File name: Pandora124s1_ComodoroRivadavia_20190729_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084447.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190729_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190729 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190729T115924.0Z 7149.499583 455 1 32.00 2 89.78 62.31 74.26 29.99 0.00 1 0.00 1 0 22 1.058e-01 9.972e-02 9.100e-02 8.760e-02 2.655526e+03 5.391154e+03 3.586091e+02 -6.000000e+00 5.542259e+03 274.86 -2.00 20.00 -2.00 505.14 0.00e+00 5.828876e-03 2.326857e-03 3.174534e-04 -6.000000e+00 2.882485e-03 274.86 -2.00 20.00 -2.00 499.75 0.00e+00 7.277757e-01 1.799661e+00 4.677790e-02 -6.000000e+00 2.072913e+00 221.49 -2.00 3.76 -2.00 501.38 0.00e+00 20.387 0.099 489.00 513.00 1 8.3373e+00 1.3771e-01 3.3197e-02 -6.0000e+00 1.5813e-01 2.0225e-01 3.5990e-02 1.7969e-03 -6.0000e+00 4.1736e-02 2.2636e-05 1.6473e-03 7.8215e-03 1.1521e-04 -6.0000e+00 9.6875e-03 -6.8783e-03 5.9389e-05 12 8 8 10 0 0 -388.45 21.54 10.32 -0.00688 0.00455 8 2 1 4 0 4000.000 25.68 19.97 21.54 41173 -3474 232 -5812 16897 9431 77 -9839 -11644 11393 -2296 -387 -12086 -3778 -7453 -13377 -1504 849 7456 8775 1713 5895 -13959 -5366 19200 1234 3161 529 15746 4361 -706 -8870 13756 21283 -6726 1612 3457 9782 -16595 7402 -1022 -4590 -7100 23914 3008 14688 -5402 4937 2433 -236 -262 8722 -8715 14740 -18085 11688 -1410 16075 -5997 9436 -3965 -3914 -66 1479 -8230 -7149 -8395 -17612 3434 2502 16545 19081 1227 -127 7137 17760 3385 1410 2364 4709 4906 -10347 15538 -17764 12910 -11980 283 6617 8301 3399 2095 1057 8281 -5458 18954 -7645 5181 -4466 10014 -15471 23798 -8917 5157 2086 -7839 2366 4372 10078 10141 -21088 10025 -3234 16057 -2260 350 5523 -4836 -6019 5781 -11069 7117 4903 -3755 -14247 -14156 14816 -1562 19395 11361 8305 5277 1967 -8097 5923 1806 5872 5675 23298 -11366 9346 -5316 2025 960 -3997 -7262 2799 19493 -1626 8658 -19252 29155 -3926 262 -7233 17162 10523 88 -12537 -14991 11433 -2592 -421 -14523 -4116 -8366 -15986 -1619 913 7679 8980 1877 6189 -17880 -6342 17875 1376 3443 583 14451 4319 -723 -9897 12534 18689 -8038 1777 3698 9688 -21147 7379 -1113 -5243 -8438 21157 3317 14450 -6456 5248 2603 -253 -271 8062 -9494 12847 -22568 11190 -1574 15177 -7048 9470 -4555 -4522 -74 1621 -9835 -8308 -9700 -21978 3424 2478 14092 15874 1232 -131 6879 15243 3285 1368 2248 4353 4535 -11204 13029 -20877 11251 -13447 280 6117 7508 3232 2033 978 7260 -5521 14874 -7687 4479 -4135 7797 -15176 15612 -8200 4237 1829 -7738 2103 3752 8033 8021 -23014 8175 -3073 12798 -2189 333 5011 -4892 -6162 5210 -11604 6109 4238 -3522 -14936 -14927 11718 -1456 14625 9264 6976 4530 1712 -7645 4793 1517 4788 4732 16569 -11568 7792 -5149 1825 877 -3847 -7212 2488 14341 -1435 6741 -19711 SO 