File name: Pandora124s1_ComodoroRivadavia_20190427_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T082509.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190427_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190427T112725.0Z 7056.477373 286 1 32.00 2 89.79 69.73 27.59 352.40 0.00 1 0.00 1 0 36 1.753e-01 1.515e-01 1.434e-01 1.333e-01 1.258791e+04 9.968382e+03 1.601119e+02 -6.000000e+00 9.296930e+03 277.96 -2.00 20.00 -2.00 505.24 0.00e+00 5.250733e-04 3.702000e-03 1.341583e-04 -6.000000e+00 4.807371e-03 277.96 -2.00 20.00 -2.00 499.80 0.00e+00 -1.621354e-01 2.767679e+00 5.730054e-02 -6.000000e+00 3.424841e+00 223.54 -2.00 3.76 -2.00 501.45 0.00e+00 20.284 0.098 489.00 513.00 1 8.9066e+00 2.1221e-01 3.2363e-02 -6.0000e+00 2.6166e-01 1.8495e-01 5.4336e-02 2.0017e-03 -6.0000e+00 6.8723e-02 1.4459e-05 -3.4122e-02 1.0809e-02 4.3022e-05 -6.0000e+00 1.6028e-02 -3.9402e-02 5.1455e-04 12 8 8 10 0 0 -29.80 22.01 10.06 -0.03940 -0.27609 8 2 1 4 0 4000.000 26.11 20.00 22.01 -14290 -4224 -2104 -641 10293 -9123 1044 22238 1963 24311 -18438 2793 9907 -18581 -14825 10591 263 19862 -8685 2982 -3627 -7949 -443 -5589 9557 25563 2045 15058 20634 -6554 17784 -14079 11163 -15038 22788 -4104 10967 -6087 29953 -2849 24927 -10686 15610 -7962 7465 -545 -17470 -5066 21652 -13236 30874 -1159 22214 -966 26767 -14769 5199 -10941 -3939 -831 1556 -4243 16334 8682 6995 35745 -2901 -9845 2041 -268 2346 36630 8728 -3889 6328 -1210 -6296 16776 4744 7096 -17166 19589 17498 43087 -18180 29140 1707 -19950 -37001 16666 -1925 5153 19292 15967 -16843 28688 16974 13353 -2515 15508 -19623 40181 -4409 -1563 7760 -14089 15023 33056 6050 27860 19569 21590 13522 -21083 -19131 -16672 29398 943 43761 15460 13846 -12897 9617 -7652 31098 -9030 17836 -19714 39386 -9610 23519 -8398 13384 -1818 -4238 -13560 -1076 -2305 52337 -8239 -7786 -17847 25189 -3320 -1029 -10933 9690 -9851 40417 -4909 -18041 -4690 -2290 -705 10530 -10814 1143 20107 2209 21981 -25378 3058 9953 -24453 -18468 10108 278 17360 -10296 3236 -4300 -9903 -512 -6794 9985 22856 2321 14977 19279 -7902 16258 -17114 10430 -18432 19689 -4824 11348 -7461 25277 -3292 21536 -13097 14742 -9599 7799 -624 -23869 -6107 19795 -16888 24814 -1246 18300 -980 20437 -17360 5170 -13190 -4512 -927 1688 -4860 15261 8809 7238 27651 -3265 -11671 2112 -280 2357 25760 8066 -4102 6103 -1277 -7021 14663 4575 6559 -20004 15744 14415 27703 -21735 21956 1715 -23263 -51086 14399 -1850 4615 15118 13107 -19326 20607 13301 10463 -2229 11139 -19587 21740 -3743 -1327 6298 -14983 12333 22819 5418 19752 14969 16314 11227 -24977 -22309 -18975 21117 906 27760 13124 11883 -14197 8254 -7638 20887 -9098 13810 -22252 24617 -9771 17114 -8383 10613 -1645 -3874 -13535 -954 -2107 