File name: Pandora124s1_ComodoroRivadavia_20190913_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085510.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190913_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190913T104252.0Z 7195.446435 204 1 32.00 2 89.78 84.30 90.07 255.22 0.00 1 0.00 1 0 22 8.889e-02 8.321e-02 9.785e-02 9.371e-02 1.029255e+04 6.689542e+03 8.705711e+02 -6.000000e+00 4.663681e+03 274.97 -2.00 20.00 -2.00 505.10 0.00e+00 1.078403e-03 2.509822e-03 4.330199e-05 -6.000000e+00 2.420014e-03 274.97 -2.00 20.00 -2.00 499.52 0.00e+00 9.439884e-01 1.968590e+00 3.398012e-02 -6.000000e+00 1.746503e+00 226.11 -2.00 3.76 -2.00 501.16 0.00e+00 20.350 0.099 489.00 513.00 1 8.4743e+00 1.5113e-01 3.2231e-02 -6.0000e+00 1.3324e-01 2.0620e-01 3.9208e-02 2.1375e-03 -6.0000e+00 3.5052e-02 2.0734e-05 -8.1989e-03 7.9582e-03 7.6536e-05 -6.0000e+00 8.1304e-03 -1.1150e-01 9.3711e-04 12 8 8 10 0 0 59.98 21.27 6.86 -0.11150 -0.16837 8 2 1 4 0 4000.000 25.47 20.00 21.27 26701 641 3744 -15504 5534 4933 -4201 5411 5365 985 5559 -5256 4370 11778 7944 -2107 -2197 3955 3470 -4716 -7411 8275 -7066 -1707 -8681 -4618 11132 2323 -3196 1928 -2053 -278 6806 248 6961 559 2176 6505 -9102 1316 -9972 8866 -6775 -9674 -5223 524 1857 3093 -6788 40 2818 6956 -2749 6016 14636 6605 -1649 22464 -5586 4825 -12901 18770 10220 -8667 -9459 7062 2388 7851 -5379 -7553 -3472 8079 10438 -6232 -457 -17928 -1403 8171 -7370 -9586 -17510 13490 8371 8273 7835 -10344 11294 -8730 14195 -5070 9274 -3024 -371 1059 15356 1844 -6027 -6410 7002 -11303 15036 -10946 1928 -6914 96 16816 -4375 14851 -10689 8483 -6046 -4026 1075 25192 -14662 -5282 10996 8901 -8635 5378 6283 6362 -4261 3178 -6571 4110 7322 23784 1250 11493 -8358 1009 5573 21722 -12551 2142 -7109 2291 -1574 8102 2825 -5235 2371 -999 3292 12778 -2721 -4389 4899 -3103 22270 701 4097 -19711 6352 5812 -5104 6039 5988 1134 6008 -6237 4630 11397 7912 -2321 -2452 4246 3848 -5763 -9317 8884 -8833 -2025 -11098 -5676 11637 2625 -3725 2056 -2219 -295 6827 275 7474 647 2459 6938 -11186 1441 -12185 9018 -8135 -12094 -6309 600 2085 3386 -8055 43 2866 6584 -2816 5651 12921 6531 -1817 19674 -6470 5009 -15946 16970 10105 -10346 -11291 7033 2446 7486 -5775 -8162 -3556 7361 9363 -6691 -468 -21780 -1417 7329 -7600 -10020 -19788 11243 7390 7363 7083 -11324 9971 -9372 12032 -5193 8253 -2856 -346 972 11985 1596 -5455 -5633 5235 -9934 10059 -9620 1543 -6349 86 12904 -4132 11396 -10446 6844 -5710 -3776 966 17844 -15483 -5092 9087 7589 -8779 4691 5316 5257 -3856 2668 -6120 3450 5954 16379 1074 8895 -7839 847 4386 14389 -11689 1742 -6480 1939 -1404 6642 2464 -4978 2099 -917 2893 10141 -2480 -3973 3952 -2686 SO 20190913T104652.0Z 7195.449213 208 1 32.00 2 