File name: Pandora124s1_ComodoroRivadavia_20190719_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084508.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190719_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190719T120933.0Z 7139.506632 246 1 32.00 2 89.81 59.10 74.65 263.40 0.00 1 0.00 1 0 15 8.251e-02 8.072e-02 7.389e-02 7.139e-02 5.868533e+03 4.786652e+03 4.919166e+02 -6.000000e+00 4.322735e+03 274.98 -2.00 20.00 -2.00 505.14 0.00e+00 6.766926e-04 1.910406e-03 2.688618e-05 -6.000000e+00 2.251037e-03 274.98 -2.00 20.00 -2.00 499.59 0.00e+00 3.099502e+00 1.466741e+00 3.257939e-02 -6.000000e+00 1.619243e+00 220.45 -2.00 3.76 -2.00 501.25 0.00e+00 20.431 0.100 489.00 513.00 1 8.0200e+00 1.1230e-01 3.2349e-02 -6.0000e+00 1.2346e-01 1.4970e-01 2.9122e-02 1.9939e-03 -6.0000e+00 3.2724e-02 2.7919e-05 -1.3796e-03 6.2330e-03 4.5313e-05 -6.0000e+00 7.5500e-03 -2.7281e-02 -1.0166e-04 12 8 8 10 0 0 -188.54 21.86 8.03 -0.02728 -0.03685 8 2 1 4 0 4000.000 25.90 20.00 21.86 1311 -2222 20807 4598 -7683 -12183 -3478 -6139 4771 -11218 20952 3229 -799 4162 1108 5830 8028 2926 10994 -5536 -6907 -10345 9033 -1932 -8467 4960 -5499 2381 1736 10546 5410 6520 992 5802 -3121 11716 -1565 -9194 -1135 4487 11380 16193 -3515 -2428 -15262 2389 8953 -4834 -11899 1063 -8944 15822 4783 3868 901 10817 -10792 10488 -373 13353 125 860 -4578 -3620 10102 11984 -5241 -1478 -6974 10640 -6411 -2654 -3642 5827 -4384 4716 5280 -4242 8340 825 -1685 -10873 1195 -6523 20946 -7161 15615 -7603 9207 -4716 991 -10764 -52 -6212 11704 8774 14940 -14277 9106 9414 -6632 -13979 -2118 -4768 14910 7332 -518 -11523 2649 -3986 10071 4340 -1153 7638 7495 -69 11499 1409 2036 1525 264 -15062 -6848 9777 -7303 4873 1499 11689 1209 10096 10499 -7490 -2155 1186 -8524 -434 -2371 13216 551 265 -4055 7591 -2847 7556 -16949 4750 -7077 10636 -1144 3807 1368 -2422 18557 5012 -9763 -15274 -4079 -7498 5237 -14305 20640 3458 -877 4278 1162 5834 7948 3117 11122 -6732 -8548 -13248 9527 -2277 -10706 5498 -6747 2677 1924 10327 5414 6420 1046 6025 -3678 12103 -1835 -11478 -1289 4756 11206 15248 -4067 -2809 -20284 2674 9346 -5722 -14854 1138 -10251 13707 4529 3684 902 10127 -12891 10270 -408 12645 135 921 -5197 -4071 9838 11285 -5753 -1535 -7543 9504 -6692 -2656 -3704 5456 -4600 4517 4943 -4268 7270 768 -1605 -11408 1119 -6634 16342 -7475 13023 -7978 8125 -4770 949 -11699 -51 -6585 10265 7743 12058 -13910 6825 6867 -5600 -12782 -1767 -4264 11398 6154 -468 -11458 2250 -3604 8001 3708 -1054 6450 6366 -63 9480 1295 1861 1387 239 -15578 -6433 7767 -6932 4115 1310 9227 1057 8071 8341 -7036 -1884 989 -7794 -369 -2097 10235 493 241 -3890 6523 -2731 6569 -18885 4249 -7037 8662 -1023 3196 SO 20190719T121336.0Z 7139.509445 250 1 