File name: Pandora124s1_ComodoroRivadavia_20190501_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T082903.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190501_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190501T113232.0Z 7060.480926 394 1 32.00 2 89.79 67.87 53.70 49.68 0.00 1 0.00 1 0 22 4.727e-02 4.691e-02 4.116e-02 4.064e-02 1.651168e+04 3.026291e+03 1.109169e+03 -6.000000e+00 2.504197e+03 277.73 -2.00 20.00 -2.00 505.34 0.00e+00 -1.333438e-04 1.091126e-03 6.285075e-05 -6.000000e+00 1.296710e-03 277.73 -2.00 20.00 -2.00 500.21 0.00e+00 6.021117e-01 8.117574e-01 9.983070e-02 -6.000000e+00 9.267695e-01 223.09 -2.00 3.76 -2.00 501.82 0.00e+00 20.293 0.098 489.00 513.00 1 7.6569e+00 6.2143e-02 3.3082e-02 -6.0000e+00 7.0746e-02 1.0987e-01 1.5746e-02 3.1039e-03 -6.0000e+00 1.8678e-02 4.9181e-05 3.7504e-03 3.3146e-03 1.0611e-04 -6.0000e+00 4.3290e-03 -1.7652e-02 7.7251e-05 12 8 8 10 0 0 50.78 21.35 5.65 -0.01765 0.00836 8 2 1 4 0 4000.000 25.47 20.00 21.35 -5179 2029 -5122 1581 -832 5621 -859 5868 -4049 3514 -4599 -4454 -5480 4272 -781 -1847 10861 3248 -2246 -3151 4659 2117 -3670 -179 2588 3703 4088 -123 1252 -87 -560 -13710 7527 1507 11531 -9575 468 -7870 3087 1179 2488 -1039 4414 -356 1091 -747 8895 3034 5576 130 2071 -4699 4027 2367 -3608 2650 -1841 -2233 1802 -2274 -5428 4576 -199 5454 -1303 2285 -5442 3192 -4291 -875 -3681 -450 -2817 -684 412 9139 386 4686 3131 3557 -6216 3974 -246 -4154 -10009 -1664 -7406 118 -2978 11822 -6208 3029 4711 1307 4291 5847 -826 -6938 1840 442 -1062 -5090 -318 -4691 7390 4963 7092 1971 -3933 -692 1533 -6139 3328 1121 1638 -631 1834 -3153 9472 -1156 -2983 -5128 8314 1901 11687 -6654 2039 -4257 7000 3075 13 -3621 -1618 -8505 6067 -5567 4319 -3949 5225 589 3839 3559 5894 -2886 3240 -5544 -5820 3169 -3882 -580 -5327 1986 -5161 1545 -854 5527 -918 5913 -4490 3562 -4987 -4761 -5825 4070 -780 -1878 9914 3293 -2469 -3533 4838 2256 -4149 -197 2775 3925 4295 -133 1297 -88 -562 -15832 7217 1597 11374 -11703 512 -9233 3205 1238 2583 -1127 4584 -393 1196 -835 8964 3197 5619 135 2037 -4822 3750 2270 -3791 2703 -2007 -2463 1905 -2494 -6152 4724 -216 5597 -1417 2359 -5968 3168 -4534 -882 -3789 -450 -2925 -706 424 8538 385 4393 2945 3313 -6398 3725 -243 -4314 -10391 -1604 -7563 111 -2872 9819 -6215 2800 4314 1223 3771 4856 -705 -6098 1450 348 -852 -4372 -274 -4484 6538 4573 6374 1839 -3859 -661 1452 -6339 3134 1077 1566 -621 1789 -3283 8702 -1164 -2987 -5120 7166 1752 9839 -6756 1902 -4226 6192 2825 12 -3460 -1496 -8394 5212 -5479 3944 -3988 4890 586 3746 3513 5717 -3062 3226 -5976 -6192 3019 -3909 -565 SO 20190501T113627.0Z 7060.483646 398 1 32.00 2 89.16 67.17 53.20 48.66 0.00 1 0.00 1 0 29 1.480e-02 1.473e-02 1.368e-02 