89.08 83.58 90.74 254.54 0.00 1 0.00 1 0 22 5.417e-02 5.107e-02 5.894e-02 5.730e-02 7.393693e+03 3.923750e+03 4.865774e+02 -6.000000e+00 2.841147e+03 274.97 -2.00 20.00 -2.00 505.14 0.00e+00 -1.080920e-04 1.520717e-03 4.583624e-05 -6.000000e+00 1.475123e-03 274.97 -2.00 20.00 -2.00 499.65 0.00e+00 2.436668e+00 1.185065e+00 5.202402e-02 -6.000000e+00 1.066702e+00 226.11 -2.00 3.76 -2.00 501.30 0.00e+00 18.997 0.080 489.00 513.00 1 8.0790e+00 9.0541e-02 2.9570e-02 -6.0000e+00 8.1340e-02 1.4401e-01 2.3412e-02 2.0154e-03 -6.0000e+00 2.1470e-02 3.4279e-05 -2.5496e-03 4.8618e-03 4.8377e-05 -6.0000e+00 4.9586e-03 -3.6408e-04 7.3324e-05 12 8 8 10 0 0 99.46 21.27 -0.78 -0.00036 -0.01805 8 2 1 4 0 4000.000 25.47 19.99 21.27 8795 2501 -2676 3120 -4300 -6322 880 -2662 1314 6338 -414 3044 -1832 353 522 -1913 -758 -2055 -2695 -3618 606 -1654 -3541 -3276 889 3556 4622 1892 -3879 -11243 2750 2152 64 1418 4209 2220 9576 2458 -1298 1971 -5207 4742 2428 8413 85 -1298 3779 14159 -2745 9068 1765 -4112 -980 862 -6932 -5273 -1369 -6678 -1156 -1335 3772 -320 -800 220 492 -7902 -7840 -1768 4732 -3823 706 12677 13095 -6335 -812 -4434 3996 3163 -1472 140 6447 -5774 18733 -6039 8324 1740 2761 -6711 568 6960 6461 -7343 -1130 4484 -78 706 2341 -8151 -7613 13030 2003 -2899 4238 -3775 -4556 -3049 -2989 3895 4050 495 -8233 1332 -2152 -3379 -5671 2460 10737 3215 -8304 2005 -5177 12878 2909 12016 6218 4095 6530 2114 -8295 -1430 2558 -3226 6005 -1314 -6422 6843 6720 2128 518 2261 -5400 7471 -2094 3969 -7288 -7121 -4676 2551 -921 1582 8434 2597 -3030 3459 -5270 -8074 1066 -3115 1475 7235 -459 3220 -2002 372 545 -2057 -818 -2308 -3131 -4296 691 -1928 -4205 -3891 1018 3962 5070 2108 -4456 -13401 2790 2203 69 1550 4617 2502 9924 2696 -1457 2119 -6004 4977 2632 8683 96 -1491 4096 13635 -3070 8772 1776 -4262 -969 841 -7514 -5806 -1484 -7700 -1258 -1448 3877 -344 -867 235 520 -8941 -8701 -1817 4496 -3896 679 10839 11253 -6702 -821 -4615 3745 2923 -1404 130 5652 -5760 14723 -6128 7405 1668 2623 -6984 547 6281 5887 -7769 -1137 4260 -76 664 2103 -7322 -6625 9039 1542 -2383 3365 -3406 -4293 -2861 -2781 3326 3411 432 -7957 1186 -2002 -3197 -5503 2209 8955 2914 -8425 1809 -4920 10018 2473 9348 5162 3481 5421 1831 -7950 -1279 2185 -2872 4792 -1117 -5743 5433 5470 1852 465 2022 -5262 6441 -1998 3581 -7365 -7139 -4500 2230 -816 1358 SO 20190913T105050.0Z 7195.451968 212 1 32.00 2 88.40 82.87 91.39 253.85 0.00 1 0.00 1 0 22 4.475e-02 4.385e-02 4.349e-02 4.231e-02 9.933365e+03 2.948030e+03 6.548945e+02 -6.000000e+00 2.347051e+03 274.97 -2.00 20.00 -2.00 505.11 0.00e+00 1.486609e-03 1.130896e-03 1.133502e-04 -6.000000e+00 1.219453e-03 274.97 -2.00 20.00 -2.00 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