File name: Pandora124s1_ComodoroRivadavia_20190810_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084517.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190810_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190810T114312.0Z 7161.488333 377 1 32.00 2 89.77 67.12 113.15 193.58 0.00 1 0.00 1 0 22 4.932e-02 4.772e-02 5.604e-02 5.475e-02 6.127464e+03 3.651362e+03 5.447280e+01 -6.000000e+00 2.581870e+03 274.71 -2.00 20.00 -2.00 505.14 0.00e+00 7.007555e-03 1.468034e-03 3.542656e-04 -6.000000e+00 1.344358e-03 274.71 -2.00 20.00 -2.00 499.71 0.00e+00 2.401982e+00 1.126011e+00 1.438142e-01 -6.000000e+00 9.714053e-01 222.74 -2.00 3.76 -2.00 501.34 0.00e+00 20.366 0.099 489.00 513.00 1 7.7225e+00 8.6107e-02 3.4951e-02 -6.0000e+00 7.4022e-02 1.5691e-01 2.2121e-02 2.7875e-03 -6.0000e+00 1.9655e-02 3.6510e-05 1.2355e-02 4.7256e-03 1.0749e-04 -6.0000e+00 4.5118e-03 3.2979e-02 -5.3496e-04 12 8 8 10 0 0 72.70 21.81 1.99 0.03298 0.11868 8 2 1 4 0 4000.000 25.90 20.00 21.81 -3941 421 -4773 1726 1273 5156 -5205 -5025 693 -2395 -6363 952 1920 1453 -4106 -2707 -267 -5336 1814 4108 -3970 4267 -477 670 -1898 6512 11221 3835 783 -4667 10495 8715 4731 -91 -1511 -2767 -4776 -152 7564 5690 -2907 -1523 -5019 1971 776 -4428 1590 6238 2663 -2840 -4409 4754 -1673 377 -6776 -692 839 2477 -4773 3417 5240 -2062 4911 7628 -2086 1750 -2024 -830 4561 -3187 -8316 5754 2830 9540 6770 11580 -2291 -3808 4498 -8239 8238 -713 329 -6632 -3930 -4990 1547 10176 2638 -5832 -4949 -2400 -4897 -6921 -3050 -7117 4758 4623 -2339 -5448 3497 5024 2505 1580 2193 2901 -225 -2564 -1535 -3215 8337 7040 4057 11820 158 459 11253 1188 -3648 311 -2388 -117 6228 5220 -5867 -5098 2174 6039 -544 10022 -1598 1671 -1308 3097 -7706 -1980 4984 3051 -8428 484 -8938 -7123 1221 -602 -2849 10110 -4204 -3559 3825 157 -4298 451 -5611 1968 1491 5923 -6207 -5992 772 -2698 -7325 1002 1965 1475 -4388 -2870 -281 -6055 1954 4340 -4538 4490 -528 738 -2162 6825 11159 4036 820 -4987 9527 8127 4724 -99 -1709 -3162 -5499 -165 7522 5752 -3226 -1690 -5861 2180 878 -5280 1771 6538 2835 -3105 -4748 4571 -1705 382 -7633 -757 921 2688 -5554 3652 5514 -2348 5228 7869 -2341 1856 -2188 -874 4479 -3327 -9059 5461 2791 8897 6509 10464 -2325 -3849 4139 -8567 7274 -691 316 -6868 -3989 -5127 1481 8860 2460 -5919 -5024 -2417 -5132 -7396 -3084 -6790 4221 3987 -1953 -4592 2680 3850 2035 1344 1890 2479 -196 -2250 -1329 -2870 6772 5907 3560 9692 147 427 9486 1110 -3550 286 -2214 -104 5202 4440 -5620 -4864 1933 5160 -496 8218 -1457 1447 -1148 2575 -7145 -1760 4221 2677 -8396 445 -9075 -7123 1128 -567 -2740 8444 -3962 -3246 3181 136 SO 20190810T114746.0Z 7161.491505 381 1 32.00 2 89.04 66.30 113.31 192.48 0.00 1 0.00 1 0 15 3.715e-02 3.595e-02 