File name: Pandora124s1_ComodoroRivadavia_20190903_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085301.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190903_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190903T110156.0Z 7185.459676 448 1 32.00 2 89.78 78.89 113.09 131.96 0.00 1 0.00 1 0 15 4.932e-02 4.890e-02 5.202e-02 5.139e-02 2.758641e+03 3.125122e+03 4.647678e+01 -6.000000e+00 2.584833e+03 274.86 -2.00 20.00 -2.00 505.29 0.00e+00 2.379282e-03 1.368399e-03 8.308310e-05 -6.000000e+00 1.343453e-03 274.86 -2.00 20.00 -2.00 500.19 0.00e+00 2.453526e+00 1.022833e+00 5.557847e-02 -6.000000e+00 9.714577e-01 225.13 -2.00 3.76 -2.00 501.79 0.00e+00 20.365 0.099 489.00 513.00 1 7.7326e+00 7.8131e-02 3.2470e-02 -6.0000e+00 7.4061e-02 1.0261e-01 2.0166e-02 1.9826e-03 -6.0000e+00 1.9583e-02 3.8766e-05 5.2735e-04 4.5304e-03 2.7532e-05 -6.0000e+00 4.5171e-03 -4.8666e-02 2.4808e-04 12 8 8 10 0 0 25.37 21.11 7.39 -0.04867 -0.04501 8 2 1 4 0 4000.000 25.28 20.01 21.11 2095 -6495 -3690 -4038 3296 -9793 3195 -6501 -9027 2630 -3400 1189 4249 -2596 1032 12294 1015 -596 4394 1216 -2559 -1106 -1021 10680 2277 3595 2547 5575 -4364 3953 5515 995 1552 -1690 -1573 2822 -1655 3129 -2814 1072 -8030 3881 1406 4601 -49 -1424 -3318 622 8589 2576 -2116 -3721 -3960 3041 -4216 -1940 3493 -5826 3678 4395 278 -228 -5358 -214 11887 -4761 2623 -1915 6961 -3940 5621 1654 9647 4799 -1975 -4400 886 -6907 8409 1543 1369 -2673 2740 8870 422 -10642 6180 -84 1594 -4802 1196 -97 -5793 -4826 10431 -5069 -2432 813 4428 -1186 5768 5640 -9634 479 2836 -2867 -8377 1981 -1037 6803 -3786 6271 2366 8623 -1008 4058 -4338 5114 -1711 2350 1798 3023 -5876 1798 3792 5321 -5429 11545 1017 2654 -5255 4594 -13761 3677 966 4191 -2447 833 -1293 2083 976 3284 -5023 5192 4313 2276 -9183 -539 -6750 -4908 2014 -6922 -3964 -4176 3527 -11266 3292 -7454 -10595 2709 -3661 1206 4114 -2655 1011 10810 1015 -621 4476 1295 -2835 -1209 -1115 10425 2434 3802 2713 5701 -4801 3859 5191 983 1557 -1820 -1749 3028 -1839 3272 -3085 1122 -9207 3984 1498 4812 -55 -1605 -3791 674 8450 2625 -2189 -3805 -4003 2886 -4426 -2058 3599 -6657 3818 4511 297 -247 -6123 -233 11327 -5275 2651 -1995 6552 -4075 5225 1602 8707 4610 -2051 -4653 872 -7197 7427 1452 1294 -2651 2590 7937 416 -11790 5793 -84 1555 -4646 1097 -92 -5876 -4878 8967 -4995 -2283 719 3679 -1020 4585 4544 -9321 436 2591 -2784 -8497 1782 -951 5800 -3650 5571 2221 7692 -997 3839 -4493 4838 -1723 2240 1694 2773 -5854 1668 3478 4823 -5487 9842 962 2473 -5273 4114 -14552 3227 868 3694 -2359 794 -1279 2015 961 3178 -5312 4986 4188 2244 -9975 -524 -6822 -4837 SO 20190903T110554.0Z 7185.462431 452 1 32.00 2 89.10 78.18 112.58 131.11 0.00 1 0.00 1 0 15 1.101e-02 1.094e-02 