File name: Pandora124s1_ComodoroRivadavia_20190504_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T083200.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190504_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190504T113625.0Z 7063.483623 486 1 32.00 2 89.78 66.53 83.46 67.78 0.00 1 0.00 1 0 15 8.673e-02 8.272e-02 6.512e-02 6.315e-02 1.414901e+04 4.705561e+03 1.493041e+03 -6.000000e+00 4.593084e+03 277.56 -2.00 20.00 -2.00 505.22 0.00e+00 -5.923396e-04 1.683235e-03 8.737114e-05 -6.000000e+00 2.377129e-03 277.56 -2.00 20.00 -2.00 499.89 0.00e+00 1.207164e+00 1.290745e+00 2.085614e-02 -6.000000e+00 1.694608e+00 222.75 -2.00 3.76 -2.00 501.50 0.00e+00 20.281 0.098 489.00 513.00 1 8.0747e+00 9.8334e-02 3.1972e-02 -6.0000e+00 1.2945e-01 1.4427e-01 2.5486e-02 2.0506e-03 -6.0000e+00 3.4022e-02 3.1175e-05 -1.4356e-02 5.1639e-03 1.4616e-04 -6.0000e+00 7.9336e-03 -5.7333e-02 5.7819e-04 12 8 8 10 0 0 75.92 21.33 -0.94 -0.05733 -0.15691 8 2 1 4 0 4000.000 25.47 20.00 21.33 -3401 8252 -2357 2896 5235 7020 -820 10787 -1621 -2304 4458 -909 -9070 22370 -12206 -281 -13406 2811 3951 11772 -2980 18880 -9640 2140 -6431 3767 2658 1116 -7620 5852 -3718 3687 -2150 2672 2998 -2007 7630 2366 2282 6858 2559 -9477 -2554 -1506 7030 -2298 6521 2818 -2668 -3586 10580 -10741 20351 -14923 14604 -6944 -6073 -7661 6651 -7365 16702 -10794 4252 -8033 12654 -11322 9623 -9490 5070 -11332 -2916 -3867 7583 -9098 2307 -9507 8140 4354 10868 8678 10480 -2118 12826 11974 16038 709 -94 4073 -5130 11094 -4271 4662 -3196 16207 1535 -4265 2842 2341 -9949 8914 -3319 10391 -7143 -6825 -7027 -916 -5649 6692 -13732 15262 -12675 10250 -10661 -3476 -8883 3528 -6750 3418 -11027 17106 -3973 16719 -5800 10477 -3713 1699 1421 12951 1209 2958 2686 -4896 16487 -8849 8210 2153 17583 6588 -4381 863 4634 898 4926 277 8425 458 15183 -15346 11167 -14278 -3612 7830 -2553 3091 5642 7601 -905 10782 -1844 -2621 4668 -991 -10577 18739 -14292 -291 -16016 2916 4175 11766 -3475 17703 -12021 2374 -7805 4142 2947 1248 -9139 5933 -4017 3667 -2293 2798 3254 -2340 8062 2602 2477 7018 2716 -11368 -2881 -1699 7361 -2658 6890 3058 -3010 -3994 9920 -12065 16371 -16976 12581 -7668 -6851 -8933 6743 -8553 15183 -12947 4411 -9443 12046 -13526 9161 -10751 4899 -12729 -2970 -3958 6966 -10003 2295 -10679 7555 4103 9414 7600 8979 -2066 10867 10316 13435 702 -95 3916 -5372 9822 -4412 4438 -3094 13962 1397 -3978 2374 1893 -8838 6422 -2670 7348 -6219 -6244 -6801 -862 -5617 5826 -14445 11940 -13221 8608 -11120 -3380 -9109 3197 -6832 3173 -11941 13911 -3916 13079 -5562 8474 -3479 1517 1275 10360 1085 2601 2362 -4587 12242 -8369 6531 1836 13133 5620 -4240 805 4220 857 4550 269 7559 443 12549 -16888 9230 -15019 SO 20190504T114058.0Z 