File name: Pandora124s1_ComodoroRivadavia_20190624_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T083729.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190624_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190624T121920.0Z 7114.513426 273 1 32.00 2 89.80 55.01 49.32 311.71 0.00 1 0.00 1 0 15 8.077e-02 7.631e-02 7.689e-02 7.384e-02 7.518364e+03 5.148443e+03 4.383301e+02 -6.000000e+00 4.242154e+03 275.64 -2.00 20.00 -2.00 505.13 0.00e+00 7.831206e-04 1.987223e-03 1.157371e-04 -6.000000e+00 2.203853e-03 275.64 -2.00 20.00 -2.00 499.50 0.00e+00 2.807615e+00 1.541348e+00 6.258145e-02 -6.000000e+00 1.573227e+00 219.53 -2.00 3.76 -2.00 501.17 0.00e+00 20.397 0.100 489.00 513.00 1 8.0792e+00 1.1835e-01 3.2661e-02 -6.0000e+00 1.2015e-01 1.6501e-01 3.0381e-02 2.1891e-03 -6.0000e+00 3.1571e-02 2.6912e-05 1.0070e-03 6.3372e-03 4.9813e-05 -6.0000e+00 7.3855e-03 -4.2182e-02 4.8858e-04 12 8 8 10 0 0 -478.81 22.00 3.98 -0.04218 -0.03520 8 2 1 4 0 4000.000 26.00 20.00 22.00 -1710 3497 11312 6744 -2330 -2202 1861 18299 -12004 13737 2595 -5286 -2607 767 8611 3317 -10582 2296 -10391 4768 -636 -3502 -3029 -2129 -8957 14258 -7171 -4272 1717 4623 -850 1579 -3835 7129 -6978 797 -11499 8712 8986 376 519 17126 -5442 -1502 13610 -7093 7524 5876 2110 4973 -3235 1926 7490 -5736 3860 -10073 10318 2480 2000 -4635 -4091 -116 4738 -1996 6783 -6676 7041 -11041 5816 760 -4491 -754 3182 -2838 4807 -6009 -3438 -4900 10949 2229 27316 -2141 -16617 -5258 -14656 8032 14231 -512 -7107 228 5076 5178 -2556 2263 5276 -2484 -7358 6509 4704 4378 -9100 14830 -2546 113 -860 16842 7656 -8152 940 17479 -8198 3902 6505 3875 -7119 13417 -3973 15448 -10575 12285 -7007 16615 -7619 1676 -9738 -3487 -9570 8407 -2186 15 -14921 -8131 3046 1715 6745 13400 -5031 19630 -3527 -2397 4679 -4408 4000 -5187 71 3022 13389 8330 1028 -2568 -1867 3711 11527 7441 -2879 -2775 2289 19198 -15634 14743 2831 -6148 -2902 815 8435 3453 -12898 2531 -13302 5281 -743 -4210 -3624 -2536 -11465 14442 -8941 -5088 1863 4708 -903 1652 -4354 7538 -8700 918 -14783 9018 9152 415 572 16108 -6482 -1739 13634 -8724 7915 6181 2255 5010 -3421 1887 6878 -6097 3845 -11886 10107 2637 2127 -5237 -4599 -126 4905 -2199 6758 -7468 6741 -12474 5470 740 -4574 -743 3046 -2922 4601 -6321 -3444 -4881 9202 2035 19460 -2061 -18589 -5297 -16396 7197 11959 -496 -7317 218 4662 4813 -2589 2167 4787 -2364 -6617 5325 3549 3258 -7760 10193 -2171 98 -774 12708 6252 -7667 802 12737 -7838 3347 5480 3364 -6917 10678 -3799 12215 -10766 9778 -6626 12193 -7087 1429 -9361 -3154 -9199 6734 -1943 13 -14882 -7438 2455 1391 5228 9903 -4576 14203 -3262 -2218 4062 -4214 3535 -5040 66 2671 10449 6673 872 -2256 SO 20190624T122354.0Z 7114.516597 277 1 32.00 2 89.15 