File name: Pandora124s1_ComodoroRivadavia_20190831_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085114.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190831_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190831T110732.0Z 7182.463565 452 1 32.01 2 89.78 77.31 100.46 89.23 0.00 1 0.00 1 0 32 1.041e-01 9.758e-02 9.296e-02 8.965e-02 7.554748e+03 6.147515e+03 1.026911e+03 -6.000000e+00 5.456456e+03 274.82 -2.00 20.00 -2.00 505.18 0.00e+00 7.421836e-04 2.373815e-03 9.495327e-06 -6.000000e+00 2.837246e-03 274.82 -2.00 20.00 -2.00 499.77 0.00e+00 1.485464e+00 1.849273e+00 1.380937e-02 -6.000000e+00 2.052647e+00 224.83 -2.00 3.76 -2.00 501.41 0.00e+00 20.363 0.099 489.00 513.00 1 8.3818e+00 1.4141e-01 3.2114e-02 -6.0000e+00 1.5645e-01 1.5883e-01 3.6853e-02 1.8882e-03 -6.0000e+00 4.1439e-02 2.1866e-05 -8.1021e-03 7.6915e-03 8.7453e-05 -6.0000e+00 9.5309e-03 -7.0214e-02 2.6389e-04 12 8 8 10 0 0 -127.86 21.12 0.35 -0.07021 -0.12641 8 2 1 4 0 4000.000 25.28 20.01 21.12 1159 7780 -6539 16227 -7354 -8535 1880 -2471 -5911 15351 -4699 12268 2132 3681 3114 7550 -9573 -1036 -6616 16763 6755 -8017 1764 4244 -3647 1451 -479 -5133 6549 -8820 6544 -17409 -1793 11696 1718 4815 -6343 4179 -3285 -1601 9932 -12478 9568 13408 22524 -3600 15245 -14444 10708 148 12740 -12125 8474 -4913 2560 9260 10936 220 -5947 -2138 13946 2525 1166 -12096 2326 -16869 1325 865 4160 -1254 9219 -11710 7487 -2477 -11694 5540 -453 -3962 -1878 -5666 -7378 13361 584 7765 6496 -87 12845 13528 2070 8134 -6847 15894 -7239 20697 3582 1350 -1538 22124 -2595 -6482 -18359 24549 3186 11345 -25435 -7013 9680 6298 -8243 -2425 -3006 -6101 -1536 9015 10164 31641 -11316 -3675 13190 -10525 5051 -5053 -874 7829 426 -5057 4697 12949 2311 -2728 13892 -12859 22799 9495 7936 -13554 -15506 -8821 20685 -7503 6276 2173 17227 23379 213 -9906 12298 -15264 18852 -6548 1196 7517 -7467 15322 -9097 -10092 2045 -2856 -7109 14832 -5461 11853 2248 3756 3156 7295 -11061 -1119 -7778 15970 7165 -9859 1967 4616 -4312 1637 -550 -6139 6859 -10428 6411 -21408 -1902 11143 1880 5238 -7715 4518 -3773 -1785 9797 -15429 9568 13045 20241 -4232 14833 -18738 10636 159 11793 -13927 7730 -5079 2491 8697 10418 238 -6872 -2369 13097 2662 1253 -14875 2467 -21427 1379 888 4075 -1279 8347 -12976 6880 -2544 -13354 5353 -459 -4069 -1853 -5742 -7577 11194 560 6978 5969 -86 11283 11791 2014 7420 -7264 13531 -7312 17201 3259 1228 -1399 15408 -2246 -5694 -17854 15556 2559 8755 -29682 -6997 8199 5453 -8120 -2236 -2810 -5972 -1455 7749 8673 21837 -12070 -3666 11172 -11226 4532 -4914 -800 6533 385 -4854 4096 10399 2058 -2551 10982 -13151 16021 7506 6323 -13436 -15955 -8689 15443 -7532 5552 2018 13835 17748 205 -10503 10339 -16568 14194 -6244 SO 