File name: Pandora124s1_ComodoroRivadavia_20190730_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084448.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190730_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190730T115812.0Z 7150.498750 484 1 32.00 2 89.78 62.67 80.84 42.36 0.00 1 0.00 1 0 15 1.406e-01 1.301e-01 1.087e-01 1.021e-01 3.196683e+02 6.079674e+03 4.622945e+02 -6.000000e+00 7.364806e+03 274.84 -2.00 20.00 -2.00 505.16 0.00e+00 7.878726e-03 2.733151e-03 4.943452e-04 -6.000000e+00 3.827937e-03 274.84 -2.00 20.00 -2.00 499.58 0.00e+00 6.196516e+00 2.098342e+00 1.400771e-01 -6.000000e+00 2.746308e+00 221.59 -2.00 3.76 -2.00 501.21 0.00e+00 20.385 0.099 489.00 513.00 1 8.0604e+00 1.6069e-01 3.5612e-02 -6.0000e+00 2.0963e-01 1.1117e-01 4.1296e-02 2.4606e-03 -6.0000e+00 5.5099e-02 1.9243e-05 3.5408e-03 8.6692e-03 1.6209e-04 -6.0000e+00 1.2855e-02 -4.8533e-02 5.5358e-04 12 8 8 10 0 0 -158.77 21.40 9.90 -0.04853 -0.02397 8 2 1 4 0 4000.000 25.58 19.98 21.40 2739 18282 -4165 2675 -13189 28160 -20568 31296 -11640 11656 -2190 11319 -2889 -4034 -14133 40897 -9679 2182 -5403 10671 565 21566 -1719 5278 -4566 23658 -14691 112 -10038 10880 -9676 9545 -8724 11776 5694 4538 -2898 14433 18304 5802 991 -4247 -8925 2743 6318 2853 10200 -11094 13104 -16925 14204 -13469 24129 -14559 674 -18657 17116 -14606 17662 -12509 19124 -11848 28071 -1872 30333 -1395 32100 1434 8184 4005 3142 -6396 13198 -4738 16532 -18771 21617 2011 12131 -4254 -5651 4987 7456 -6103 14303 4408 -8146 8980 -7141 7825 -16090 30201 -11193 -10234 -21282 3973 7660 5586 -7570 22182 -20387 39844 17145 17598 -144 13878 -23522 11662 707 5178 -9710 12766 -4518 10792 -2969 17745 -7167 4603 8313 4186 -20770 486 10400 4562 -17180 9990 1829 3501 3746 18759 10370 -6980 11478 12381 8987 -3574 6031 -5720 21551 -8880 23524 -8960 14278 -7928 20887 -12908 23761 -2833 -14040 -12789 2901 17075 -5071 3146 -17158 26770 -29765 29230 -15232 11843 -2512 11152 -3225 -4503 -17407 29278 -11697 2402 -6530 11007 644 19920 -2011 5810 -5589 21854 -19790 128 -12208 10385 -11247 9257 -10476 11966 6268 5030 -3413 14110 17048 6119 1107 -5067 -11336 3146 7052 3294 10835 -14346 13012 -22018 13120 -16070 19688 -17819 732 -25275 16469 -19338 16859 -16081 17959 -15230 24201 -2162 24983 -1546 24957 1490 7812 3916 3072 -6892 11785 -5106 14380 -22830 17139 1904 10272 -4224 -5698 4530 6600 -6202 11891 4038 -8402 7742 -7201 6806 -16676 21620 -11441 -10388 -23883 3408 6187 4472 -6709 14270 -19964 21644 12010 12579 -123 10218 -24716 8502 576 4108 -9162 9855 -4231 8794 -2801 13699 -7121 4046 6952 3590 -22566 424 8251 3881 -18297 8140 1621 3053 3266 14079 8376 -6585 8860 9381 7066 -3245 5087 -5519 16020 -9014 17319 -9159 11634 -8103 