File name: Pandora124s1_ComodoroRivadavia_20191027_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T090158.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20191027_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20191027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191027T092117.0Z 7239.389780 360 1 32.00 2 89.79 108.20 91.25 96.52 0.00 1 0.00 1 0 22 7.761e-02 7.511e-02 6.807e-02 6.581e-02 1.168356e+04 4.933083e+03 6.724690e+02 -6.000000e+00 4.099054e+03 276.55 -2.00 20.00 -2.00 505.21 0.00e+00 1.753936e-03 1.781086e-03 1.207067e-04 -6.000000e+00 2.120016e-03 276.55 -2.00 20.00 -2.00 499.69 0.00e+00 2.785294e+00 1.384337e+00 7.559854e-02 -6.000000e+00 1.529393e+00 229.47 -2.00 3.76 -2.00 501.35 0.00e+00 20.275 0.098 489.00 513.00 1 8.0062e+00 1.0606e-01 3.2569e-02 -6.0000e+00 1.1670e-01 1.3896e-01 2.7137e-02 2.4521e-03 -6.0000e+00 3.0706e-02 2.9029e-05 -8.6970e-03 5.5627e-03 5.8319e-05 -6.0000e+00 7.0976e-03 -3.4145e-02 4.8093e-04 12 8 8 10 0 0 20.06 21.12 5.74 -0.03415 -0.09447 8 2 1 4 0 4000.000 25.28 20.00 21.12 1406 12055 -11945 8933 -361 5956 -3306 5321 -3090 3542 -10569 16823 -8201 105 -3015 2870 -5058 4699 -6282 6607 -7892 -1696 4014 2071 10021 -4777 -3056 -2776 2682 6610 9752 -9280 -8357 -344 5375 3761 -1901 -3305 15550 -11066 14895 -5210 5684 -5858 -2298 -4863 15089 -4613 -7269 732 7694 9442 6136 -11035 9448 2645 15809 3421 12601 -5727 3943 -3383 -4293 -3951 8189 -1068 3184 5472 -874 -1942 -274 -4325 -2102 -5605 -6007 7765 4701 -1726 8938 3053 -12154 6661 -16519 10743 -5995 11036 5571 -4194 -19 -3463 -8025 10630 9085 7347 -2068 -2841 6213 -41 11926 -5383 -5700 9053 6386 490 -1126 7589 -5669 18174 -8315 11652 1848 4324 -9228 -11136 5721 2975 3006 727 475 7519 -5186 -6918 1817 3486 6481 -1550 3379 -8684 -5064 -11328 -5632 -3210 12996 -11772 3344 825 6435 1459 5106 -15804 19463 5744 13317 -1727 13694 -4683 -1896 -14260 6797 11726 1451 11336 -14763 9313 -425 6721 -3854 5753 -3633 3847 -13002 15521 -9559 111 -3260 2933 -5670 4895 -7509 7046 -9748 -1969 4400 2321 10439 -5782 -3623 -3249 2900 6623 9239 -10633 -9659 -381 5812 4179 -2216 -3853 14810 -13613 14112 -6073 6005 -7032 -2690 -5862 14820 -5446 -8653 785 7442 8711 5752 -12316 8811 2729 14664 3631 12189 -6619 4127 -3826 -4919 -4508 8206 -1155 3237 5347 -898 -1985 -272 -4463 -2137 -5978 -6496 7279 4454 -1704 7803 2802 -12962 5914 -18600 9272 -6186 9690 5168 -4264 -18 -3453 -8399 9333 8202 6742 -2041 -2539 5270 -33 8349 -4389 -4621 6422 4824 413 -1006 6327 -5379 13394 -7890 9070 1608 3724 -9181 -11336 4928 2645 2700 676 444 6477 -4969 -6596 1565 2954 5373 -1399 2911 -8440 -4735 -11270 -5266 -2883 9757 -11225 2742 703 5306 1290 4421 -17106 14971 5106 11041 -1671 11354 -4637 -1799 -14975 5666 9235 SO 20191027T092515.0Z 