20190831T111131.0Z 7182.466331 456 1 32.00 2 89.10 76.60 99.78 88.56 0.00 1 0.00 1 0 22 9.933e-02 9.540e-02 7.272e-02 7.030e-02 1.116113e+04 5.105477e+03 9.556830e+02 -6.000000e+00 5.204741e+03 274.82 -2.00 20.00 -2.00 505.20 0.00e+00 -8.010621e-04 1.866239e-03 3.767256e-05 -6.000000e+00 2.705767e-03 274.82 -2.00 20.00 -2.00 499.80 0.00e+00 -2.244928e-01 1.457547e+00 4.094490e-02 -6.000000e+00 1.956817e+00 224.83 -2.00 3.76 -2.00 501.45 0.00e+00 19.050 0.081 489.00 513.00 1 8.4621e+00 1.1075e-01 2.9630e-02 -6.0000e+00 1.4916e-01 1.7438e-01 2.8982e-02 2.1462e-03 -6.0000e+00 3.9477e-02 2.8038e-05 -7.3481e-03 5.8871e-03 7.6027e-05 -6.0000e+00 9.0958e-03 -1.5763e-02 -6.7528e-06 12 9 8 11 8 0 -133.42 21.12 5.56 -0.01576 -0.06673 8 2 1 4 0 4000.000 25.28 19.98 21.12 5807 -11878 13083 1083 16416 -2549 -2382 -3160 10406 -7141 3436 -6535 6709 -637 15685 -14576 4715 -8805 1629 -5987 13512 -10186 -11927 3284 6622 -7925 722 10862 17180 -2470 -1193 8665 -1357 9000 171 3186 25 4966 -6835 12722 -9680 7415 -1818 14629 -2997 15169 -818 10603 -13337 15662 -17752 4821 -10920 17629 -19799 5494 -6223 7500 -3262 6333 -10520 8870 -6512 4396 -9877 4295 505 5159 -389 -5273 2886 -254 7718 7356 8232 3634 7197 3328 14562 -6419 4844 -272 8629 -3880 17512 -10197 20841 -4233 17711 -19584 12598 -9954 7230 -7194 17477 -11121 12887 -4153 27617 -9207 12386 -5223 14146 -3877 5615 -14516 9050 -5774 1908 1770 12242 7674 3576 -3876 10551 6102 -11754 -6817 -7569 -5902 -5870 4802 1102 3144 -11009 191 -8038 -1969 11224 3316 -15904 14244 -4672 12863 -4345 14341 -4396 -5840 -7755 20925 -5675 15975 -4278 16388 -3738 7958 10216 9331 -17280 7237 5700 -13976 12315 1194 16018 -3073 -2701 -3667 11467 -8589 3659 -7582 6719 -674 13961 -17530 4722 -10310 1769 -7169 13387 -12791 -15230 3601 7052 -9784 815 10992 16020 -2709 -1252 8172 -1431 8822 190 3511 28 5288 -8075 12200 -11540 7464 -2023 13952 -3446 14627 -923 10561 -16606 14273 -21914 4598 -11918 14384 -23916 5327 -6990 7470 -3630 6375 -12485 8694 -7487 4541 -11722 4369 525 5029 -396 -5559 2767 -250 7074 6859 7720 3582 6749 3174 12190 -6564 4414 -263 7681 -3947 14566 -11345 17115 -4463 14920 -22160 11147 -10333 6895 -7397 14908 -11380 10788 -3698 17391 -8198 8775 -4445 10231 -3528 4890 -15926 7881 -5767 1736 1602 10058 6682 3272 -3833 9032 5464 -12664 -7077 -7969 -6069 -5920 4253 992 2754 -11157 174 -7949 -1831 9112 2904 -16822 11002 -4275 9746 -3891 10725 -4044 -5574 -7669 15751 -5640 12889 -4251 13303 -3715 7008 8695 7850 -18533 5982 SO 20190831T111526.0Z 7182.469051 460 1 32.01 2 88.44 75.89 99.12 87.89 0.00 1 0.00 1 0 15 5.689e-02 5.556e-02 6.303e-02 6.169e-02 1.839657e+03 3.664623e+03 3.805435e+01 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