20190729T120359.0Z 7149.502766 459 1 32.00 2 89.08 61.48 73.88 29.00 0.00 1 0.00 1 0 22 6.066e-02 5.854e-02 5.444e-02 5.307e-02 6.734217e+03 3.642227e+03 6.380379e+02 -6.000000e+00 3.176511e+03 274.86 -2.00 20.00 -2.00 505.17 0.00e+00 2.678141e-03 1.418157e-03 2.412687e-04 -6.000000e+00 1.653158e-03 274.86 -2.00 20.00 -2.00 499.79 0.00e+00 1.761450e+00 1.095687e+00 3.879230e-02 -6.000000e+00 1.190400e+00 221.49 -2.00 3.76 -2.00 501.42 0.00e+00 19.005 0.080 489.00 513.00 1 7.9882e+00 8.3746e-02 2.9944e-02 -6.0000e+00 9.0771e-02 1.4502e-01 2.1685e-02 1.7806e-03 -6.0000e+00 2.4025e-02 3.7817e-05 -1.7140e-03 4.5999e-03 9.5358e-05 -6.0000e+00 5.5537e-03 1.0649e-02 -2.1526e-04 12 8 8 10 0 0 27.19 21.54 0.95 0.01065 -0.00124 8 2 1 4 0 4000.000 25.68 20.03 21.54 -9452 4395 3418 7286 6889 2003 -2569 3212 -2571 -5242 6936 6672 1093 1044 933 -2047 1469 -8332 3422 -3738 8161 -3631 7313 -7768 -982 -3817 3320 -5039 -3234 -4043 -1035 -1592 1219 2435 2614 -3902 6126 -3290 -1039 532 6552 11279 -1085 5027 1741 -6436 8968 2099 -1448 4816 -687 -932 8154 -1756 -4763 -4371 -218 -5063 -3984 -4779 11824 -978 -12839 5531 -7905 11364 -5642 4563 1599 -8700 -2022 7335 -1486 981 -11416 5930 2036 6596 6374 -1701 17266 6933 -2679 3717 498 3053 5748 -77 2635 8015 -8732 -2199 -11507 5653 1983 -1630 -5235 118 2687 16774 7209 -3698 -5139 -3332 -5259 -3859 2019 -766 13461 2600 7980 -944 -4711 1670 7552 -5563 177 -175 -223 -11026 -1368 -5637 4084 -2514 8002 -8670 2134 -8560 13771 124 8744 -1712 -3179 8718 8254 6339 4854 -254 -5453 -694 4661 -4301 410 448 5828 -1448 -11440 8300 -3771 14031 -10730 4399 3570 7609 7433 2318 -2929 3786 -2962 -6122 7047 6698 1141 1073 951 -2153 1510 -9665 3627 -4321 8389 -4197 7575 -9383 -1116 -4473 3612 -5905 -3635 -4415 -1068 -1650 1248 2552 2833 -4573 6444 -3750 -1143 570 6604 10917 -1202 5308 1922 -7749 9218 2283 -1605 4892 -714 -943 7404 -1762 -5048 -4773 -235 -5791 -4509 -5429 11350 -1072 -15919 5708 -9264 10818 -6251 4489 1599 -9500 -2038 6719 -1498 977 -13013 5669 1987 6016 5736 -1646 13812 6184 -2647 3464 484 2918 5357 -75 2508 7213 -9326 -2226 -12979 5404 1943 -1501 -4860 101 2176 11525 5381 -3104 -4504 -2995 -5000 -3669 1800 -691 10399 2240 6609 -870 -4567 1532 6564 -5537 168 -168 -214 -11630 -1286 -5422 3519 -2316 6687 -8598 1902 -8489 10894 112 7242 -1551 -2869 6897 6530 5156 4092 -230 -5286 -650 4172 -4234 386 425 5238 -1393 -11982 6967 -3487 10735 SO 20190729T120833.0Z 7149.505937 463 1 32.00 2 88.38 60.66 73.52 28.00 0.00 1 0.00 1 0 15 4.093e-02 4.157e-02 3.873e-02 3.807e-02 3.221640e+03 2.376450e+03 1.646246e+02 -6.000000e+00 2.143401e+03 274.86 -2.00 20.00 -2.00 505.18 0.00e+00 3.620914e-03 1.017467e-03 1.784538e-04 -6.000000e+00 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