File name: Pandora124s1_ComodoroRivadavia_20190918_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085517.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190918_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190918T103309.0Z 7200.439687 198 1 32.00 2 89.78 87.06 71.65 310.89 0.00 1 0.00 1 0 15 9.772e-02 9.051e-02 9.796e-02 9.428e-02 6.889247e+03 6.476000e+03 3.319950e+02 -6.000000e+00 5.127163e+03 275.10 -2.00 20.00 -2.00 505.17 0.00e+00 2.056561e-03 2.536843e-03 1.492460e-04 -6.000000e+00 2.666326e-03 275.10 -2.00 20.00 -2.00 499.62 0.00e+00 3.255196e+00 1.965411e+00 7.502053e-02 -6.000000e+00 1.935159e+00 226.56 -2.00 3.76 -2.00 501.28 0.00e+00 20.342 0.099 489.00 513.00 1 8.3008e+00 1.5049e-01 3.2755e-02 -6.0000e+00 1.4739e-01 1.3264e-01 3.8599e-02 2.2627e-03 -6.0000e+00 3.9204e-02 2.0574e-05 8.3295e-03 8.1998e-03 4.7567e-05 -6.0000e+00 8.9377e-03 3.3078e-02 -6.0414e-04 12 8 8 10 0 0 -294.51 21.62 6.83 0.03308 0.09085 8 2 1 4 0 4000.000 25.79 20.00 21.62 16520 4711 -2402 -2043 8016 -11487 5776 -7679 13117 2093 -168 -13121 -8893 -9655 1477 3359 14490 4135 -2923 1260 -8907 7845 -4199 1771 -7279 12424 -2330 136 -825 5619 -8283 10735 2204 15298 -10619 12378 -4825 -92 -3911 2937 9182 17318 -2174 5484 1270 -3462 3292 -686 -14463 4585 16231 -7550 -2157 -8173 -663 1210 4147 7016 2007 11943 6805 24817 -9704 -11104 -10950 -2800 13807 -1649 39549 8409 -13646 -6406 -8861 587 673 10234 7335 1326 9330 1532 -2154 -3016 5801 3342 7469 -10457 4244 11614 -1294 -4278 -921 -21104 9976 -7311 13127 -11680 10040 8721 -10604 -5150 3166 -1229 4679 5873 1349 3675 13978 9843 4722 -12927 -175 8318 392 -5886 -8150 9558 3661 -8596 -3624 -5715 3740 8118 17292 -3736 -1493 17111 14696 -10023 254 2504 1195 9783 -12043 12187 11258 -8317 -8054 31843 -11083 9182 -15153 -6413 1626 18088 -7222 16732 -5600 5523 4962 -9426 14624 4787 -2718 -2391 8701 -15474 6669 -9439 14136 2290 -185 -16222 -10363 -11183 1522 3413 13385 4349 -3385 1415 -11075 8250 -4983 1988 -9000 12624 -2731 153 -914 5629 -9358 10069 2302 14566 -13506 12578 -5759 -103 -4502 3130 9199 16120 -2487 5884 1434 -4108 3626 -775 -18396 4691 14301 -8208 -2192 -8885 -688 1273 4331 7178 2154 11541 6915 21161 -11722 -13571 -13227 -3064 12558 -1723 26977 7708 -15417 -6736 -9633 588 679 9307 6724 1263 8088 1426 -2082 -2958 5235 3111 6740 -11368 3981 10068 -1269 -4316 -903 -23810 9003 -7284 11286 -11636 8418 6674 -9585 -4316 2423 -997 3705 4805 1192 3201 10883 7859 3926 -12879 -156 6916 357 -5748 -8174 8072 3310 -8848 -3539 -5619 3282 6695 12893 -3451 -1359 12983 11442 -9986 228 2198 1057 7811 -11760 9247 8617 -7847 -7758 21010 -11408 7816 -16597 -6474 1524 14441 -7433 13468 -5543 4774 4223 -9205 SO 20190918T103708.0Z 