File name: Pandora124s1_ComodoroRivadavia_20191106_L2Fit_fwvt1c2d20190219p1-8.txt File generation date: 20251117T090630.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v5d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20191106_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20191106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0686 492.1895 492.3103 492.4311 492.5519 492.6727 492.7934 492.9142 493.0349 493.1556 493.2763 493.3970 493.5176 493.6383 493.7589 493.8795 494.0001 494.1206 494.2412 494.3617 494.4823 494.6028 494.7232 494.8437 494.9642 495.0846 495.2050 495.3254 495.4458 495.5662 495.6865 495.8069 495.9272 496.0475 496.1678 496.2881 496.4083 496.5285 496.6488 496.7690 496.8891 497.0093 497.1295 497.2496 497.3697 497.4898 497.6099 497.7300 497.8500 497.9700 498.0901 498.2101 498.3300 498.4500 498.5700 498.6899 498.8098 498.9297 499.0496 499.1694 499.2893 499.4091 499.5289 499.6487 499.7685 499.8883 500.0080 500.1277 500.2474 500.3671 500.4868 500.6065 500.7261 500.8457 500.9654 501.0849 501.2045 501.3241 501.4436 501.5631 501.6827 501.8021 501.9216 502.0411 502.1605 502.2799 502.3993 502.5187 502.6381 502.7575 502.8768 502.9961 503.1154 503.2347 503.3540 503.4732 503.5925 503.7117 503.8309 503.9501 504.0692 504.1884 504.3075 504.4266 504.5457 504.6648 504.7839 504.9029 505.0219 505.1409 505.2599 505.3789 505.4979 505.6168 505.7358 505.8547 505.9736 506.0924 506.2113 506.3301 506.4490 506.5678 506.6865 506.8053 506.9241 507.0428 507.1615 507.2802 507.3989 507.5176 507.6362 507.7549 507.8735 507.9921 508.1107 508.2293 508.3478 508.4663 508.5848 508.7033 508.8218 508.9403 509.0587 509.1772 509.2956 509.4140 509.5323 509.6507 509.7691 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191106T090628.0Z 7249.379491 257 1 32.00 2 89.79 112.96 109.54 225.27 0.00 1 0.00 1 0 15 5.722e-02 5.523e-02 4.994e-02 4.847e-02 1.772514e+03 2.943486e+03 2.521885e+02 -6.000000e+00 3.028210e+03 276.99 -2.00 20.00 -2.00 505.11 0.00e+00 2.325194e-03 1.300390e-03 1.300497e-04 -6.000000e+00 1.565115e-03 276.99 -2.00 20.00 -2.00 499.57 0.00e+00 3.950925e+00 1.009900e+00 3.027142e-02 -6.000000e+00 1.129484e+00 230.03 -2.00 3.76 -2.00 501.23 0.00e+00 20.261 0.098 489.00 513.00 1 7.6304e+00 7.7416e-02 3.1987e-02 -6.0000e+00 8.6180e-02 1.4320e-01 2.0140e-02 1.8105e-03 -6.0000e+00 2.2704e-02 3.9457e-05 6.3352e-04 4.2053e-03 5.1779e-05 -6.0000e+00 5.2363e-03 -5.8040e-02 5.4738e-04 12 8 8 10 0 0 22.08 21.45 2.82 -0.05804 -0.05365 8 2 1 4 0 4000.000 25.58 20.02 21.45 -2484 915 1773 3179 -2535 6917 253 4427 -6601 9755 2584 -892 -6213 2964 8778 9054 -5836 3804 -7579 -1300 -1335 5830 921 -817 977 -3756 -2789 -1812 -1461 -9212 -1040 -684 5432 -6269 8685 -2109 1399 -3884 4368 -3029 3868 1330 12674 -4974 -440 -2074 839 -6753 8513 1990 3336 -1410 12327 -6479 -6148 -6702 2885 -3374 6804 1672 5179 -9589 2953 -5507 2275 -986 6540 -581 -1369 9713 -1032 6980 -4204 8343 712 -3109 -8556 4429 -5978 -4926 363 -3634 -6602 2742 2431 -1739 -411 12567 5142 6113 -11409 11180 674 1486 3630 -1377 -2241 3304 -270 7630 -250 -4372 -4639 877 -2727 -6127 4578 788 -7275 5510 14693 -6081 2493 -4345 -2679 5380 6276 6209 -1263 -11050 12622 -6609 -3472 -4215 2138 1525 4341 -2812 6959 -1357 4470 -11662 8632 -6332 9862 464 460 -11840 6169 -6370 4109 -2229 9869 -2575 10377 1967 -574 -197 2663 5009 -2693 981 1958 3585 -3100 7857 313 5273 -8054 10771 3016 -980 -7082 3042 8466 8765 -6673 4058 -9275 -1506 -1546 6283 1042 -946 1117 -4500 -3291 -2085 -1622 -10668 -1094 -722 5537 -7466 9138 -2474 1563 -4512 4612 -3420 4083 1453 12500 -5923 -505 -2417 941 -8042 8521 2064 3302 -1427 10762 -6911 -6738 -7614 3036 -3796 6885 1771 5298 -11420 3106 -6276 2369 -1041 6283 -590 -1380 8622 -1011 6324 -4300 7620 705 -3157 -8971 3996 -5918 -4804 337 -3532 -6633 2524 2265 -1697 -395 10559 4639 5471 -12253 9720 660 1444 3408 -1333 -2136 2897 -239 6104 -200 -3708 -4076 755 -2479 -5736 3789 666 -6613 4448 11015 -5714 2182 -4112 -2508 4672 5428 5371 -1166 -11057 9805 -6143 -3121 -3846 1842 1324 3666 -2547 5712 -1210 3730 -11234 6676 -5628 7460 392 398 -11808 5210 -6158 3596 -2087 8236 -2446 8659 1768 -518 -172 2222 4078 SO 20191106T091032.0Z 7249.382315 261 1 32.00 2 89.14 112.23 110.03 224.40 0.00 1 0.00 1 0 15 3.798e-02 3.649e-02 3.961e-02 3.871e-02 3.176807e+03 2.404645e+03 4.750284e+02 -6.000000e+00 2.009029e+03 276.99 -2.00 20.00 -2.00 505.10 0.00e+00 1.006512e-03 1.035866e-03 6.563196e-05 -6.000000e+00 1.038954e-03 276.99 -2.00 20.00 -2.00 499.64 0.00e+00 2.767565e+00 8.012489e-01 4.119070e-02 -6.000000e+00 7.508973e-01 230.03 -2.00 3.76 -2.00 501.29 0.00e+00 19.033 0.081 489.00 513.00 1 7.6768e+00 6.1367e-02 2.9388e-02 -6.0000e+00 5.7271e-02 1.4234e-01 1.5921e-02 1.6661e-03 -6.0000e+00 1.5128e-02 4.9767e-05 2.1454e-03 3.3725e-03 6.4022e-05 -6.0000e+00 3.4777e-03 -1.4082e-03 5.4803e-05 12 9 8 11 8 0 8.65 21.45 3.34 -0.00141 0.01347 8 2 1 4 0 4000.000 25.58 19.98 21.45 971 -2484 3568 771 129 2745 1805 114 -1954 -1713 -1691 -169 -3765 1531 6042 2313 -109 -1133 1586 88 -4202 1896 -1464 492 -1349 6433 -3029 2221 -4316 -923 -1858 6316 -5406 6322 621 -2780 -190 -57 -2196 2377 4417 1848 -1620 7102 -5019 -3312 2284 3446 4172 1565 -350 11255 1561 -2946 1229 -7206 134 -137 -1871 2541 -1072 -3278 -1457 -6284 -250 -1762 1219 -1457 1833 566 -3334 6179 -823 -4977 -1810 -1751 -971 -259 -2930 -6643 -1487 4967 1958 1770 3446 5018 1242 -1211 -8698 800 2706 2547 2925 7204 -1291 4174 8211 -5234 374 1753 -3924 -6903 -7050 -3066 -2555 1585 -5198 -2836 1215 1890 4754 1971 1700 -5361 -3208 8755 -4344 369 2783 2041 -355 9650 734 409 3509 4284 -992 2793 -778 6439 -4313 6862 -5056 -169 5149 7045 -8357 3200 -1157 -1573 2321 2770 369 1729 1460 -866 668 -7517 -588 -923 1001 -2708 3800 875 151 3193 2156 140 -2427 -2089 -2031 -198 -4131 1703 6397 2361 -116 -1252 1749 100 -4953 2102 -1678 555 -1559 6869 -3535 2423 -4873 -973 -1946 6136 -6056 6547 699 -3244 -214 -63 -2448 2511 4575 1978 -1815 7376 -5930 -3845 2486 3649 4297 1607 -355 9884 1494 -2982 1230 -8094 142 -147 -2035 2632 -1151 -3615 -1581 -7131 -264 -1856 1223 -1480 1775 547 -3317 5607 -809 -5170 -1832 -1752 -944 -245 -2812 -6589 -1405 4434 1811 1652 3197 4611 1185 -1180 -9110 763 2550 2437 2824 6662 -1281 3836 7066 -5008 330 1493 -3526 -6040 -6398 -2782 -2360 1404 -4858 -2543 1037 1612 4005 1735 1519 -5184 -3051 7423 -4225 343 2503 1819 -318 7712 638 359 3004 3644 -890 2406 -694 5338 -3949 5521 -4506 -142 4101 5592 -7924 2756 -1056 -1457 2081 2484 340 1583 1341 -807 600 -7148 -511 -803 SO 20191106T091427.0Z 7249.385035 265 1 32.00 2 88.50 111.54 110.50 223.56 0.00 1 0.00 1 0 22 3.877e-02 3.798e-02 3.091e-02 3.036e-02 4.805259e+03 1.912228e+03 5.384190e+02 -6.000000e+00 2.050833e+03 276.99 -2.00 20.00 -2.00 505.11 0.00e+00 4.282982e-04 8.152030e-04 3.965475e-05 -6.000000e+00 1.061109e-03 276.99 -2.00 20.00 -2.00 499.74 0.00e+00 1.278957e+00 6.261687e-01 1.313204e-02 -6.000000e+00 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