File name: Pandora124s1_ComodoroRivadavia_20190716_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084452.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190716_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190716T121159.0Z 7136.508322 292 1 32.00 2 89.81 58.28 93.17 234.36 0.00 1 0.00 1 0 33 1.529e-01 1.360e-01 1.376e-01 1.294e-01 -1.840492e+04 7.286375e+03 1.410333e+03 -6.000000e+00 8.011897e+03 275.02 -2.00 20.00 -2.00 505.17 0.00e+00 -2.308563e-03 3.450002e-03 2.352614e-04 -6.000000e+00 4.171938e-03 275.02 -2.00 20.00 -2.00 499.59 0.00e+00 6.439993e+00 2.654775e+00 1.642652e-01 -6.000000e+00 2.998863e+00 220.14 -2.00 3.76 -2.00 501.31 0.00e+00 20.433 0.100 489.00 513.00 1 8.4543e+00 2.0135e-01 3.5422e-02 -6.0000e+00 2.2868e-01 1.1347e-01 5.3312e-02 3.9784e-03 -6.0000e+00 6.0586e-02 1.5204e-05 1.4212e-02 1.0746e-02 2.6983e-04 -6.0000e+00 1.3994e-02 -1.4488e-02 -1.5322e-04 12 8 8 10 0 0 83.75 22.30 12.07 -0.01449 0.08409 8 2 1 4 0 4000.000 26.32 20.00 22.30 -12591 26517 -3303 27414 -20272 20662 -6775 -7084 -10883 8684 -12769 1510 48395 -83 -8650 -8263 -11479 1366 5237 2413 5056 14047 -6334 -8251 21390 11353 -3163 1485 7887 259 -5638 22927 7646 5923 -8578 8082 3114 -9075 14900 32710 -13719 17615 -21122 9359 677 13804 434 9561 -12286 -8151 -3519 3872 3184 -7714 16533 -16365 263 -17407 -4998 4478 -279 -2796 10546 2829 8265 -3476 2467 17392 15793 21608 17236 26829 962 1174 7620 20042 3882 11436 14549 10 -10029 -7250 40669 7183 -11179 -11538 15952 -18924 -11832 15189 19662 -876 9227 10206 -8212 -5036 14417 13985 -7342 22260 20720 27810 -19751 -4177 -13806 29898 -6868 4195 -16066 16204 -13588 14457 9841 15201 11982 -14701 -3561 -399 10673 10491 -6944 -729 -10891 10511 7317 2935 -5058 23910 17059 160 -34376 24506 -30425 -2618 -7988 -3308 -3421 13554 57598 10674 -13286 5547 -6713 28147 32388 -6258 12774 3037 983 -8839 -15303 22419 -3910 24625 -27685 20744 -8393 -8845 -14014 9064 -16317 1650 32575 -90 -10210 -9834 -14445 1559 5875 2801 5721 14525 -8033 -10705 20658 12072 -3857 1695 8156 281 -6435 19905 7980 6529 -11129 8831 3524 -11420 14535 26484 -17666 16668 -29671 9768 773 13735 487 9607 -14981 -9223 -3673 3664 3012 -8278 14354 -20275 280 -22075 -5558 4500 -294 -3027 9979 2871 7821 -3628 2382 14251 12941 16441 13619 19367 910 1123 6839 15641 3484 9371 11496 9 -10273 -7285 25390 6306 -11886 -12381 13071 -20570 -12111 12891 16111 -833 8107 9060 -8927 -5383 12667 12035 -7582 16736 15766 19901 -23079 -4200 -15007 20312 -6533 3496 -16300 12036 -13908 11524 8469 12668 10420 -16646 -3549 -376 8798 8552 -6730 -667 -11148 8760 6296 2632 -4902 17327 13289 148 -44529 17314 -36379 -2324 -7453 -2996 -3192 10927 30261 8992 -14201 4924 -6811 20397 22590 -6349 10414 2641 855 -8487 SO 20190716T121600.0Z 7136.511111 296 1 32.00 2 89.21 57.56 93.72 233.64 0.00 1 0.00 1 0 15 1.154e-01 1.054e-01 1.073e-01 1.020e-01 -3.348897e+03 5.966261e+03 7.558463e+02 -6.000000e+00 6.045416e+03 275.02 -2.00 20.00 -2.00 505.18 0.00e+00 -2.029636e-04 2.750633e-03 5.370233e-05 -6.000000e+00 3.146683e-03 275.02 -2.00 20.00 -2.00 499.50 0.00e+00 6.475930e+00 2.095295e+00 8.435203e-02 -6.000000e+00 2.260159e+00 220.14 -2.00 3.76 -2.00 501.20 0.00e+00 19.333 0.085 489.00 513.00 1 8.3159e+00 1.6098e-01 3.0443e-02 -6.0000e+00 1.7239e-01 9.2771e-02 4.1448e-02 1.8066e-03 -6.0000e+00 4.5600e-02 1.9356e-05 5.7740e-04 8.7718e-03 8.9999e-05 -6.0000e+00 1.0567e-02 3.2182e-02 -3.2595e-04 12 8 8 10 0 0 53.03 22.30 -1.82 0.03218 0.03619 8 2 1 4 0 4000.000 26.32 19.99 22.30 7245 -5883 -4546 -3553 13990 -18065 13487 -7278 -354 -13359 12563 -6916 9736 -5282 4729 -12539 294 -1146 2378 -4649 20079 -3139 6074 1650 4815 -6024 -5265 -3258 -2027 -16290 29135 -169 9148 8372 -3292 -10360 -4783 9866 34038 -1161 14510 -4987 18157 13658 1564 12239 12183 10648 -1384 13669 -23905 -8634 8667 865 -2675 -4545 -4362 -8213 1663 23428 5696 2217 8396 15305 -8070 14124 -6390 7842 -15169 556 -3168 9913 -4145 42692 -554 11129 15364 7614 -1488 14815 -19904 2938 -3984 -8200 515 -2017 9901 2909 -3601 -5667 1114 614 10465 3791 6770 -4503 -6696 -10529 29004 -3366 -1971 7833 5747 -5882 21377 -2658 12558 11397 -4744 -9309 -4705 -10382 4906 4759 10775 2198 3250 -925 -1183 -15097 -2571 31954 28334 -16471 1575 13998 6913 2633 -8348 -2767 -11973 24482 7331 9515 10800 -16717 1017 -5179 -1816 -2126 -14892 5235 7546 -3900 -17474 7116 -5890 15800 2925 -457 7183 -6764 -5341 -4293 14570 -24454 14721 -9124 -414 -17569 12560 -8298 9735 -6052 4873 -15430 324 -1313 2707 -5757 19458 -3839 6774 1929 5481 -7644 -6600 -3959 -2370 -21174 23528 -183 9217 8821 -4026 -13705 -5922 10395 27749 -1330 14172 -5945 17316 13761 1793 12613 12462 10892 -1564 12931 -31807 -9563 7932 858 -2818 -5033 -4931 -9727 1778 20001 5783 2336 8330 14125 -9310 12818 -6979 7298 -17500 538 -3143 8615 -4176 27253 -549 9758 12644 6617 -1396 11736 -22350 2644 -3861 -8325 483 -1955 8529 2685 -3545 -5710 1054 590 9256 3357 5802 -4278 -6408 -10227 18435 -2885 -1647 5986 4597 -5461 15420 -2430 9686 8709 -4201 -8643 -4234 -10083 4169 4113 8849 1978 2901 -859 -1090 -15741 -2332 20310 18616 -17057 1372 10796 5727 2275 -8049 -2530 -11971 16785 5864 7339 8176 -16834 879 -4882 -1686 -2004 -16060 4636 6575 -3844 -19842 6302 -5847 12299 2527 -405 SO 20190716T121958.0Z 7136.513866 300 1 32.00 2 88.63 56.84 94.26 232.94 0.00 1 0.00 1 0 15 1.020e-01 9.738e-02 9.420e-02 9.020e-02 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