File name: Pandora124s1_ComodoroRivadavia_20190817_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T084543.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190817_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190817T113210.0Z 7168.480671 227 1 32.00 2 89.77 70.31 78.81 268.43 0.00 1 0.00 1 0 22 6.701e-02 6.491e-02 6.301e-02 6.141e-02 5.257516e+03 4.057649e+03 2.408696e+02 -6.000000e+00 3.508742e+03 274.65 -2.00 20.00 -2.00 505.19 0.00e+00 3.055929e-03 1.654074e-03 1.250119e-04 -6.000000e+00 1.823912e-03 274.65 -2.00 20.00 -2.00 499.78 0.00e+00 2.370753e+00 1.258604e+00 6.594198e-02 -6.000000e+00 1.314943e+00 223.45 -2.00 3.76 -2.00 501.41 0.00e+00 20.359 0.099 489.00 513.00 1 7.9006e+00 9.6382e-02 3.2683e-02 -6.0000e+00 1.0030e-01 1.5028e-01 2.4834e-02 2.1437e-03 -6.0000e+00 2.6445e-02 3.2389e-05 9.9928e-04 5.3176e-03 4.8262e-05 -6.0000e+00 6.1340e-03 -5.0345e-02 4.0805e-04 12 8 8 10 0 0 15.92 20.75 1.93 -0.05034 -0.04341 8 2 1 4 0 4000.000 24.96 20.01 20.75 -1209 -477 -3116 -7121 6543 3701 4564 -1061 -2830 -4068 12738 -8008 6190 -9509 11071 -1054 5083 -4450 7827 -12369 -812 -18 3827 -10408 5367 3288 10242 562 -4168 -550 -2177 6711 10620 3434 4065 4767 13981 501 -1171 -155 3133 -9880 -3121 658 -10130 489 -5068 -1313 -5319 2530 -3382 3679 -3904 422 -5432 2116 -540 12274 1548 10110 -2669 2550 9585 11163 -2407 -1194 -6836 12307 4956 7804 -4105 5091 -11924 9342 383 -678 2797 -9779 -4212 3520 3235 -3393 381 -9488 -1304 -4431 4345 -43 5840 -8657 8620 -7371 6941 -4254 15120 -503 -6968 -7093 2790 3979 7997 805 9166 -8166 16863 -5058 1656 -2406 2710 8727 3280 623 9272 -5033 -976 -10332 -2291 4005 10613 -3349 -6114 -2283 -8287 -2672 1342 2565 4126 18813 14183 -561 5951 6729 475 -2498 -7215 -1417 -8843 -9164 -5600 1356 -5213 7212 1536 3303 3709 9591 -6478 -883 -9272 12758 -1273 -510 -3547 -8748 7185 4269 5309 -1213 -3275 -4689 12205 -9304 6131 -10871 10249 -1107 5105 -5046 8043 -15687 -917 -20 4127 -13007 5764 3607 10429 622 -4688 -575 -2277 6461 10077 3640 4402 5141 13589 550 -1289 -168 3292 -11935 -3568 734 -12707 553 -6005 -1476 -6105 2611 -3585 3542 -4011 419 -5908 2204 -590 11873 1662 9920 -2977 2715 9538 10902 -2663 -1282 -7626 11165 4772 7188 -4218 4784 -13411 8605 389 -687 2680 -10411 -4191 3226 2980 -3361 365 -10100 -1292 -4553 4083 -42 5353 -9176 7740 -7318 6522 -4150 12877 -454 -6529 -6463 2242 3095 5946 654 7091 -7827 12901 -4826 1459 -2172 2306 7051 2847 565 7811 -4932 -923 -10790 -2225 3666 9031 -3224 -5939 -2100 -8050 -2469 1200 2271 3600 14150 11156 -511 5039 5553 410 -2201 -6667 -1255 -8628 -9138 -5463 1247 -5153 6324 1432 3038 3396 8203 -6376 -801 -8966 9870 SO 20190817T113641.0Z 7168.483808 231 1 32.00 2 89.03 69.49 79.59 267.66 0.00 