3.532e-02 3.463e-02 8.802090e+03 2.339915e+03 5.468819e+02 -6.000000e+00 1.945045e+03 274.71 -2.00 20.00 -2.00 505.13 0.00e+00 2.430198e-03 9.296059e-04 1.427612e-04 -6.000000e+00 1.011467e-03 274.71 -2.00 20.00 -2.00 499.77 0.00e+00 1.935449e+00 7.082189e-01 7.568264e-02 -6.000000e+00 7.290741e-01 222.74 -2.00 3.76 -2.00 501.39 0.00e+00 18.912 0.079 489.00 513.00 1 7.5556e+00 5.4180e-02 2.9932e-02 -6.0000e+00 5.5603e-02 1.3822e-01 1.3937e-02 2.2682e-03 -6.0000e+00 1.4684e-02 5.8345e-05 4.0458e-03 2.9533e-03 7.3897e-05 -6.0000e+00 3.4011e-03 1.1510e-02 -6.5436e-05 12 8 8 10 0 0 -137.91 21.81 2.28 0.01151 0.03957 8 2 1 4 0 4000.000 26.00 20.01 21.81 -4181 -3862 -2100 3946 724 1324 2484 3010 -1926 1626 1515 1531 -4130 314 -2343 4257 1908 1623 -4570 3647 253 4326 -1096 -563 -4796 2518 -3840 5037 -902 81 -3234 -928 -2924 2938 4980 4775 3783 -485 5950 4321 -579 -821 -70 -3882 -4818 3036 -2952 204 -1595 -9818 -2298 187 1188 694 3062 -1886 -2778 -338 299 -132 -247 4270 1068 -1207 -2379 1745 3550 -3281 4433 1288 1821 -3860 5186 -3258 -460 -2694 3868 -2746 3813 -1438 -1469 3363 -1101 -1873 -1845 3827 -2051 3533 4649 -51 -4332 227 -1285 1807 2799 -8706 -858 -1570 2845 4825 -1279 1473 -4662 -1992 2790 795 -10786 11130 -2790 1655 -6297 -3339 -2951 -1175 3380 2938 -204 3589 -80 1922 2285 8095 -8118 10387 -2461 762 7913 4304 2438 2612 -2690 7004 1959 -3571 2115 -2618 7871 -5652 4202 528 1831 -1261 1295 1306 -5636 -3415 -1307 -1104 3762 -4077 -4481 -4226 -2345 4296 833 1546 2915 3532 -2358 1890 1735 1727 -4474 321 -2453 4200 1963 1720 -5272 3903 280 4595 -1230 -632 -5646 2754 -4451 5259 -967 83 -3385 -956 -3159 3113 5303 5098 4028 -532 6041 4432 -625 -898 -77 -4489 -5672 3305 -3383 223 -1740 -11301 -2375 184 1147 683 3037 -2028 -3074 -367 321 -142 -266 4424 1146 -1320 -2602 1800 3530 -3443 4247 1254 1749 -3940 4886 -3384 -467 -2764 3635 -2702 3473 -1374 -1407 3089 -1064 -1838 -1830 3606 -2045 3310 4283 -49 -4399 223 -1298 1759 2637 -8930 -788 -1410 2384 3892 -1095 1253 -4079 -1777 2441 713 -10744 8767 -2509 1436 -6013 -3140 -2789 -1096 3023 2656 -192 3279 -76 1747 2027 6651 -7791 8333 -2260 680 6578 3704 2133 2279 -2452 5687 1648 -3150 1769 -2335 6467 -5411 3697 488 1682 -1201 1208 1222 -5642 -3310 -1216 -1000 3191 -3735 SO 20190810T115213.1Z 7161.494596 385 1 32.12 2 88.33 65.49 113.46 191.40 0.00 1 0.00 1 0 22 3.043e-02 2.987e-02 2.365e-02 2.327e-02 7.821613e+03 1.549370e+03 5.891245e+02 -6.000000e+00 1.593346e+03 274.71 -2.00 20.00 -2.00 505.17 0.00e+00 2.922707e-03 6.248105e-04 1.280427e-04 -6.000000e+00 8.284885e-04 274.71 -2.00 20.00 -2.00 499.82 0.00e+00 1.974505e+00 4.767637e-01 4.334667e-02 -6.000000e+00 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