File name: Pandora124s1_ComodoroRivadavia_20191105_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T090611.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20191105_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20191105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191105T090750.0Z 7248.380440 274 1 32.00 2 89.79 112.50 111.29 213.46 0.00 1 0.00 1 0 15 6.260e-02 6.093e-02 4.968e-02 4.884e-02 3.656577e+03 3.105318e+03 2.514728e+02 -6.000000e+00 3.311985e+03 276.95 -2.00 20.00 -2.00 505.26 0.00e+00 1.766989e-03 1.313022e-03 9.030234e-05 -6.000000e+00 1.711525e-03 276.95 -2.00 20.00 -2.00 500.05 0.00e+00 3.376731e+00 9.876736e-01 3.784748e-02 -6.000000e+00 1.233755e+00 229.97 -2.00 3.76 -2.00 501.67 0.00e+00 20.263 0.098 489.00 513.00 1 7.6774e+00 7.5574e-02 3.2024e-02 -6.0000e+00 9.4160e-02 9.8885e-02 1.9381e-02 1.9194e-03 -6.0000e+00 2.4761e-02 3.9362e-05 -3.0043e-04 4.2602e-03 3.5957e-05 -6.0000e+00 5.7242e-03 -5.9877e-02 6.6404e-04 12 8 8 10 0 0 -355.99 21.34 4.27 -0.05988 -0.06196 8 2 1 4 0 4000.000 25.47 20.04 21.34 -2278 -932 -6582 1600 6220 -235 2529 738 -2872 -5083 4870 -7922 -2800 -10380 9644 -11438 7328 -2702 14081 3497 6716 3608 -5814 10392 5224 -3455 4306 1723 -1829 46 -1448 -527 4847 -3627 -1797 4869 -8669 1957 -1302 2948 -1567 10404 3320 10636 -2602 -3281 -2578 10821 -4230 1081 -13933 6004 -8481 -182 -1330 -5092 -1531 14958 -428 8772 -709 -4166 -2300 5973 -5241 9716 -1663 3451 2799 3587 2085 -6990 -109 -619 5813 9268 5871 -5536 8334 5945 -8561 -442 -1072 -4325 -5442 -9445 12845 78 10973 -7153 -180 -10222 11129 -10846 8478 413 13379 -2282 7591 -9301 -1835 -7973 -2717 9136 1668 -2633 -402 -3500 879 -4094 17385 -2071 6688 4854 -460 -1230 -4958 10372 -5376 4769 -4923 9642 -1005 8672 -5281 2175 2277 7533 -4029 665 -2433 4496 -9200 5003 -2400 2521 -2113 3851 -9298 -135 175 1425 4945 -1890 -4246 7371 -5012 -1979 -5038 6197 -2334 -966 -7507 1742 6623 -273 2681 801 -3213 -5726 4894 -8924 -2948 -11654 8840 -13052 7067 -2964 13373 3720 6922 3839 -6806 10405 5538 -3994 4581 1851 -1972 47 -1487 -541 4853 -4112 -2050 5197 -10466 2096 -1423 3071 -1713 10188 3532 10649 -2998 -3805 -2942 10636 -4734 1114 -16156 5570 -9022 -180 -1381 -5661 -1674 13931 -464 8621 -767 -4692 -2549 6068 -5885 9227 -1739 3379 2720 3407 1995 -7359 -108 -627 5542 8427 5403 -5604 7271 5296 -8856 -425 -1042 -4378 -5629 -10222 11112 76 9614 -7531 -179 -10552 10119 -11381 7771 373 11130 -2005 5890 -8394 -1537 -7249 -2433 7557 1516 -2493 -367 -3242 775 -3834 13371 -1968 5898 4397 -442 -1198 -5051 9076 -5457 4304 -4813 8042 -931 7352 -5181 1985 2078 6514 -3911 616 -2304 3904 -9025 4224 -2190 2232 -2008 3514 -9820 -131 171 1383 4665 -1918 -4412 6752 -5088 -1901 -4908 5402 SO 20191105T091153.0Z 7248.383252 