1.354e-02 1.936909e+04 1.027420e+03 1.312873e+03 -6.000000e+00 7.838327e+02 277.73 -2.00 20.00 -2.00 505.51 0.00e+00 1.952570e-03 3.639372e-04 1.328924e-04 -6.000000e+00 4.060069e-04 277.73 -2.00 20.00 -2.00 500.67 0.00e+00 2.147392e+00 2.665930e-01 1.238409e-01 -6.000000e+00 2.902834e-01 223.09 -2.00 3.76 -2.00 502.23 0.00e+00 19.113 0.082 489.00 513.00 1 6.5364e+00 2.0266e-02 3.1422e-02 -6.0000e+00 2.2156e-02 9.6763e-03 5.0956e-03 3.5940e-03 -6.0000e+00 5.8554e-03 1.5387e-04 3.0310e-04 1.0953e-03 1.2391e-04 -6.0000e+00 1.3554e-03 1.0055e-02 -1.4421e-04 12 8 8 10 0 0 -582.97 21.36 2.74 0.01005 0.01216 8 2 1 4 0 4000.000 25.47 19.99 21.36 -4517 245 692 1496 1936 1133 1371 -41 1676 998 -20 -1083 303 -4094 445 2678 -1867 -1392 -1302 245 -2857 556 -1278 1565 425 975 793 278 471 -154 1081 1321 1476 4321 520 -939 -2461 148 1190 1190 210 -2497 747 692 514 -1571 2047 -219 2352 -832 876 -933 -1075 960 -1215 -1518 -1746 267 -2302 -925 176 -2541 3113 2435 1167 359 -844 -247 -1217 -664 -1121 112 56 -921 -1091 -137 16 82 -1565 1808 -2220 2899 -270 372 35 739 133 -516 -2468 374 -1452 -565 -491 321 2111 1694 606 -427 -495 -2780 -2638 -1513 184 -539 -1105 359 481 -529 -1975 499 513 1057 81 1197 1500 -182 1157 -636 2372 650 -562 1386 -306 -520 2156 -594 -27 551 2407 665 1917 -1931 619 -1712 -399 -1792 843 -1596 2259 969 -781 -300 1033 -1220 1792 2463 -989 273 -2294 -1915 -3968 209 610 1363 1807 1091 1345 -41 1659 983 -20 -1061 289 -4022 416 2461 -1826 -1393 -1340 252 -3040 572 -1345 1610 446 1020 830 290 478 -151 1033 1266 1444 4276 553 -1024 -2704 157 1232 1224 218 -2695 791 744 561 -1758 2201 -239 2452 -874 878 -927 -1056 931 -1240 -1610 -1907 289 -2558 -1011 191 -2844 3312 2610 1258 385 -900 -258 -1269 -680 -1060 105 53 -894 -1072 -133 15 76 -1454 1611 -2059 2570 -249 345 33 700 127 -492 -2378 348 -1386 -542 -476 306 1920 1483 514 -353 -400 -2265 -2139 -1240 156 -488 -1060 348 468 -514 -1931 479 500 1038 81 1180 1475 -183 1169 -667 2438 673 -577 1361 -301 -513 2091 -597 -27 552 2367 666 1886 -1945 599 -1691 -392 -1817 854 -1691 2341 1035 -862 -334 1143 -1386 1974 2681 -1101 295 -2504 -2075 SO 20190501T114024.1Z 7060.486390 402 1 32.12 2 88.53 66.45 52.71 47.62 0.00 1 0.00 1 0 22 1.843e-02 1.838e-02 1.469e-02 1.454e-02 2.083706e+04 1.123752e+03 1.375712e+03 -6.000000e+00 9.763051e+02 277.73 -2.00 20.00 -2.00 505.48 0.00e+00 1.424414e-03 3.916048e-04 1.103371e-04 -6.000000e+00 5.055406e-04 277.73 -2.00 20.00 -2.00 500.59 0.00e+00 1.353057e+00 2.873587e-01 1.305975e-01 -6.000000e+00 3.613231e-01 223.09 -2.00 3.76 -2.00 502.16 0.00e+00 17.524 0.063 489.00 513.00 1 6.8986e+00 2.1928e-02 2.8729e-02 -6.0000e+00 2.7582e-02 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