7200.442454 202 1 32.00 2 89.08 86.34 72.17 310.05 0.00 1 0.00 1 0 15 7.770e-02 7.457e-02 6.714e-02 6.510e-02 9.296526e+03 4.617337e+03 1.127968e+03 -6.000000e+00 4.076439e+03 275.10 -2.00 20.00 -2.00 505.17 0.00e+00 3.609929e-03 1.741110e-03 2.007054e-04 -6.000000e+00 2.119944e-03 275.10 -2.00 20.00 -2.00 499.64 0.00e+00 2.099876e+00 1.356695e+00 5.222674e-02 -6.000000e+00 1.538552e+00 226.56 -2.00 3.76 -2.00 501.28 0.00e+00 18.990 0.080 489.00 513.00 1 8.1788e+00 1.0359e-01 2.9726e-02 -6.0000e+00 1.1718e-01 1.4704e-01 2.6902e-02 1.6407e-03 -6.0000e+00 3.1167e-02 2.9993e-05 -3.4947e-04 5.5498e-03 1.3054e-04 -6.0000e+00 7.1054e-03 2.1036e-02 -5.2972e-04 12 8 8 10 0 0 12.56 21.62 4.08 0.02104 0.01861 8 2 1 4 0 4000.000 25.90 20.00 21.62 -451 9266 -236 13939 207 8479 -4811 5202 -12901 5592 -6722 -958 2920 -652 -9743 -5523 4764 -3467 9978 -5776 21390 -6798 6238 1449 5710 -2188 -3601 -5169 -4671 -316 -183 -8610 6227 -7220 2707 -6564 3634 7364 4619 756 6074 2425 2652 -4334 -5133 5065 13875 -2713 -4751 7534 2082 7921 769 1913 -11473 -2849 6152 4902 -2534 2417 -2852 14563 -5016 5827 -6716 -2522 -14868 -2554 -247 7223 -7891 8870 -2328 4219 -4738 16749 -10304 13419 -10385 1798 -3204 10455 -6261 10889 -3027 3967 -866 10765 -5526 8839 4598 10982 9185 9488 12336 6460 -14069 15329 -1185 9956 -3061 6045 -18852 7386 -4978 -8014 -194 -4460 4468 -613 -5431 2866 -8980 -15214 -6285 312 20703 -1233 1158 2809 483 -4067 16428 -4172 1119 -1802 -7363 584 14026 -255 13686 -2695 5983 -12787 6847 4032 -7081 -6843 11937 -9062 7190 4223 -3139 9828 1284 -5253 -4129 5186 -1376 7824 -475 8915 -258 13708 241 9285 -6138 6084 -16711 5954 -7949 -1053 3037 -691 -11186 -6071 4768 -3844 9939 -6859 19417 -8173 6581 1607 6108 -2544 -4240 -6137 -5409 -338 -189 -9632 6080 -8325 2936 -7956 3959 7624 4850 817 6199 2582 2850 -5061 -6120 5492 13753 -3141 -5525 7578 2146 7463 763 1868 -13060 -3075 6249 5124 -2860 2585 -3204 13791 -5808 6062 -7875 -2796 -18311 -2732 -255 6805 -8518 8052 -2376 4078 -5068 14464 -11477 11523 -11109 1685 -3144 8977 -6390 9404 -3030 3737 -859 9455 -5667 7807 4242 9592 8292 8613 10774 5833 -14038 11884 -977 7167 -2469 4462 -18296 5754 -4581 -7777 -174 -4125 3725 -536 -5048 2494 -8919 -16221 -6157 287 15659 -1174 1082 2560 442 -3817 12350 -3840 984 -1642 -7112 522 10928 -229 10663 -2444 4880 -12409 5428 3306 -6614 -6517 9572 -9083 6191 3771 -3032 8373 1193 -5193 -3988 4466 -1235 6310 SO 20190918T104059.0Z 7200.445127 206 1 32.00 2 88.41 85.65 72.69 309.25 0.00 1 0.00 1 0 36 6.084e-02 6.016e-02 4.849e-02 4.739e-02 4.262210e+03 2.964374e+03 5.392168e+01 -6.000000e+00 3.193070e+03 275.10 -2.00 20.00 -2.00 505.10 0.00e+00 2.176503e-05 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