28317 -8301 -7917 -20311 18798 -3314 -1008 -11831 8497 -10385 25262 -4717 SO 20190427T113120.0Z 7056.480093 290 1 32.00 2 89.15 69.02 27.69 350.45 0.00 1 0.00 1 0 29 1.370e-01 1.206e-01 1.069e-01 1.010e-01 1.225344e+04 7.257630e+03 8.691691e+02 -6.000000e+00 7.268673e+03 277.96 -2.00 20.00 -2.00 505.12 0.00e+00 1.630808e-03 2.679364e-03 9.920149e-05 -6.000000e+00 3.760874e-03 277.96 -2.00 20.00 -2.00 499.63 0.00e+00 5.459838e-01 2.060336e+00 6.818726e-02 -6.000000e+00 2.686031e+00 223.54 -2.00 3.76 -2.00 501.26 0.00e+00 19.087 0.082 489.00 513.00 1 8.7385e+00 1.5739e-01 3.0063e-02 -6.0000e+00 2.0509e-01 1.8258e-01 4.0521e-02 2.3850e-03 -6.0000e+00 5.4079e-02 1.9155e-05 5.0264e-03 8.3623e-03 8.3756e-05 -6.0000e+00 1.2549e-02 -6.2218e-02 4.1981e-04 12 9 8 11 8 0 -318.22 22.01 -1.88 -0.06222 -0.02735 8 2 1 4 0 4000.000 26.21 20.00 22.01 6679 -12946 1909 8277 -1583 -4166 -2578 -1460 16940 -2593 -11132 4607 6517 -13885 6323 -9819 3598 -11562 22528 -4343 18212 -3863 12729 -17639 -411 -5040 10563 6729 -803 -68 1604 3918 5156 6829 -4290 30058 5036 30997 2343 31879 -20658 6406 -6068 -2931 471 28730 -2490 3418 11703 6453 -21091 22901 -2301 7736 -12197 15663 -14053 9331 964 9297 -4092 7752 -9733 6151 -11303 -1147 5130 10817 -3606 -7921 12290 -8863 -7729 3072 -5937 -4418 -1529 -16216 19901 10211 3679 -6496 33211 8474 31155 -18105 14276 -2608 28015 6061 5164 -5638 8097 -6716 17047 -14595 11789 -11683 39653 -17920 -5757 -8941 8421 -13489 23177 -16371 -423 -23983 9599 2897 1163 10370 6705 5214 13646 17813 6386 15474 -9392 15763 -1360 389 -11724 3188 3770 5612 -6136 25602 -1420 33523 -4444 5819 -13863 37589 16 30589 -1684 8956 -12014 14095 -3630 -8117 -1974 30115 -3054 -13321 10558 -10041 -14538 -4222 6717 -16223 2140 9007 -1945 -5357 -3060 -1723 17875 -3019 -13893 4838 6596 -17011 6304 -11581 3778 -14518 20572 -5222 17463 -4615 12883 -24295 -479 -6137 10932 7118 -886 -72 1648 3965 5297 7171 -5158 25618 5442 25475 2532 25472 -27983 6678 -7250 -3435 537 24705 -2899 3693 11399 6433 -26803 18298 -2347 7241 -14387 14422 -17752 9373 1049 9268 -4671 7905 -11850 6366 -13762 -1240 5114 10043 -3814 -8619 10849 -9712 -8469 3062 -6506 -4707 -1548 -18633 15750 8858 3416 -6723 23251 7674 22760 -21768 12384 -2660 20892 5627 4872 -6007 7579 -6691 14011 -14748 9510 -10732 21295 -16841 -4800 -7898 6545 -13726 16869 -17815 -388 -27454 7800 2538 1052 8647 5828 4605 11089 13972 5686 12684 -9822 12587 -1258 346 -11681 2748 3250 4759 -5853 17729 -1285 21319 -4082 4729 -13518 21780 14 19454 -1511 7341 -12310 11254 -3489 -8202 -1883 20855 -2935 -14025 8580 -9792 -14588 -3819 SO 20190427T113518.0Z 7056.482847 294 1 32.00 2 88.51 68.30 27.82 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