32.01 2 89.20 58.37 75.34 262.73 0.00 1 0.00 1 0 15 6.260e-02 6.126e-02 5.408e-02 5.247e-02 8.015818e+03 3.591429e+03 6.862267e+02 -6.000000e+00 3.279366e+03 274.98 -2.00 20.00 -2.00 505.11 0.00e+00 2.331047e-03 1.406904e-03 1.076221e-04 -6.000000e+00 1.705385e-03 274.98 -2.00 20.00 -2.00 499.60 0.00e+00 1.791598e+00 1.086590e+00 2.537547e-02 -6.000000e+00 1.223103e+00 220.45 -2.00 3.76 -2.00 501.25 0.00e+00 19.308 0.084 489.00 513.00 1 7.9379e+00 8.3143e-02 3.0059e-02 -6.0000e+00 9.3344e-02 1.6895e-01 2.1544e-02 1.8612e-03 -6.0000e+00 2.4594e-02 3.8215e-05 -3.1111e-03 4.4797e-03 8.0828e-05 -6.0000e+00 5.7280e-03 -5.5438e-03 1.3643e-04 12 9 8 11 8 0 29.79 21.86 2.11 -0.00554 -0.02712 8 2 1 4 0 4000.000 25.90 20.00 21.86 7091 -3871 -2665 -6516 2160 -2929 -407 -4948 9918 -699 -2434 -2140 6167 5839 826 -8640 8419 6919 980 2832 -6387 -2466 7881 5978 5447 906 -924 675 -5917 1094 -5508 7027 -9248 2664 73 6535 -6048 -2749 146 4417 -7411 10624 1814 3796 -1249 2150 1157 -2681 -5258 704 -5538 11702 -14794 14004 -9695 8353 -7182 4155 237 9297 -3286 444 -3853 6280 3793 3253 995 147 9814 4423 3663 -15646 1259 3362 5045 -3200 1030 -1184 -5401 -1669 4743 1015 1550 -304 11597 -10524 10472 10388 -1388 -3586 -5468 -1074 6885 3540 -3484 187 10040 -4745 4706 -2573 6644 -7290 -342 -5548 4984 -10070 5138 1798 -1440 203 -2043 -116 -5404 11901 -4889 -1723 6514 8139 -8267 1009 -6920 8553 -2900 3701 11203 9660 4826 -6461 -4782 4733 -12842 8204 -12587 4888 -3681 10744 3257 3862 1030 2625 -10591 3111 1119 11214 -6013 6484 -8522 -2375 7191 1967 6987 -4328 -3048 -8039 2507 -3651 -504 -6465 11132 -860 -2763 -2387 6737 5818 859 -9907 8256 7059 1089 3125 -7728 -2866 8259 6406 5901 1028 -1063 755 -6879 1142 -6011 6780 -10715 2845 83 6977 -7247 -3141 159 4594 -8674 10460 1973 4098 -1432 2389 1291 -3064 -6051 743 -6023 10412 -16906 12072 -10888 8092 -8321 4337 256 9154 -3664 479 -4357 6406 3929 3332 1023 150 8965 4198 3462 -17942 1230 3257 4848 -3315 1002 -1152 -5403 -1597 4258 951 1453 -292 9997 -11403 9193 9078 -1355 -3573 -5579 -1062 6370 3388 -3513 177 8337 -4428 3890 -2078 5228 -6210 -282 -5032 4210 -9983 4339 1545 -1264 176 -1838 -104 -5159 9614 -4685 -1607 5645 6993 -8348 915 -6657 6909 -2599 3112 8803 7733 4058 -6073 -4407 3962 -12732 6476 -12016 3877 -3176 8127 2715 3262 908 2304 -10695 2753 1015 9223 -5873 5547 -8323 -2128 5729 1640 SO 20190719T121732.0Z 7139.512176 254 1 32.00 2 88.62 57.66 76.01 262.07 0.00 1 0.00 1 0 22 4.448e-02 4.312e-02 4.176e-02 4.076e-02 4.456493e+03 2.581841e+03 4.777256e+02 -6.000000e+00 2.330128e+03 274.98 -2.00 20.00 -2.00 505.11 0.00e+00 -2.079559e-04 1.085984e-03 2.708759e-05 -6.000000e+00 1.212350e-03 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