File name: Pandora124s1_ComodoroRivadavia_20190616_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T083553.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190616_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190616T121743.0Z 7106.512303 329 1 32.00 2 89.73 55.03 99.92 229.19 0.00 1 0.00 1 0 22 6.756e-03 6.653e-03 1.725e-03 1.720e-03 1.115661e+04 1.121445e+02 7.606097e+02 -6.000000e+00 3.550444e+02 275.87 -2.00 20.00 -2.00 505.39 0.00e+00 1.546114e-03 4.631006e-05 9.400535e-05 -6.000000e+00 1.845483e-04 275.87 -2.00 20.00 -2.00 500.87 0.00e+00 1.497354e+00 3.284423e-02 8.294321e-02 -6.000000e+00 1.319714e-01 219.32 -2.00 3.76 -2.00 502.39 0.00e+00 20.292 0.098 489.00 513.00 1 3.9653e+00 2.5032e-03 3.2807e-02 -6.0000e+00 1.0073e-02 4.7887e-03 6.3959e-04 2.6596e-03 -6.0000e+00 2.6590e-03 1.8253e-03 1.1699e-03 1.4685e-04 1.0635e-04 -6.0000e+00 6.1859e-04 3.5686e-02 -2.5293e-04 12 8 8 10 0 0 26.24 21.75 3.10 0.03569 0.04380 8 2 1 4 0 4000.000 25.79 20.00 21.75 -2301 -1512 -676 32 -150 801 891 717 845 151 -184 343 -348 -608 -929 -426 -375 95 460 357 535 349 497 533 889 601 572 -129 26 -824 -965 -1244 -740 452 644 14 339 -163 201 -433 295 -85 453 547 1296 608 803 199 187 -237 -216 -1555 -1241 -1193 87 -105 519 579 507 134 466 1044 843 667 741 451 -144 -78 -504 -489 -516 -566 -528 -50 -20 -366 -752 -990 -1162 -1006 -1006 -481 -502 -262 -471 -28 -706 195 -623 -261 -136 590 678 958 837 492 85 -46 -418 -1200 -1538 -1146 -610 -241 167 226 76 -248 -600 -415 -183 249 420 765 771 1368 1386 1199 830 508 302 64 197 375 274 -23 499 111 778 255 233 -584 -361 -679 -610 -671 36 68 375 -160 151 326 340 194 499 305 -121 -918 -1040 -1397 -2084 -1389 -605 30 -143 773 877 714 839 150 -180 330 -332 -576 -879 -404 -362 94 467 349 522 342 488 526 882 600 570 -129 25 -776 -946 -1166 -708 446 654 15 345 -165 201 -432 293 -86 460 564 1343 637 836 206 190 -236 -210 -1489 -1173 -1140 85 -106 535 603 528 139 485 1090 843 669 737 467 -148 -79 -507 -486 -508 -561 -530 -50 -19 -356 -758 -981 -1141 -983 -986 -474 -499 -263 -456 -27 -694 189 -607 -253 -133 581 677 951 815 467 82 -44 -386 -1101 -1413 -1072 -563 -234 168 231 77 -250 -603 -418 -187 258 439 801 810 1441 1409 1237 861 523 306 64 203 370 273 -23 502 112 781 258 234 -584 -355 -667 -601 -673 36 71 396 -173 165 358 376 206 530 338 -133 -995 -1110 -1492 SO 20190616T122215.6Z 7106.515459 333 1 33.28 2 89.08 54.21 100.49 228.32 0.00 1 0.00 1 0 22 5.375e-03 5.251e-03 1.114e-03 1.110e-03 1.010372e+04 7.235322e+01 6.979107e+02 -6.000000e+00 2.824610e+02 275.87 -2.00 20.00 -2.00 505.41 0.00e+00 1.342203e-03 3.004661e-05 8.456976e-05 -6.000000e+00 1.468304e-04 275.87 -2.00 20.00 -2.00 500.83 0.00e+00 1.347035e+00 2.130642e-02 