15975 -13655 16984 -2572 -14050 -12707 SO 20190730T120247.0Z 7150.501933 488 1 32.00 2 89.07 61.85 80.32 41.47 0.00 1 0.00 1 0 15 7.094e-02 6.889e-02 6.383e-02 6.175e-02 9.897121e+03 4.443732e+03 8.875438e+02 -6.000000e+00 3.716194e+03 274.84 -2.00 20.00 -2.00 505.15 0.00e+00 4.857994e-03 1.658485e-03 2.575888e-04 -6.000000e+00 1.931846e-03 274.84 -2.00 20.00 -2.00 499.66 0.00e+00 2.696974e+00 1.285097e+00 4.140098e-02 -6.000000e+00 1.387563e+00 221.59 -2.00 3.76 -2.00 501.28 0.00e+00 18.996 0.080 489.00 513.00 1 8.0401e+00 9.8434e-02 3.0063e-02 -6.0000e+00 1.0589e-01 1.4395e-01 2.4988e-02 1.8886e-03 -6.0000e+00 2.7879e-02 3.2268e-05 8.2524e-03 5.1996e-03 1.3621e-04 -6.0000e+00 6.4908e-03 -4.0397e-02 4.0301e-04 12 9 8 11 8 0 57.29 21.41 -3.59 -0.04040 0.01685 8 2 1 4 0 4000.000 25.58 20.00 21.41 -11684 -2492 119 8136 978 9459 -5940 1554 4901 -6845 1849 8266 -8632 6023 3158 -330 -1730 8847 -9082 13865 -9043 7757 2412 -2584 3201 6019 -3101 834 -3717 13271 -4970 10739 7406 5665 -812 -3884 -5660 2531 -4331 -256 -5270 -3594 1525 -474 6009 2366 -391 -2477 1923 -2056 5845 -6505 -6548 -7290 4371 -6116 13185 -12333 9546 -1268 5583 2146 1728 -5575 12634 -2453 14420 -8217 688 -9191 -305 -4738 4654 5667 6863 -12005 4631 -1007 6994 -2376 5360 -3086 7719 14452 5669 -6696 -440 -11829 -2919 3120 2211 8809 -7689 2011 -4128 4118 -1247 8546 -5525 17804 7553 2781 -21735 -2903 -3067 9306 7924 6143 5216 -7120 -6710 -2120 -5004 11160 -3177 13080 -687 3321 -554 9866 -3648 16846 -2278 -8409 -4593 8068 -1834 -3913 -2544 10248 -3415 -2376 461 105 5730 -6695 580 3523 11483 1391 1989 1971 8173 2838 8175 -15008 5898 -12467 6710 -2817 -14020 -2815 136 8860 1169 10587 -7243 1757 5291 -8155 1988 8195 -9963 5943 3204 -350 -1900 8976 -11201 13616 -11153 8087 2660 -3018 3546 6471 -3623 916 -4117 12044 -5389 10096 7445 6011 -933 -4573 -6691 2721 -4938 -280 -6107 -4148 1697 -545 6516 2654 -446 -2836 2058 -2220 5658 -6993 -7039 -8075 4455 -7116 12825 -15497 9596 -1416 5847 2337 1890 -6512 12113 -2683 13087 -9216 694 -10094 -305 -4984 4505 5486 6548 -13577 4332 -980 6217 -2311 4840 -3044 6862 12107 5224 -6980 -428 -12772 -2866 2889 2089 7913 -8194 1918 -4073 3622 -1120 6761 -4560 11464 5419 2151 -22449 -2585 -2784 7440 6335 4938 4238 -6646 -6350 -1942 -4757 9067 -2993 10570 -644 2999 -515 8101 -3358 12449 -2038 -8068 -4268 6625 -1664 -3619 -2319 8193 -3084 -2084 388 88 4606 -6220 512 3060 9329 1262 1805 1797 7029 2576 6995 -15955 4971 -12338 5423 -2520 SO 20190730T120715.0Z 7150.505035 492 1 32.00 2 88.39 61.04 79.83 40.59 0.00 1 0.00 1 0 15 5.152e-02 5.033e-02 4.518e-02 4.400e-02 7.608553e+03 2.993370e+03 4.398552e+02 -6.000000e+00 2.697891e+03 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