File name: Pandora124s1_ComodoroRivadavia_20190907_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085422.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190907_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190907T105430.0Z 7189.454514 358 1 32.01 2 89.76 81.01 112.64 187.79 0.00 1 0.00 1 0 15 1.975e-01 1.670e-01 1.694e-01 1.547e-01 1.888049e+04 1.184799e+04 1.057341e+03 -6.000000e+00 1.035429e+04 274.90 -2.00 20.00 -2.00 505.15 0.00e+00 -5.886900e-04 4.250458e-03 1.525776e-04 -6.000000e+00 5.381123e-03 274.90 -2.00 20.00 -2.00 499.65 0.00e+00 -2.069274e+00 3.214658e+00 1.564366e-01 -6.000000e+00 3.894376e+00 225.52 -2.00 3.76 -2.00 501.30 0.00e+00 20.330 0.099 489.00 513.00 1 9.1863e+00 2.4716e-01 3.4657e-02 -6.0000e+00 2.9684e-01 2.2495e-01 6.3675e-02 3.7337e-03 -6.0000e+00 7.8573e-02 1.2420e-05 -7.9011e-03 1.2296e-02 7.8649e-05 -6.0000e+00 1.8090e-02 4.6615e-03 -1.2971e-04 12 9 8 11 8 0 94.77 20.92 18.78 0.00466 -0.05014 8 2 1 4 0 4000.000 25.17 19.98 20.92 -4787 -12923 17753 1888 25942 -9243 12504 -18180 14329 13467 9540 -6533 36426 -15495 2475 12773 28263 4072 -8336 15831 -14757 -1954 -4969 17304 4313 3480 23655 13220 -18290 21400 -24106 16032 8424 17584 -14378 -88 -7164 11057 5199 9484 -12772 13759 -14515 4233 -20991 10338 2549 33108 -10921 3098 -12318 3675 -16790 29291 2741 25497 6795 10881 10066 9697 -19712 28814 -724 41675 22562 -6081 6140 9199 24968 10361 10344 6231 18609 -21920 -2757 -14502 -2673 -17147 12330 -7880 37828 -2331 81377 -39114 31620 -11488 1996 -16840 11754 -19325 13539 -14775 15488 -3239 18807 3158 6199 8816 20989 -17651 -14140 18769 -8490 -9736 40870 14760 47830 5372 -8304 29968 369 16085 -1500 34998 -14666 -1424 -2906 19255 -2047 31474 -1159 16698 -7750 48052 -3184 44991 -10313 2091 -8631 38748 -24732 22107 3278 5964 -11418 16330 -22239 45273 8030 -3795 -22730 21130 -20186 4013 19023 -1440 -1520 12556 7785 39982 -5444 -16001 16599 2147 23927 -11427 12688 -25444 14539 13665 9902 -7848 28039 -19699 2598 12067 23074 4321 -10306 15694 -19964 -2324 -6085 16953 4829 3937 21795 13414 -24959 18969 -32613 14398 8253 16202 -18949 -103 -8940 11348 5579 9623 -16088 13319 -18792 4591 -29622 10731 2853 27029 -13628 3288 -14797 3643 -19974 21864 2717 20816 6895 10787 10097 9727 -26439 23860 -811 30621 19998 -7093 6231 8905 20384 9667 9530 5959 15843 -28377 -2991 -17760 -2868 -20798 10929 -8455 25589 -2365 36066 -58392 23602 -13398 2049 -19332 10830 -22394 11290 -16481 12915 -3262 14869 2805 5103 6779 13866 -16822 -12863 12399 -7632 -9385 25230 12309 29008 4945 -8634 21096 352 13239 -1478 23878 -16359 -1388 -2895 15640 -2084 22837 -1142 13382 -7722 27061 -3000 26311 -10498 1880 -8599 23919 -28660 15802 2769 4844 -11005 12026 -24566 25986 6783 -3658 -26831 16247 -23610 3694 15039 -1388 -1449 10198 6492 23815 SO 20190907T105859.0Z 7189.457627 362 1 32.00 2 88.99 80.21 112.73 186.71 0.00 1 0.00 1 0 29 1.123e-01 1.025e-01 1.061e-01 1.014e-01 1.240103e+04 7.489407e+03 9.940956e+02 -6.000000e+00 5.886393e+03 274.90 -2.00 20.00 -2.00 505.16 0.00e+00 4.934368e-03 2.706054e-03 3.319004e-04 -6.000000e+00 3.060258e-03 274.90 -2.00 20.00 -2.00 499.70 0.00e+00 1.783347e+00 2.103261e+00 6.331194e-02 -6.000000e+00 2.216678e+00 225.52 -2.00 3.76 -2.00 501.31 0.00e+00 18.772 0.078 489.00 513.00 1 8.6441e+00 1.6084e-01 3.0265e-02 -6.0000e+00 1.6891e-01 1.4741e-01 4.1478e-02 2.1866e-03 -6.0000e+00 4.4797e-02 1.9205e-05 7.9118e-04 8.4224e-03 1.3044e-04 -6.0000e+00 1.0281e-02 3.2910e-02 -4.1715e-04 12 8 8 10 0 0 93.08 20.92 1.28 0.03291 0.03840 8 2 1 4 0 4000.000 25.17 20.01 20.92 2975 -1778 5526 1087 -12177 -6984 95 10131 2743 1914 14078 10956 7642 3773 -6419 3794 8856 7989 -1641 11051 5896 7248 -10114 9143 -2613 8786 -13648 -8621 9437 -14960 -5595 -2784 8836 -4295 5360 -1802 -7189 -1389 3642 13432 8859 -5080 -11331 9595 3014 7031 16322 -6556 -10766 44000 -20545 -3250 20420 17164 -6749 -16808 -9925 -4259 1797 7107 5511 11242 -5100 2224 -4639 -1559 23971 17019 5861 -15981 11037 -11638 16717 4656 12006 -7940 -2870 4810 10742 -11975 -386 15252 -1925 -5198 -6466 -16043 12383 3282 -892 -9636 29421 -10962 -5941 -2797 646 7275 15607 -4723 156 -14570 12973 5936 -5145 -4446 -8018 3083 -370 -116 8000 10110 -841 -12412 -6354 11602 -2535 7311 4356 12996 5174 8062 10985 -16109 -9294 7211 -6246 28440 7273 24756 4641 -17427 -11119 -9880 3918 11745 18274 4650 25490 34878 -4287 766 6496 5524 -13442 -8507 -5815 -686 5523 1628 3504 4249 3054 -1943 5810 1241 -15076 -8379 108 10529 3060 2120 13556 10717 7592 3835 -7162 3827 8595 7997 -1856 11147 6263 7588 -12598 9433 -3055 9198 -17834 -10607 9448 -18406 -6114 -2957 8508 -4891 5735 -2093 -8736 -1571 3869 12831 8869 -5901 -14201 9899 3363 7576 15966 -7966 -13410 30935 -26691 -3453 16853 14691 -7530 -21451 -12135 -4980 1977 7386 5812 11254 -6042 2447 -5424 -1739 20334 15217 5778 -19296 10037 -13252 14436 4590 11102 -8920 -3005 4558 9440 -13086 -375 12704 -1913 -5363 -6819 -18758 10883 3135 -879 -10309 21359 -11201 -5860 -2679 587 5988 11407 -4089 125 -13234 8838 4381 -4381 -3944 -7681 2691 -333 -103 6472 8035 -758 -12771 -6222 9550 -2411 6329 3926 10882 4700 7037 9121 -17147 -9102 5987 -5984 19374 6142 17567 4018 -18797 -11205 -9675 3281 9002 13097 3861 17545 22275 -4107 706 5716 4939 -14594 -8813 -5860 -653 4860 1455 3009 3588 SO 20190907T110332.0Z 7189.460787 366 1 32.00 2 88.21 79.39 112.81 185.62 0.00 1 0.00 1 0 22 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