278 1 32.00 2 89.14 111.78 111.67 212.54 0.00 1 0.00 1 0 15 1.627e-02 1.620e-02 1.286e-02 1.277e-02 9.576403e+03 8.637761e+02 6.035477e+02 -6.000000e+00 8.608352e+02 276.95 -2.00 20.00 -2.00 505.44 0.00e+00 7.344582e-04 3.418928e-04 6.086003e-05 -6.000000e+00 4.452007e-04 276.95 -2.00 20.00 -2.00 500.67 0.00e+00 1.579535e+00 2.521050e-01 8.299138e-02 -6.000000e+00 3.218479e-01 229.97 -2.00 3.76 -2.00 502.24 0.00e+00 19.036 0.081 489.00 513.00 1 6.5971e+00 1.9212e-02 3.0078e-02 -6.0000e+00 2.4546e-02 3.9220e-02 4.8932e-03 2.4745e-03 -6.0000e+00 6.4853e-03 1.5881e-04 -3.7973e-04 1.0997e-03 7.0989e-05 -6.0000e+00 1.4903e-03 -2.7788e-02 1.9533e-04 12 8 8 10 0 0 30.33 21.34 1.74 -0.02779 -0.03042 8 2 1 4 0 4000.000 25.47 19.97 21.34 403 -2536 -555 -1066 -235 -3056 2221 397 2156 156 -768 -2720 -1190 -824 876 -3038 1415 -2445 1570 -1198 1501 543 2110 -1179 155 -1635 2570 2778 2577 -3212 -1415 -1377 1161 -576 2819 -274 301 -1558 -267 -1572 2202 1074 2018 -360 31 2457 1585 1542 -1092 486 2011 2521 -2113 178 2398 70 -294 1761 -2957 -1771 -2400 2271 -888 119 810 1538 -839 2334 -2600 1047 -2138 636 -2977 -85 710 249 -2477 -1521 -2212 1976 361 349 -264 3622 350 -16 218 -1736 -456 -120 478 14 997 -405 -1454 1103 153 -1394 -498 -1504 2476 -1659 -1405 -2110 2035 -1354 2217 -1018 159 -1702 3286 -2284 1743 781 2649 -877 4209 141 1103 -416 38 -1605 1678 -360 251 -1581 815 -402 2722 -435 1458 1084 -864 -190 -395 -1563 -559 600 -655 1842 591 -5 -1397 -551 -746 1489 -1759 -277 -1590 -961 339 -2243 -500 -1003 -225 -3083 2170 400 2129 155 -761 -2716 -1152 -785 817 -2966 1344 -2483 1577 -1254 1534 561 2149 -1247 163 -1754 2636 2814 2548 -3250 -1382 -1351 1137 -597 2920 -296 320 -1665 -278 -1649 2226 1107 2087 -387 33 2602 1685 1620 -1157 494 1953 2374 -2058 171 2323 72 -310 1841 -3239 -1911 -2608 2372 -962 128 857 1592 -874 2325 -2691 1031 -2155 626 -3072 -86 725 254 -2367 -1520 -2042 1876 324 316 -243 3238 328 -15 207 -1677 -433 -114 453 14 967 -398 -1415 1016 138 -1240 -428 -1285 2027 -1444 -1271 -2024 1947 -1358 2135 -999 152 -1673 3122 -2330 1725 785 2622 -905 4176 148 1142 -431 39 -1623 1626 -357 250 -1611 813 -406 2662 -440 1438 1057 -845 -183 -383 -1559 -566 614 -690 1920 630 -5 -1545 -608 -825 1601 -1925 -292 -1669 -998 SO 20191105T091547.0Z 7248.385961 282 1 32.00 2 88.51 111.09 112.02 211.65 0.00 1 0.00 1 0 15 8.613e-03 8.563e-03 7.163e-03 7.141e-03 1.091285e+04 4.756071e+02 7.436040e+02 -6.000000e+00 4.554772e+02 276.95 -2.00 20.00 -2.00 505.35 0.00e+00 1.206944e-03 1.935854e-04 7.967308e-05 -6.000000e+00 2.356904e-04 276.95 -2.00 20.00 -2.00 500.64 0.00e+00 1.181333e+00 1.404586e-01 7.591630e-02 -6.000000e+00 1.705311e-01 229.97 -2.00 3.76 -2.00 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