7239.392535 364 1 32.00 2 89.13 107.49 90.57 95.85 0.00 1 0.00 1 0 29 5.835e-02 5.737e-02 4.903e-02 4.808e-02 -2.394925e+02 2.723318e+03 2.749803e+01 -6.000000e+00 3.081573e+03 276.55 -2.00 20.00 -2.00 505.16 0.00e+00 2.657702e-03 1.293734e-03 8.313191e-05 -6.000000e+00 1.596670e-03 276.55 -2.00 20.00 -2.00 499.76 0.00e+00 2.141515e+00 9.781270e-01 1.428495e-02 -6.000000e+00 1.157380e+00 229.47 -2.00 3.76 -2.00 501.42 0.00e+00 19.030 0.081 489.00 513.00 1 7.9181e+00 7.5154e-02 2.9326e-02 -6.0000e+00 8.8198e-02 1.4952e-01 1.9673e-02 1.6252e-03 -6.0000e+00 2.3412e-02 4.0130e-05 9.0855e-03 4.2838e-03 2.8066e-05 -6.0000e+00 5.3419e-03 1.7069e-03 -2.7289e-04 12 8 8 10 0 0 -190.77 21.12 4.33 0.00171 0.06473 8 2 1 4 0 4000.000 25.28 19.99 21.12 3928 -12052 10801 -1453 6461 -5526 902 -9100 10716 62 430 -730 10094 2832 -466 -2610 7658 1088 1725 -9770 2725 -3477 2397 2234 -486 1749 4186 5062 -9252 5102 -1037 -3123 -4573 -6459 936 10281 3129 -8226 -6696 1865 -4860 4805 1898 -1108 -1201 2084 -1031 3108 -937 13330 -1529 -6121 -6397 3587 -4120 18571 1751 9089 5162 206 3730 3920 -5159 2802 628 1302 -6621 -2676 11339 -269 6070 -4813 3170 -4209 13791 -3648 -3992 -4104 2044 -5426 -2805 -9930 1011 -5355 -3718 -4959 -5351 165 -8167 3739 15070 4583 4707 826 7823 739 10357 -6431 6162 -4763 -9823 1097 6486 -3236 8580 2923 5455 -2866 -2157 1372 162 5194 5763 -736 317 -1644 1838 -1933 -1333 3876 795 1444 -3932 11834 -10230 6466 -5025 2383 2263 8490 -13896 -7236 -2914 -56 -1873 1009 -4590 -451 -6567 3994 -1476 6548 2175 6795 -1558 2569 -706 6433 -6077 6305 3917 -14431 10685 -1682 7077 -6963 1084 -11212 11652 68 463 -783 9546 2843 -481 -2771 7465 1163 1876 -12002 2953 -4007 2606 2445 -549 1933 4490 5301 -10829 4992 -1063 -3293 -5021 -7514 1038 10394 3357 -9747 -7716 1960 -5477 4962 2042 -1245 -1363 2289 -1158 3300 -1015 12172 -1568 -6410 -6653 3419 -4374 16218 1846 8959 5275 220 3853 4063 -5870 2934 665 1345 -7270 -2783 10108 -265 5565 -4936 3033 -4393 12094 -3767 -4050 -4090 1897 -5407 -2735 -10471 960 -5453 -3759 -5103 -5527 161 -8642 3523 12778 4384 4571 838 7343 681 9157 -6081 4997 -4215 -9090 923 5325 -3027 7246 2597 4644 -2603 -1931 1195 146 4526 5081 -701 301 -1598 1732 -1886 -1278 3469 722 1288 -3692 9557 -10361 5548 -4836 2125 2018 7113 -14448 -6915 -2618 -48 -1639 869 -4278 -411 -6452 3562 -1396 5729 1998 5991 -1494 2343 -651 5368 -5623 5134 SO 20191027T092905.0Z 7239.395197 368 1 32.00 2 88.49 106.81 89.92 95.20 0.00 1 0.00 1 0 15 4.295e-02 4.274e-02 3.659e-02 3.597e-02 6.029395e+03 2.313588e+03 3.487088e+02 -6.000000e+00 2.267916e+03 276.55 -2.00 20.00 -2.00 505.11 0.00e+00 1.583711e-03 9.664798e-04 1.223173e-04 -6.000000e+00 1.173747e-03 276.55 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