7063.486782 490 1 32.00 2 89.05 65.71 82.76 66.94 0.00 1 0.00 1 0 15 4.874e-02 4.755e-02 4.329e-02 4.271e-02 9.616917e+03 2.964714e+03 7.408735e+02 -6.000000e+00 2.580294e+03 277.56 -2.00 20.00 -2.00 505.29 0.00e+00 7.377944e-04 1.144897e-03 5.117044e-05 -6.000000e+00 1.336222e-03 277.56 -2.00 20.00 -2.00 500.14 0.00e+00 1.613970e+00 8.508865e-01 4.446460e-02 -6.000000e+00 9.545765e-01 222.75 -2.00 3.76 -2.00 501.75 0.00e+00 18.869 0.079 489.00 513.00 1 7.8336e+00 6.5119e-02 2.9272e-02 -6.0000e+00 7.2879e-02 9.9295e-02 1.6641e-02 2.0777e-03 -6.0000e+00 1.9223e-02 4.6730e-05 3.7373e-03 3.6605e-03 6.0925e-05 -6.0000e+00 4.4623e-03 4.1272e-03 3.2973e-06 12 9 8 11 8 0 85.66 21.34 -0.27 0.00413 0.03005 8 2 1 4 0 4000.000 25.47 20.01 21.34 2789 -4466 -2915 -2880 -4452 6789 -3476 -4820 5787 -4251 3509 -370 1177 8426 8853 4177 -3127 -1156 -3712 936 -3072 2279 -596 1702 1315 2745 -4184 3465 -5073 2343 -9643 3685 -562 -513 3577 6125 -6134 4560 1784 -379 -1340 746 -2227 4072 -3846 3404 -1546 6657 1531 867 -3289 2074 1235 -1613 7249 1626 3028 -1836 -4742 -441 6890 -546 9464 3153 3933 -6768 4384 -5734 3051 -12531 -25 -11246 -243 -4416 9864 -5825 5227 2276 4656 -6727 2901 -1992 2049 2096 13229 1168 -1759 -6846 -1703 5664 -1144 -3177 5472 2748 6687 -165 4971 -4953 3785 -8525 -6651 5607 2700 -3718 2304 -3616 -5178 -1435 -2152 15242 -3875 9084 -5717 1031 -569 722 1278 1768 -3740 4767 -2940 11004 -4283 8757 114 5966 -735 1340 -2303 1425 -4521 3010 -6478 3387 3528 1033 -8638 5623 -2293 5844 -5619 5844 -2043 -4571 -1823 -3290 2360 2585 298 218 2674 -4719 -3151 -3223 -4786 7221 -3849 -5446 5849 -4679 3524 -381 1174 7729 8065 4020 -3301 -1231 -4158 1009 -3451 2428 -655 1835 1431 2942 -4781 3614 -5584 2315 -10615 3582 -586 -557 3822 6387 -7148 4712 1872 -404 -1445 795 -2473 4299 -4432 3649 -1727 6750 1601 888 -3399 1983 1181 -1609 6836 1674 3138 -2010 -5327 -472 6875 -591 9291 3288 4026 -7581 4318 -6165 2965 -14037 -24 -12416 -243 -4677 9112 -6225 4896 2154 4256 -6864 2698 -1962 1953 2017 11540 1158 -1795 -7316 -1721 5324 -1160 -3095 5319 2530 5776 -148 4101 -4382 2998 -7517 -5765 4407 2283 -3523 2121 -3556 -5123 -1347 -2019 12118 -3787 7901 -5810 983 -553 697 1242 1723 -3834 4417 -2882 9210 -4148 7486 107 5296 -699 1245 -2217 1320 -4405 2672 -6235 2936 3069 939 -8856 5092 -2282 5432 -5912 5519 -2101 -4836 -1874 -3403 2264 2418 280 205 SO 20190504T114525.0Z 7063.489873 494 1 32.00 2 88.35 64.90 82.08 66.11 0.00 1 0.00 1 0 29 4.868e-02 4.866e-02 4.800e-02 4.689e-02 1.385300e+04 3.432155e+03 9.340492e+02 -6.000000e+00 2.577473e+03 277.56 -2.00 20.00 -2.00 505.11 0.00e+00 -3.042730e-04 1.261376e-03 8.767510e-05 -6.000000e+00 1.336363e-03 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