File name: Pandora124s1_ComodoroRivadavia_20190627_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T083927.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190627_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190627T121921.0Z 7117.513438 380 1 32.00 2 89.81 55.18 53.03 355.54 0.00 1 0.00 1 0 39 1.753e-01 1.535e-01 1.668e-01 1.535e-01 1.144441e+04 1.146798e+04 7.959965e+02 -6.000000e+00 9.204978e+03 275.56 -2.00 20.00 -2.00 505.29 0.00e+00 6.584922e-03 4.152197e-03 3.972198e-04 -6.000000e+00 4.777604e-03 275.56 -2.00 20.00 -2.00 499.74 0.00e+00 6.425979e+00 3.215553e+00 8.289322e-02 -6.000000e+00 3.392665e+00 219.60 -2.00 3.76 -2.00 501.39 0.00e+00 20.425 0.100 489.00 513.00 1 8.4367e+00 2.4644e-01 3.4207e-02 -6.0000e+00 2.5939e-01 6.5326e-02 6.1965e-02 2.4708e-03 -6.0000e+00 6.7614e-02 1.2743e-05 -8.4966e-03 1.2722e-02 1.4135e-04 -6.0000e+00 1.5964e-02 -9.0889e-02 1.2318e-03 12 8 8 10 0 0 93.48 21.41 18.60 -0.09089 -0.14982 8 2 1 4 0 4000.000 25.58 19.97 21.41 16281 29046 5062 -15828 22352 20673 -14810 7800 -11529 25486 1486 -6128 -1687 3625 -20627 -11669 12583 18858 -19448 -2536 -1607 36566 4871 20409 -8092 3714 15231 -1178 -5389 -7949 4491 7596 373 -7574 -16479 15721 -1418 6523 5460 11788 11285 -4125 -1644 -10285 20091 -15087 11530 3720 -11675 28269 15914 8672 13998 -7161 70458 -22685 7161 -8257 32835 -18704 35305 -2823 -3653 -7018 4561 25171 43827 3259 -18445 20789 14414 -24717 8981 -18499 13853 -3995 -6443 14224 11492 -13995 32873 5598 25217 2446 12040 21896 -3484 -16562 9156 6259 16504 15194 -4904 22699 -20931 -14952 -3184 22866 9037 11658 8198 -20116 -11483 23327 15302 7359 -22414 9144 -2810 14668 3184 29112 -5910 26230 -20199 10825 -9796 13164 -24700 -3298 -12835 18543 7274 47501 29366 13943 579 18731 875 27790 -8939 3170 -14979 30019 -5880 -398 -395 26003 -15923 -7701 -10775 -17648 -6533 22877 14901 17727 -13296 11037 6006 20833 14696 23670 5458 -20149 19917 19140 -19882 8394 -14943 22416 1634 -7163 -1855 3734 -26974 -14045 12086 17459 -27008 -2993 -1878 29198 5355 19367 -10301 4212 15335 -1377 -6361 -9291 4574 7559 410 -9378 -22884 15828 -1673 7020 5876 11868 11493 -4965 -1959 -13569 19763 -21127 12276 4219 -15133 23882 14733 8430 12798 -8205 38323 -32291 7707 -10415 27360 -25975 28600 -3365 -4397 -8690 4962 21847 30939 3394 -23481 17563 12844 -32609 8523 -23336 12665 -4299 -6934 12181 9974 -15549 22826 5118 18969 2321 10450 17231 -3257 -17442 7380 5179 12415 11756 -4690 16343 -22718 -14782 -2703 14497 6409 7892 5726 -19023 -10365 15542 11346 5931 -24086 7075 -2446 10876 2703 19396 -5652 18321 -22574 8957 -10106 10892 -29728 -3154 -13241 13749 6019 26543 19881 11087 529 14291 799 19411 -8934 2760 -15452 19678 -5561 -364 -369 19001 -17967 -8110 -11811 -20861 -6950 18192 12810 14668 -14717 9370 5293 15895 SO 20190627T122321.0Z 7117.516215 384 1 32.00 2 89.24 54.46 53.11 354.33 0.00 1 0.00 1 0 15 1.525e-01 1.369e-01 1.236e-01 1.171e-01 1.662906e+04 8.629876e+03 1.211769e+03 -6.000000e+00 8.005173e+03 275.56 -2.00 20.00 -2.00 505.19 0.00e+00 -5.740523e-03 3.176447e-03 4.112808e-04 -6.000000e+00 4.165547e-03 275.56 -2.00 20.00 -2.00 499.90 0.00e+00 -3.738651e+00 2.339117e+00 1.115623e-01 -6.000000e+00 2.986919e+00 219.60 -2.00 3.76 -2.00 501.54 0.00e+00 19.385 0.085 489.00 513.00 1 9.2310e+00 1.7987e-01 3.2884e-02 -6.0000e+00 2.2784e-01 2.1967e-01 4.6003e-02 3.0431e-03 -6.0000e+00 6.0342e-02 1.6846e-05 1.2908e-02 9.0591e-03 1.5734e-04 -6.0000e+00 1.3960e-02 3.3657e-02 -4.3084e-04 12 9 8 11 8 0 56.58 21.41 -0.97 0.03366 0.12320 8 2 1 4 0 4000.000 25.58 20.03 21.41 17920 -19656 8877 -15270 -137 -5925 24430 4870 5868 4500 -798 -3024 -6250 4398 2627 16791 20190 -16535 7326 3090 19512 -4610 -4042 -13108 6912 7144 2174 4310 -10130 20278 -1755 26351 -7648 20971 -1164 20575 -15082 8659 -5085 2867 -10626 -8712 -19255 13490 5907 17137 -14925 15248 -10874 -2812 32 8236 -4434 2066 933 -2922 3822 8524 -3878 6837 1901 -827 22622 19242 13185 -2703 85 -6899 12912 18133 -7410 -10409 23051 -13177 9074 3198 2915 -4083 8908 -14848 11667 -13506 23875 -21942 29913 -11058 -4684 -15512 12055 -12616 45074 5945 8399 -12683 1988 -10914 29869 13948 14518 -18257 1607 -11594 6205 8748 33867 6751 26498 27946 -17474 11393 -19912 26871 26285 33285 -27408 25805 -11735 -5508 -6061 10990 -10221 48403 -13318 18163 -6642 27023 2370 7300 3891 11005 -16768 9420 -6891 13237 -3503 26522 2654 23352 -3109 10780 -11832 17406 -6935 25984 9377 -12593 -14478 -9593 -2631 4550 15595 -25565 8999 -18737 -159 -6904 23130 5202 6165 4728 -873 -3337 -7008 4387 2667 14971 17823 -21749 7761 3437 18430 -5535 -4818 -17125 7383 7568 2399 4566 -11984 17185 -1843 21169 -8912 19068 -1346 19071 -19705 8790 -5835 3012 -12757 -10305 -25497 12981 6154 15884 -18841 13999 -12671 -2929 32 7271 -4423 1970 931 -3121 3880 8277 -4245 6700 1964 -884 19172 16817 12106 -2863 87 -7430 11285 14887 -7850 -11486 18518 -15471 8571 3162 2831 -4181 7942 -16778 10196 -15380 18969 -28087 23238 -13081 -5210 -17802 11281 -14064 30638 5604 7711 -14036 1825 -10915 19098 10176 10353 -17959 1317 -11310 5392 7888 24708 6530 20852 21305 -20769 10180 -24483 20705 20254 23738 -35723 19884 -13371 -5959 -6559 9819 -10976 28171 -14192 14144 -6642 19272 2156 6283 3445 9021 -17869 7568 -6440 10091 -3188 18262 2371 17228 -3032 9278 -12899 14268 -7276 19596 8302 -13730 -15785 -9751 -2459 3954 SO 20190627T122719.0Z 7117.518970 388 1 32.00 2 88.68 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