File name: Pandora124s1_ComodoroRivadavia_20190927_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T085457.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20190927_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20190927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190927T101544.0Z 7209.427593 406 1 32.01 2 89.76 92.05 88.24 72.62 0.00 1 0.00 1 0 15 3.173e-02 3.154e-02 3.315e-02 3.255e-02 1.139259e+04 2.304186e+03 8.547572e+02 -6.000000e+00 1.667455e+03 275.41 -2.00 20.00 -2.00 505.20 0.00e+00 1.899361e-03 8.761357e-04 8.250742e-05 -6.000000e+00 8.645055e-04 275.41 -2.00 20.00 -2.00 499.82 0.00e+00 2.639983e+00 6.695245e-01 5.264024e-02 -6.000000e+00 6.245812e-01 227.30 -2.00 3.76 -2.00 501.46 0.00e+00 20.295 0.098 489.00 513.00 1 7.2732e+00 5.1265e-02 3.2332e-02 -6.0000e+00 4.7642e-02 1.2537e-01 1.3056e-02 2.3340e-03 -6.0000e+00 1.2552e-02 6.0921e-05 5.1876e-03 2.7369e-03 8.2866e-05 -6.0000e+00 2.9022e-03 3.8041e-03 1.6477e-04 12 9 8 11 8 0 -163.73 22.31 0.12 0.00380 0.03979 8 2 1 4 0 4000.000 26.32 19.99 22.31 -1611 1339 2252 -1727 2585 -4114 4008 -4958 3319 962 -220 -2426 2547 -3203 -3941 -2417 1852 1688 1140 896 -1304 -1722 1333 -28 1031 -1117 1445 -1862 -3830 -2984 2174 822 323 290 7362 559 552 4692 -1481 414 -1581 4242 911 -975 -4797 2471 -4463 2686 3453 -5397 -143 -1 -6115 4732 3541 -1369 -4264 6668 2430 1838 -2385 6209 -4395 3593 2176 1273 1198 5006 -694 -1146 -3548 1008 -6450 -1725 478 -1922 -788 3597 -5872 6845 -1599 856 -4855 -1844 -281 4120 -393 6107 3163 1990 3689 707 -2499 2229 -3087 2911 6045 -861 -1971 -3029 896 -157 -5602 -1688 -2449 -1532 3699 -2122 3649 -908 -5781 -3241 4331 -2212 6962 -276 5037 -39 -808 -721 -432 1674 5067 -4945 3269 714 -2918 1675 5266 1349 -197 -3793 -525 -2626 -908 1001 -2588 -3373 1002 2971 3317 78 -1566 -1 -6785 -1337 3967 1013 -442 2544 -1678 1395 2419 -1993 2921 -5074 4624 -5790 3829 1117 -235 -2613 2569 -3387 -4196 -2562 1922 1806 1251 989 -1472 -1952 1469 -32 1151 -1271 1592 -2079 -4210 -3155 2171 843 344 321 7731 625 610 4905 -1628 445 -1742 4454 1001 -1105 -5685 2716 -5202 2867 3576 -5919 -144 -1 -6391 4528 3545 -1481 -4824 6773 2564 1944 -2639 6337 -4993 3747 2269 1315 1217 4827 -698 -1142 -3604 985 -6869 -1773 481 -1948 -772 3309 -5879 6012 -1534 806 -4872 -1814 -275 3871 -385 5560 2949 1880 3458 692 -2539 2127 -3015 2586 5029 -746 -1688 -2586 741 -126 -4965 -1508 -2260 -1403 3178 -1905 3085 -813 -5518 -3049 3799 -2076 5980 -257 4510 -37 -766 -670 -392 1461 4260 -4631 2838 638 -2706 1481 4487 1193 -175 -3422 -453 -2310 -792 876 -2400 -3204 924 2721 3054 74 -1531 -1 -6972 -1285 3543 912 -399 2238 SO 20190927T102010.0Z 7209.430671 410 1 32.00 2 88.98 91.25 87.51 71.85 0.00 1 0.00 1 0 15 1.822e-02 1.798e-02 1.729e-02 