File name: Pandora124s1_ComodoroRivadavia_20190601_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T083500.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190601_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190601T120724.1Z 7091.505140 476 1 32.12 2 89.80 57.18 70.20 43.89 0.00 1 0.00 1 0 15 6.581e-02 6.251e-02 6.910e-02 6.677e-02 7.939170e+03 4.685776e+03 4.141651e+02 -6.000000e+00 3.465840e+03 276.36 -2.00 20.00 -2.00 505.12 0.00e+00 1.881282e-03 1.789818e-03 1.313603e-04 -6.000000e+00 1.800690e-03 276.36 -2.00 20.00 -2.00 499.51 0.00e+00 2.876945e+00 1.387821e+00 7.519172e-02 -6.000000e+00 1.288875e+00 220.28 -2.00 3.76 -2.00 501.16 0.00e+00 20.374 0.099 489.00 513.00 1 7.9654e+00 1.0620e-01 3.2788e-02 -6.0000e+00 9.8341e-02 1.6036e-01 2.7498e-02 2.3038e-03 -6.0000e+00 2.6026e-02 2.9728e-05 5.1193e-04 5.6517e-03 4.9397e-05 -6.0000e+00 6.0253e-03 3.3353e-02 -3.8803e-04 12 9 8 11 8 0 11.60 21.67 1.98 0.03335 0.03690 8 2 1 4 0 4000.000 25.90 20.00 21.67 9873 -7612 -1385 27 7058 674 362 -5447 2973 5725 4488 1212 -2761 316 8399 -230 -2125 -5475 747 5727 -7576 3040 -972 3288 -976 4008 4511 -6495 -8669 1301 5263 -4797 -2519 13291 -3048 2269 -2 3501 -12440 4839 469 -729 5395 -5030 3872 11759 -441 2233 4091 -3576 -3675 -422 382 -5253 -2258 -4145 -3940 1666 -5272 9733 -7833 8837 -1347 -1030 394 2536 3573 -4906 2965 -2154 4238 13022 -3882 -1669 1285 -1730 6628 -5065 -3613 8679 -12461 9073 -399 5053 17831 -9493 -12251 -5122 10857 14748 1417 8540 -15870 -5084 843 14552 1496 -14234 -439 -4979 10618 12418 4147 -5333 -7220 3443 663 -4062 4376 -3165 3623 -1288 12000 -39 -9104 -2360 5227 9394 -1194 -435 184 1379 1749 7516 7123 4694 -604 -6813 7344 86 -374 -837 15042 -8000 -4564 -190 -11460 8670 -10226 -4575 -2636 13045 -2994 7804 9004 9565 -3555 -1859 -3066 3576 9527 -8881 -1571 32 7850 815 449 -6661 3336 6166 4811 1323 -3085 337 8200 -246 -2342 -6392 843 6225 -9417 3396 -1129 3673 -1144 4478 4995 -7943 -10558 1382 5244 -5286 -2763 12908 -3605 2569 -2 3823 -15713 5090 515 -815 5729 -5999 4268 12012 -506 2461 4344 -3995 -3976 -429 378 -5525 -2364 -4569 -4441 1794 -6075 9600 -9184 8805 -1491 -1135 425 2629 3596 -5284 2910 -2190 3988 11206 -3986 -1696 1281 -1768 6104 -5123 -3545 7468 -13231 7808 -380 4577 14357 -10128 -13440 -5207 9343 12172 1341 7607 -16983 -5271 810 11863 1347 -13502 -353 -4095 7393 8588 3217 -4759 -6815 2960 582 -3682 3599 -2810 3048 -1156 9533 -35 -9019 -2195 4543 7902 -1116 -398 164 1192 1487 6041 5792 3926 -534 -6399 5971 75 -327 -724 10895 -7215 -3967 -160 -11031 6968 -10082 -4318 -2463 10485 -2840 6674 7615 8001 -3339 -1677 -2736 2958 SO 20190601T121144.0Z 7091.508148 480 1 32.00 2 89.17 56.40 69.70 42.93 0.00 1 0.00 1 0 36 7.260e-02 