1 0.00 1 0 29 4.539e-02 4.539e-02 4.309e-02 4.228e-02 3.860663e+03 2.706546e+03 2.926079e+02 -6.000000e+00 2.376410e+03 274.65 -2.00 20.00 -2.00 505.20 0.00e+00 1.366762e-03 1.132845e-03 7.439165e-05 -6.000000e+00 1.236601e-03 274.65 -2.00 20.00 -2.00 499.82 0.00e+00 3.016421e+00 8.632204e-01 2.878605e-02 -6.000000e+00 8.936217e-01 223.46 -2.00 3.76 -2.00 501.47 0.00e+00 18.884 0.079 489.00 513.00 1 7.7074e+00 6.5977e-02 2.9199e-02 -6.0000e+00 6.8113e-02 1.1517e-01 1.7049e-02 1.7324e-03 -6.0000e+00 1.8047e-02 4.7516e-05 4.8341e-03 3.7033e-03 3.6491e-05 -6.0000e+00 4.1555e-03 -7.3515e-03 -1.4516e-04 12 8 8 10 0 0 -141.72 20.75 2.84 -0.00735 0.02618 8 2 1 4 0 4000.000 24.96 20.00 20.75 -1432 -1100 -679 3338 -4109 635 -4902 3647 -8433 5795 -1178 5373 -5942 6227 -8399 8221 -930 4800 -4555 5461 -3384 2882 -3063 1012 719 1050 5556 778 -8800 2716 -3708 1359 -6797 10702 1792 875 927 4235 -2939 6361 596 -3858 2146 -1261 4872 -1609 3985 -1242 6095 -1226 -3931 -8751 -1125 -1905 -286 2951 2710 -5567 2310 292 4476 -5660 2518 3203 -821 176 5281 509 3008 -6448 2719 -5815 7962 -6256 1389 1530 4781 4398 3849 2272 12343 819 1381 -4167 5535 3525 -92 -5502 -1738 4669 2558 2232 -9872 -1908 -2019 5013 -4183 10194 -1277 2766 -2966 4005 -2291 855 1285 7067 -7732 4854 -1963 2244 -2479 3813 -2305 3059 -7254 -672 984 1699 -1684 1520 -258 -551 -2503 6414 2375 -5049 -6187 -663 5504 3848 -1684 3348 -4349 -124 5374 -6103 5591 2924 -2268 -11125 -950 -4668 3935 -8156 5271 -1934 7119 2917 5197 -433 -1483 -1159 -738 3618 -4921 741 -5686 4242 -10185 5983 -1284 5410 -6589 6032 -9366 7806 -984 4924 -5269 5777 -3914 3131 -3533 1125 807 1175 5913 857 -10375 2752 -3934 1377 -7645 10503 1981 982 1028 4481 -3297 6446 640 -4364 2311 -1423 5216 -1840 4279 -1385 6196 -1305 -4159 -9453 -1111 -1912 -291 2999 2824 -6350 2429 312 4578 -6438 2648 3337 -882 184 5150 513 2914 -6760 2573 -6004 7231 -6638 1377 1502 4449 4022 3496 2085 10265 769 1298 -4169 5080 3325 -90 -5662 -1717 4329 2437 2162 -10947 -1958 -2046 4632 -3837 8478 -1077 2194 -2475 3164 -1993 751 1156 6022 -7550 4107 -1760 1939 -2281 3351 -2183 2769 -7319 -638 925 1593 -1625 1398 -238 -501 -2304 5428 2108 -4840 -6005 -608 4739 3370 -1549 2883 -3976 -108 4404 -5688 4747 2604 -2161 -11719 -910 -4668 3632 -8543 4835 -1894 6256 2607 4444 -390 SO 20190817T114110.0Z 7168.486921 235 1 32.00 2 88.30 68.68 80.36 266.90 0.00 1 0.00 1 0 22 3.496e-02 3.499e-02 3.149e-02 3.097e-02 5.795433e+03 1.968483e+03 2.997025e+02 -6.000000e+00 1.829973e+03 274.65 -2.00 20.00 -2.00 505.13 0.00e+00 1.519116e-03 8.297853e-04 9.402754e-05 -6.000000e+00 9.521483e-04 274.65 -2.00 20.00 -2.00 499.80 0.00e+00 1.423841e+00 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