54.19 49.92 310.48 0.00 1 0.00 1 0 22 5.176e-02 5.013e-02 5.157e-02 5.013e-02 1.078313e+04 3.563044e+03 7.170478e+02 -6.000000e+00 2.717948e+03 275.64 -2.00 20.00 -2.00 505.11 0.00e+00 2.245502e-03 1.345466e-03 1.674879e-04 -6.000000e+00 1.413760e-03 275.64 -2.00 20.00 -2.00 499.60 0.00e+00 2.356405e+00 1.037509e+00 7.450660e-02 -6.000000e+00 1.012810e+00 219.53 -2.00 3.76 -2.00 501.24 0.00e+00 19.163 0.083 489.00 513.00 1 7.8663e+00 7.9520e-02 3.0457e-02 -6.0000e+00 7.7273e-02 1.4623e-01 2.0294e-02 2.3486e-03 -6.0000e+00 2.0438e-02 4.0055e-05 2.5438e-03 4.2363e-03 8.7566e-05 -6.0000e+00 4.7392e-03 9.7987e-03 -2.0888e-04 12 8 8 10 0 0 68.56 21.99 -1.21 0.00980 0.02744 8 2 1 4 0 4000.000 26.11 20.00 21.99 -4587 -2399 -1060 2295 -3859 2652 52 555 7470 -6162 -3295 6148 1864 3720 -3444 -4098 3093 3804 2529 -759 -2366 -767 -9029 4360 1537 3326 -2428 4804 -3154 416 -1623 6531 -2042 3862 81 2066 5848 -7894 -2076 5838 9230 -3831 5941 11249 3594 98 -8230 6353 -134 2508 -9821 3184 4125 -2136 1396 264 3304 -8041 -3017 594 3315 -5826 -1468 -3684 842 2360 3437 -787 -1079 -1536 -4184 3927 2409 -8091 5299 -4144 3594 -2185 11256 -1304 2693 7450 914 -2331 2297 -4280 -2119 -9021 -1237 -3468 3265 -8116 4077 -6073 6553 -1209 -3035 5387 1384 6367 461 -15250 -462 238 -8812 8285 273 1580 498 9415 -832 -3290 3062 712 9465 -563 -3971 828 -3286 8180 10325 12154 3550 13878 -2715 -4617 1843 2595 -12081 5584 10132 5783 -5789 7644 -965 3380 3133 5057 -3759 4151 1192 -450 -1416 3847 -6949 -3732 -5747 -1307 -2937 -2784 -5031 -2621 -1185 2573 -4723 3104 64 682 8531 -7333 -3746 6794 1951 3766 -3721 -4475 3190 3996 2762 -866 -2744 -876 -11188 4744 1730 3682 -2835 5155 -3563 436 -1704 6341 -2207 4086 92 2310 6231 -9513 -2329 5999 9171 -4371 6217 11305 3938 111 -10106 6648 -147 2605 -11169 3091 3912 -2171 1408 278 3458 -9509 -3385 640 3469 -6713 -1625 -4162 900 2444 3454 -811 -1101 -1550 -4284 3709 2330 -8803 5085 -4337 3408 -2146 9526 -1242 2462 6530 860 -2281 2169 -4349 -2106 -9543 -1201 -3433 3034 -8555 3851 -6333 5892 -1137 -2809 4436 1156 4955 378 -13803 -374 201 -8470 6801 242 1358 428 7432 -739 -3036 2675 640 7803 -515 -3803 764 -3159 6916 8367 9466 2976 10516 -2447 -4260 1597 2230 -11994 4642 7998 4687 -5179 5926 -816 2775 2638 4258 -3508 3626 1083 -419 -1336 3455 -6948 -3588 -5545 -1178 -2637 -2481 SO 20190624T122824.0Z 7114.519722 281 1 32.01 2 88.51 53.38 50.52 309.29 0.00 1 0.00 1 0 15 4.457e-02 4.291e-02 3.780e-02 3.691e-02 3.682171e+03 2.312920e+03 1.192668e+02 -6.000000e+00 2.340727e+03 275.64 -2.00 20.00 -2.00 505.11 0.00e+00 1.184375e-03 9.978164e-04 7.299600e-05 -6.000000e+00 1.216699e-03 275.64 -2.00 20.00 -2.00 499.61 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