6.539e-02 5.110e-02 4.965e-02 9.738282e+03 3.524207e+03 7.593419e+02 -6.000000e+00 3.824293e+03 276.36 -2.00 20.00 -2.00 505.18 0.00e+00 4.465932e-03 1.348093e-03 2.093123e-04 -6.000000e+00 1.986563e-03 276.36 -2.00 20.00 -2.00 499.69 0.00e+00 3.220268e+00 1.029544e+00 4.702770e-02 -6.000000e+00 1.421272e+00 220.28 -2.00 3.76 -2.00 501.34 0.00e+00 19.192 0.083 489.00 513.00 1 7.7603e+00 7.9193e-02 3.0281e-02 -6.0000e+00 1.0846e-01 1.2029e-01 2.0245e-02 2.0475e-03 -6.0000e+00 2.8673e-02 4.0340e-05 -5.5603e-03 4.2036e-03 1.0071e-04 -6.0000e+00 6.6476e-03 -4.2643e-02 1.2901e-04 12 8 8 10 0 0 66.31 21.67 5.12 -0.04264 -0.08121 8 2 1 4 0 4000.000 25.79 20.01 21.67 -2708 4627 -8213 7928 65 5134 -3123 8540 -2525 1037 -446 1790 -1203 3195 -1161 2677 -7328 1541 2126 574 1605 -2150 5703 2468 827 1055 657 3025 6006 -9069 -6991 -1821 -267 -10247 7794 -5416 15708 1315 -3008 -12605 2510 -9444 6151 -5581 12925 -7794 3935 4310 12108 -3203 -52 -4224 13758 -1304 5144 -2516 5372 -1033 2985 5407 -861 -1905 11028 -1271 -1175 5800 9158 2822 8194 -6594 -12201 -3827 -9008 -129 -485 -2250 -6375 8827 -9532 -597 -10024 1536 -3055 4401 -10998 -3690 -141 7282 -8610 21428 44298 4675 1066 7891 518 8886 -10115 3743 -5096 8882 -8849 2221 -4954 -3167 -4059 119 4141 4972 -7848 3866 722 546 -1858 -556 3066 1180 2419 939 4879 -2653 5855 -7924 1396 1941 792 -3843 10089 -8376 4357 -3433 4971 -9524 4399 1465 7328 -12446 12206 -5749 13809 -3133 -185 1275 698 1891 600 624 7454 -4190 4572 -4200 -2887 4614 -9589 8195 75 5765 -3887 9590 -2929 1149 -492 1903 -1296 3240 -1217 2695 -8227 1615 2275 636 1766 -2453 6018 2696 925 1185 740 3306 6248 -10588 -7743 -1901 -278 -12156 8020 -6486 15165 1447 -3410 -15565 2658 -11344 6398 -6620 12914 -9654 4329 4678 11962 -3608 -55 -4521 12046 -1322 4985 -2721 5528 -1152 3206 5645 -953 -2138 10935 -1427 -1310 5947 8910 2873 7788 -7156 -13788 -3952 -9843 -130 -497 -2349 -6822 7927 -10095 -572 -10503 1437 -3006 4035 -11852 -3729 -138 6567 -9021 16518 27185 4303 1033 7205 504 7747 -9595 3222 -4321 6388 -7472 1682 -4131 -2707 -3653 105 3510 4129 -7309 3197 625 482 -1705 -508 2717 1070 2185 871 4374 -2544 5066 -7709 1218 1679 699 -3579 8204 -8207 3755 -3197 4249 -9300 3668 1242 5831 -12152 9500 -5473 10988 -2993 -173 1187 658 1767 569 589 6501 -4018 3924 -3882 SO 20190601T121557.0Z 7091.511076 484 1 32.00 2 88.56 55.64 69.23 41.98 0.00 1 0.00 1 0 15 3.707e-02 3.726e-02 3.918e-02 3.840e-02 6.728607e+03 2.535644e+03 4.552841e+02 -6.000000e+00 1.951876e+03 276.36 -2.00 20.00 -2.00 505.13 0.00e+00 4.915895e-04 1.030829e-03 3.152809e-05 -6.000000e+00 1.013865e-03 276.36 -2.00 20.00 -2.00 499.69 0.00e+00 1.963531e+00 7.866342e-01 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