e-02 1.3303e-05 1.7374e-02 1.1417e-02 1.6712e-04 -6.0000e+00 1.5096e-02 3.1739e-02 -5.6408e-05 12 9 8 11 8 0 -324.75 21.46 4.35 0.03174 0.15225 8 2 1 4 0 4000.000 25.58 20.01 21.46 -24754 -17835 1149 -8599 -17227 16945 12571 1598 -17383 35640 -11716 -21369 5961 10976 -4182 10737 -11183 40210 -7341 26682 6007 11653 -2025 25728 13560 -9665 -6175 -19660 993 15414 12812 -3555 13956 -13717 17810 1929 5075 -2946 13424 18519 365 -24461 20187 1301 10723 6625 22191 2757 18144 -3794 9506 -625 7037 15872 14226 42269 -5034 10497 25082 9740 11244 5062 19120 -5266 43445 -18663 1797 -11515 12752 -2681 6643 5644 35597 -21100 -17863 -13712 19746 12096 16816 9685 282 10437 356 -5320 1917 -17115 23268 -5392 -20825 23721 4529 17660 33758 25364 -9465 5818 19866 31387 -15290 995 -15948 17666 19147 30732 6055 14101 34613 3134 -17268 10973 4994 989 -16278 3981 -5806 -3791 4106 9104 -17034 7555 29806 -3154 -2877 7525 -10483 26614 11870 20 -4393 -25071 3946 -13546 -9054 6020 19473 3582 1222 -23441 6478 7531 -5965 -1364 -5776 -10425 19092 -12899 9231 -16855 46039 -13393 -34483 -24030 1325 -10333 -23060 16431 12852 1819 -23635 28173 -14695 -29055 6094 10643 -4760 10751 -14379 31786 -9439 24467 6774 12405 -2476 23863 14150 -12632 -7680 -27146 1078 14296 12288 -4122 14121 -18794 17833 2237 5616 -3478 13300 17372 411 -35579 18936 1481 11076 7052 19881 2935 16064 -4039 8617 -619 6527 13885 13045 29850 -5730 10179 20885 9444 10784 5176 16928 -5884 29306 -23015 1780 -12865 11021 -2685 6092 5294 25138 -26465 -21464 -15464 15609 10199 13470 8370 270 9130 349 -5607 1899 -20565 18639 -5740 -24050 19002 4122 14173 24551 18122 -9264 4726 13610 18738 -14366 799 -15609 12968 14617 21656 5511 11730 23036 2822 -19097 9236 4497 929 -18162 3623 -5853 -3784 3818 8019 -19172 6507 20128 -2933 -2675 6333 -10568 18493 9526 18 -4127 -28709 3321 -13390 -8507 4890 14103 3120 1112 -27760 5769 6708 -6130 -1349 -5992 -11326 15322 -14013 7860 -18311 26585 -14156 SO 20190224T100849.0Z 6994.422789 184 1 32.00 2 89.10 102.72 39.75 329.42 0.00 1 0.00 1 0 22 1.278e-01 1.180e-01 1.006e-01 9.540e-02 1.770829e+03 5.968591e+03 7.260243e+02 -6.000000e+00 6.854687e+03 280.45 -2.00 20.00 -2.00 505.11 0.00e+00 -1.876894e-03 2.582530e-03 1.099492e-04 -6.000000e+00 3.525509e-03 280.45 -2.00 20.00 -2.00 499.62 0.00e+00 3.616038e+00 1.949655e+00 1.954954e-01 -6.000000e+00 2.515569e+00 230.09 -2.00 3.76 -2.00 501.27 0.00e+00 18.847 0.078 489.00 513.00 1 8.5873e+00 1.4971e-01 3.2289e-02 -6.0000e+00 1.9220e-01 1.3544e-01 3.8737e-02 2.9840e-03 -6.0000e+00 5.0537e-02 1.9656e-05 -9.3152e-03 8.2575e-03 1.1740e-04 -6.0000e+00 1.1693e-02 -4.5516e-02 5.3140e-04 12 8 8 10 0 0 -63.73 21.46 5.81 -0.04552 -0.11013 8 2 1 4 0 4000.000 25.58 19.98 21.46 -3106 -7448 17976 -17107 4321 -5103 10585 -14223 20035 6328 4165 -315 1381 -11334 5147 -13092 22642 -13176 23351 -12283 15767 -10278 10202 -1704 37455 -1904 -1797 -11328 4889 -4491 24001 -9078 10529 -8727 15371 -11254 20930 -884 20220 15126 1410 969 8324 5171 -2282 -8026 8157 16741 -6130 -484 -7139 8651 -16743 7365 -10156 7507 -3812 17987 -5470 13999 -1421 36112 -12732 317 -5108 2674 -17228 18417 2703 5705 571 19222 -3903 4026 13848 11895 9999 -3788 -2400 8756 -10919 -8770 -12804 8541 -12991 -1653 -6242 1596 2937 -674 -12606 1439 2003 -13672 8263 -5426 7274 -18370 29524 -11859 15203 519 11128 -7373 15940 -4007 2872 -16230 23041 -829 -478 8754 26674 -6770 20683 -1789 9863 -3753 13698 -6350 20883 284 16516 9853 -4187 13237 4981 -18308 15302 -107 3373 14458 4191 25597 -4661 16412 -5024 14859 -13871 15355 -15478 10202 -1120 17228 -15070 -7868 -19875 18514 -14176 15038 -3436 -8702 16803 -21772 4948 -6055 11873 -19123 19160 6871 4552 -355 1509 -13855 5293 -16191 19862 -16958 21492 -16428 15985 -13524 10930 -2058 30701 -2313 -2171 -14905 5343 -5199 20364 -10705 10372 -10793 15473 -14970 20016 -1036 18900 14683 1561 1080 8679 5614 -2691 -10042 8621 16010 -7228 -526 -8008 8024 -19623 6778 -11392 7287 -4248 16296 -6253 13086 -1543 27004 -15562 339 -5730 2730 -21058 15494 2624 5291 550 15341 -3957 3821 12049 10520 8844 -3759 -2312 7492 -11384 -9018 -13810 7492 -14291 -1640 -6508 1537 2788 -664 -13046 1407 1973 -14697 7061 -5217 6022 -19134 18529 -11006 10658 426 8470 -7040 12452 -3852 2550 -17122 16153 -737 -428 7248 18700 -6690 15605 -1696 8363 -3658 11158 -6232 15337 253 12350 7895 -3886 10341 4224 -19558 11647 -95 2882 10908 3442 16748 -4108 11835 -4595 11409 -14447 12097 -16741 8582 -1062 13688 -16602 -8038 -22559 13968 -14482 11346 SO 20190224T101239.0Z 6994.425451 188 1 32.00 2 88.45 102.04 40.08 328.08 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