7.534e-03 7.504e-03 7.800709e+03 4.704249e+02 5.344492e+02 -6.000000e+00 5.768859e+02 274.86 -2.00 20.00 -2.00 505.39 0.00e+00 1.336662e-03 2.023792e-04 8.032996e-05 -6.000000e+00 2.997030e-04 274.86 -2.00 20.00 -2.00 500.87 0.00e+00 1.630025e+00 1.450737e-01 6.310852e-02 -6.000000e+00 2.166415e-01 225.13 -2.00 3.76 -2.00 502.41 0.00e+00 19.053 0.081 489.00 513.00 1 5.9633e+00 1.1068e-02 2.9929e-02 -6.0000e+00 1.6518e-02 5.8051e-03 2.8177e-03 2.1866e-03 -6.0000e+00 4.3640e-03 2.9410e-04 -2.6281e-04 6.5571e-04 8.0402e-05 -6.0000e+00 1.0077e-03 -1.7576e-03 1.7865e-05 12 8 8 10 0 0 99.88 21.11 1.68 -0.00176 -0.00358 8 2 1 4 0 4000.000 25.28 19.98 21.11 -3116 -1306 -682 -535 -2082 -222 296 1741 215 522 -802 -523 -538 1177 -1171 1647 -677 2679 -232 1254 -710 1072 -689 1959 -1099 -390 1730 1352 -512 -107 -1201 716 -1938 -105 -554 103 484 -152 -135 1413 -494 1007 1227 605 619 242 931 -584 299 471 -892 -1761 -1151 -2017 -358 -430 772 -331 467 -340 2352 -380 2224 -1340 1349 -1755 1809 -448 327 -1421 -1274 -1194 1422 -128 1794 -446 292 -366 313 -227 41 -394 315 -393 -1679 -409 128 -481 -716 812 -29 -1128 608 1272 -293 1049 115 -60 -1541 -537 -2037 -601 -262 1438 -1120 320 -774 -92 -1657 1272 -114 400 -67 1948 -432 2739 -1244 978 -469 409 73 931 -688 1089 -205 1537 400 153 -456 331 474 653 263 -440 -834 1727 358 -1528 513 11 248 646 215 -1359 1456 -1179 1442 -1527 -318 -2767 -2728 -1146 -618 -504 -2046 -219 297 1741 218 522 -801 -515 -523 1109 -1126 1550 -664 2614 -240 1295 -750 1115 -679 2036 -1102 -390 1688 1312 -493 -100 -1107 651 -1853 -103 -563 105 486 -153 -134 1368 -488 991 1221 615 636 251 954 -600 300 460 -857 -1664 -1068 -1908 -343 -428 778 -341 478 -350 2360 -395 2264 -1416 1378 -1822 1784 -446 320 -1395 -1239 -1165 1368 -128 1767 -447 286 -353 297 -215 39 -380 304 -386 -1695 -412 128 -485 -722 807 -29 -1170 629 1310 -301 1039 111 -57 -1446 -490 -1881 -557 -252 1427 -1104 314 -765 -89 -1616 1212 -112 398 -67 1947 -444 2749 -1315 1021 -496 425 74 927 -691 1080 -208 1541 407 156 -468 338 480 652 259 -434 -828 1697 366 -1627 544 12 271 708 238 -1541 1609 -1331 1562 -1667 -336 -2990 SO 20190903T110953.0Z 7185.465197 456 1 32.00 2 88.42 77.47 112.07 130.26 0.00 1 0.00 1 0 15 2.849e-02 2.855e-02 2.420e-02 2.400e-02 6.458974e+03 1.561594e+03 4.675712e+02 -6.000000e+00 1.492922e+03 274.86 -2.00 20.00 -2.00 505.25 0.00e+00 1.429260e-03 6.439751e-04 5.793847e-05 -6.000000e+00 7.760275e-04 274.86 -2.00 20.00 -2.00 500.15 0.00e+00 1.104818e+00 4.815738e-01 4.042443e-02 -6.000000e+00 5.614516e-01 225.13 -2.00 3.76 -2.00 501.77 0.00e+00 17.298 0.061 489.00 513.00 1 7.4905e+00 3.6810e-02 2.6275e-02 -6.0000e+00 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