1.711e-02 8.878580e+03 1.155591e+03 6.136769e+02 -6.000000e+00 9.572341e+02 275.41 -2.00 20.00 -2.00 505.23 0.00e+00 9.100983e-04 4.582817e-04 6.609928e-05 -6.000000e+00 4.968327e-04 275.41 -2.00 20.00 -2.00 500.05 0.00e+00 3.044392e+00 3.460073e-01 6.222381e-02 -6.000000e+00 3.598444e-01 227.30 -2.00 3.76 -2.00 501.67 0.00e+00 18.738 0.077 489.00 513.00 1 6.8107e+00 2.6449e-02 2.9215e-02 -6.0000e+00 2.7429e-02 7.8606e-02 6.7986e-03 2.1827e-03 -6.0000e+00 7.2602e-03 1.1918e-04 4.9593e-04 1.4652e-03 6.5246e-05 -6.0000e+00 1.6687e-03 -9.2278e-03 -3.0934e-05 12 8 8 10 0 0 -139.41 22.31 2.79 -0.00923 -0.00579 8 2 1 4 0 4000.000 26.32 20.00 22.31 -2750 -1279 1594 511 944 -1944 2405 560 1197 -61 1368 1995 2603 -5767 2752 -550 -853 -427 4760 -171 49 717 -974 -1961 -644 -1287 3774 -827 -1175 1123 -316 229 671 -1123 1140 1321 755 116 602 -1751 351 -635 -4307 2410 -1596 -161 -51 1091 -969 1939 -1061 1394 -1549 -730 -313 874 -244 155 -1540 -232 237 -338 -3685 344 1431 188 239 2894 -104 -294 -892 770 -1055 2421 1193 -669 449 -1217 -1028 -2252 -2053 2031 1882 2399 240 1698 -1587 -3894 -981 1393 -508 -468 1612 -237 -1859 -1773 4357 -1324 -2188 -803 2497 -125 -3577 -2843 2867 1580 100 -3324 -150 -769 1754 92 1505 -109 5826 2913 -1103 -1288 2721 -2748 585 -841 -502 -856 -3073 -833 1735 318 678 3634 -763 1119 1537 1649 -980 -2290 1993 388 -3044 1216 822 2081 -259 -455 -891 -100 -498 1219 -511 -250 -2785 -1299 1630 549 1038 -2075 2509 601 1276 -65 1416 2027 2588 -6150 2680 -556 -879 -450 4898 -188 54 781 -1080 -2204 -720 -1448 4024 -914 -1270 1144 -320 231 689 -1219 1251 1460 831 127 647 -1908 375 -688 -4898 2595 -1807 -180 -57 1183 -1053 1995 -1089 1357 -1530 -719 -316 901 -261 166 -1680 -249 252 -363 -4120 369 1505 197 246 2855 -104 -291 -879 747 -1051 2363 1191 -676 440 -1186 -986 -2172 -1977 1891 1767 2258 234 1645 -1590 -3977 -967 1340 -500 -467 1594 -239 -1867 -1604 3871 -1207 -1961 -696 2080 -101 -3100 -2570 2544 1440 92 -3116 -134 -697 1573 85 1388 -102 5190 2686 -1069 -1265 2568 -2705 547 -781 -460 -789 -2921 -778 1583 295 624 3250 -710 1006 1354 1439 -879 -2111 1804 365 -3011 1169 802 2020 -260 -459 -903 -100 -494 1160 -485 -235 SO 20190927T102431.0Z 7209.433692 414 1 32.01 2 88.23 90.48 86.81 71.10 0.00 1 0.00 1 0 15 1.450e-02 1.450e-02 1.369e-02 1.353e-02 1.022300e+04 9.567825e+02 7.234575e+02 -6.000000e+00 7.616589e+02 275.41 -2.00 20.00 -2.00 505.32 0.00e+00 9.003492e-04 3.617218e-04 5.844675e-05 -6.000000e+00 3.953066e-04 275.41 -2.00 20.00 -2.00 500.07 0.00e+00 2.044373e+00 2.757787e-01 6.523515e-02 -6.000000e+00 2.862847e-01 227.30 -2.00 3.76 -2.00 501.70 0.00e+00 16.734 0.055 489.00 513.00 1 6.9201e+00 2.1063e-02 2.5599e-02 -6.0000e+00 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