File name: Pandora124s1_ComodoroRivadavia_20190428_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T082629.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190428_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190428T113054.0Z 7057.479792 301 1 32.02 2 89.43 68.86 30.81 12.57 0.00 1 0.00 1 0 22 1.143e-02 1.134e-02 1.008e-02 1.002e-02 1.627559e+04 7.214436e+02 1.107849e+03 -6.000000e+00 6.060526e+02 277.90 -2.00 20.00 -2.00 505.46 0.00e+00 2.646545e-03 2.724180e-04 1.570649e-04 -6.000000e+00 3.136466e-04 277.90 -2.00 20.00 -2.00 500.71 0.00e+00 1.611162e+00 1.948701e-01 1.069285e-01 -6.000000e+00 2.240958e-01 223.43 -2.00 3.76 -2.00 502.28 0.00e+00 19.683 0.089 489.00 513.00 1 6.1669e+00 1.4817e-02 3.2179e-02 -6.0000e+00 1.7108e-02 1.6307e-02 3.7957e-03 3.1643e-03 -6.0000e+00 4.5145e-03 2.1298e-04 1.3798e-03 8.3161e-04 1.2458e-04 -6.0000e+00 1.0467e-03 -2.0389e-02 1.2746e-04 12 8 8 10 0 0 -24.79 21.49 3.90 -0.02039 -0.01082 8 2 1 4 0 4000.000 25.58 20.02 21.49 -679 -824 -108 1789 -1108 1348 1430 266 -1378 447 -678 1151 -906 1458 -192 -1082 -2316 1036 812 -506 973 214 36 1457 834 494 919 872 751 -785 -1036 -1865 386 157 678 1001 544 613 -639 -725 -322 -852 1734 -868 1181 -383 1021 -1598 -861 368 -1492 -1298 -1051 -2431 -928 251 1085 697 -1369 1725 2096 -157 -722 316 967 232 577 252 -458 -456 -950 1919 860 793 -688 -497 -2176 -615 -790 -249 -930 -29 -1090 -156 2021 -529 -2874 -601 -1100 -329 -2138 44 871 2291 -450 1439 1780 -617 -1769 -1182 -1531 -171 -2808 857 -1463 674 173 -704 -9 -1422 780 319 -675 838 637 1032 1168 2259 1196 200 599 890 1408 -786 787 453 1693 -24 334 -930 2032 -1936 483 -1921 -521 -1066 144 -547 2012 -452 1138 63 579 -544 488 891 309 -178 -2438 -562 -575 -713 -96 1632 -1070 1299 1405 267 -1403 441 -666 1097 -869 1350 -180 -1032 -2276 1013 817 -522 992 221 37 1495 869 518 957 899 755 -774 -1008 -1843 382 163 720 1068 577 643 -672 -759 -337 -907 1825 -952 1285 -425 1112 -1766 -928 382 -1533 -1299 -1040 -2466 -889 246 1081 704 -1412 1721 2089 -161 -750 325 980 233 570 246 -445 -438 -910 1793 821 770 -684 -490 -2138 -583 -742 -231 -870 -27 -1037 -148 1912 -518 -2883 -585 -1068 -317 -2110 43 857 2206 -433 1308 1552 -534 -1515 -991 -1287 -145 -2564 800 -1460 671 173 -701 -8 -1429 781 325 -700 859 655 1065 1224 2382 1280 214 624 904 1406 -806 803 466 1731 -25 346 -978 2062 -2011 483 -1963 -528 -1108 141 -551 2011 -471 1182 67 615 -586 520 941 323 -183 -2533 -572 SO 20190428T113453.0Z 7057.482558 305 1 32.00 2 88.79 68.14 30.68 10.74 0.00 1 0.00 1 0 15 1.507e-02 1.502e-02 1.412e-02 1.401e-02 1.253274e+04 1.000697e+03 9.035491e+02 -6.000000e+00 7.988119e+02 277.90 -2.00 20.00 -2.00 505.40 0.00e+00 2.379772e-03 3.774781e-04 1.175733e-04 -6.000000e+00 4.137475e-04 277.90 -2.00 20.00 -2.00 500.43 0.00e+00 1.647552e+00 2.777753e-01 7.240482e-02 -6.000000e+00 2.960552e-01 223.43 -2.00 3.76 -2.00 502.02 0.00e+00 18.201 0.071 489.00 513.00 1 6.7431e+00 2.1225e-02 2.8509e-02 -6.0000e+00 2.2591e-02 5.1448e-02 5.3882e-03 2.4645e-03 -6.0000e+00 5.9816e-03 1.4846e-04 4.5181e-03 1.1900e-03 9.3250e-05 -6.0000e+00 1.3795e-03 9.7048e-03 -2.5879e-04 12 8 8 10 0 0 -6.97 21.50 3.57 0.00970 0.04104 8 2 1 4 0 4000.000 25.58 19.97 21.50 -84 -512 -2045 560 -1321 896 -480 -577 -328 -691 725 1588 1428 -2118 146 -1118 -494 -1670 1448 -635 1557 -1451 -888 2926 -1149 -1600 666 970 1843 -2002 1306 1648 1653 -291 100 -386 -1225 201 1284 734 283 764 -2638 264 1604 902 -2755 914 -3168 876 -366 2467 -2575 -198 510 1652 61 -711 795 2778 788 1685 -1298 2281 -20 -779 -280 1896 -3301 1846 2225 -1724 502 -925 337 -652 -1077 675 -2609 -531 -2117 -1504 1376 585 3844 696 -310 -2896 2605 -1355 221 481 2198 -176 2113 2487 1487 -2636 -657 1036 -74 -143 863 -2618 1639 -2349 -9 -1730 740 -388 2194 1218 2533 -1317 -1530 2292 960 -322 -1477 -145 1977 -1920 -1944 -782 345 -1889 1146 2547 -500 640 457 -472 -1255 178 -1578 -756 -2509 751 -770 1470 -783 1255 881 339 -585 -1311 -1457 861 1635 68 -79 -494 -1922 533 -1315 892 -494 -600 -339 -708 721 1546 1370 -2080 140 -1088 -486 -1709 1476 -668 1607 -1544 -941 3003 -1237 -1735 704 1011 1853 -2019 1252 1584 1627 -304 108 -420 -1330 212 1327 759 295 799 -2892 285 1729 983 -3098 979 -3472 899 -369 2355 -2556 -194 511 1694 65 -773 851 2905 841 1796 -1432 2428 -21 -835 -294 1918 -3475 1821 2166 -1751 504 -957 348 -674 -1097 662 -2609 -517 -2096 -1491 1335 536 3723 652 -294 -2797 2365 -1278 207 455 2069 -169 1940 2200 1283 -2297 -548 835 -60 -118 738 -2444 1527 -2312 -8 -1664 689 -368 2059 1171 2427 -1317 -1538 2231 960 -330 -1537 -147 1923 -1902 -1905 -760 335 -1884 1112 2440 -493 624 444 -455 -1202 167 -1512 -730 -2527 746 -790 1496 -825 1306 926 360 -626 -1405 -1540 871 1611 67 SO 20190428T113846.0Z 7057.485255 309 1 32.00 2 88.16 67.44 30.58 8.95 0.00 1 0.00 1 0 22 2.013e-02 1.992e-02 2.023e-02 2.007e-02 1.216550e+04 1.400294e+03 8.460607e+02 -6.000000e+00 1.067502e+03 277.90 -2.00 20.00 -2.00 505.25 0.00e+00 5.562360e-04 5.407240e-04 5.161706e-05 -6.000000e+00 5.525393e-04 277.90 -2.00 20.00 -2.00 500.17 0.00e+00 1.301288e+00 3.999866e-01 7.002149e-02 -6.000000e+00 3.948781e-01 223.43 -2.00 3.76 -2.00 501.78 0.00e+00 16.530 0.053 489.00 513.00 1 7.4075e+00 3.0597e-02 2.5355e-02 -6.0000e+00 3.0144e-02 7.9046e-02 7.8277e-03 2.2610e-03 -6.0000e+00 7.9587e-03 1.0188e-04 3.6690e-03 1.6813e-03 8.3492e-05 -6.0000e+00 1.8441e-03 1.6523e-03 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