7.344240e-02 -6.000000e+00 1.049983e-01 219.32 -2.00 3.76 -2.00 502.39 0.00e+00 19.010 0.081 489.00 513.00 1 3.4661e+00 1.6243e-03 3.0014e-02 -6.0000e+00 8.0141e-03 1.7595e-03 4.1543e-04 2.3991e-03 -6.0000e+00 2.1155e-03 3.6613e-03 1.4485e-03 9.5170e-05 9.7952e-05 -6.0000e+00 4.9217e-04 6.2993e-03 -7.6710e-05 12 8 8 10 0 0 -27.88 21.75 2.38 0.00630 0.01635 13 3 1 4 0 2560.056 25.90 20.00 21.75 -1739 -1364 -480 191 236 645 901 782 718 320 94 24 -573 -509 -808 -404 -430 145 436 362 166 395 146 305 461 567 532 215 -308 -752 -621 -608 -676 327 526 219 137 101 11 -39 -131 -227 447 555 827 728 440 319 219 -291 -454 -846 -1121 -1077 -250 -165 432 169 517 331 552 542 607 448 746 136 109 -24 -246 -811 -660 -373 -478 -111 -111 -253 -152 -733 -994 -952 -686 -403 -621 -431 60 -274 -348 -124 -507 -267 96 287 686 732 437 597 156 -132 -219 -1273 -1262 -1041 -436 28 39 -27 -146 -252 -516 -48 201 102 173 320 710 920 984 963 623 458 180 176 189 375 163 228 285 174 130 530 43 -162 -222 -264 -667 -249 -172 -116 119 208 136 269 341 97 427 48 -181 -558 -848 -1067 -1584 -1201 -436 179 228 634 901 753 691 320 93 24 -557 -489 -776 -390 -422 139 428 361 167 395 147 308 468 577 541 217 -304 -722 -586 -577 -659 329 545 229 142 103 11 -39 -133 -233 462 556 836 740 446 320 217 -295 -448 -818 -1075 -1044 -249 -162 432 171 522 335 557 551 622 460 757 137 108 -24 -240 -783 -632 -358 -464 -109 -111 -251 -148 -703 -946 -902 -651 -385 -600 -420 59 -274 -348 -123 -505 -266 96 291 702 747 439 582 148 -122 -198 -1144 -1132 -952 -414 28 38 -28 -146 -249 -507 -47 201 104 178 330 732 954 1033 1023 665 483 187 180 191 381 167 236 295 180 135 548 45 -165 -223 -264 -673 -254 -172 -119 124 220 145 290 369 106 466 52 -195 -590 -883 -1111 SO 20190616T122640.7Z 7106.518527 337 1 33.43 2 88.46 53.41 101.03 227.47 0.00 1 0.00 1 0 22 4.780e-03 4.696e-03 8.439e-04 8.417e-04 8.635155e+03 5.385437e+01 5.969864e+02 -6.000000e+00 2.512288e+02 275.87 -2.00 20.00 -2.00 505.39 0.00e+00 1.213144e-03 2.275389e-05 7.757523e-05 -6.000000e+00 1.305603e-04 275.87 -2.00 20.00 -2.00 500.79 0.00e+00 1.299203e+00 1.618166e-02 6.480049e-02 -6.000000e+00 9.332058e-02 219.32 -2.00 3.76 -2.00 502.35 0.00e+00 17.405 0.062 489.00 513.00 1 3.1902e+00 1.2337e-03 2.6833e-02 -6.0000e+00 7.1238e-03 2.7492e-03 3.1645e-04 2.1139e-03 -6.0000e+00 1.8787e-03 6.0970e-03 5.3106e-04 7.2934e-05 8.3733e-05 -6.0000e+00 4.3759e-04 -1.8399e-02 1.2782e-04 12 8 8 10 0 0 15.86 21.75 1.82 -0.01840 -0.01472 20 4 1 4 0 1671.164 25.90 20.00 21.75 -1245 -1108 -370 -57 294 589 824 688 700 232 266 109 -271 -537 -434 -439 -212 -312 267 166 228 295 201 251 491 381 464 233 -260 -635 -729 -742 -446 476 371 305 321 135 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