File name: Pandora124s1_ComodoroRivadavia_20191211_L2Fit_fout2c2d20190219p1-8.txt File generation date: 20251117T090842.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 124 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora124_OF_v6d20160603.txt Instrument calibration file used: Pandora124s1_CF_v2d20190219.txt Level 1 file used: Pandora124s1_ComodoroRivadavia_20191211_L1_smca1c2d20190219p1-8.txt Full location name: CITEDEF/SMN Comodoro Rivadavia Short location name: ComodoroRivadavia Country of location: Argentina Location latitude [deg]: -45.7833 Location longitude [deg]: -67.4500 Location altitude [m]: 46 Local noon date: 20191211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.1144 305.2551 305.3958 305.5365 305.6772 305.8179 305.9586 306.0993 306.2399 306.3806 306.5212 306.6619 306.8025 306.9431 307.0837 307.2242 307.3648 307.5054 307.6459 307.7865 307.9270 308.0675 308.2080 308.3485 308.4890 308.6295 308.7699 308.9104 309.0508 309.1913 309.3317 309.4721 309.6125 309.7529 309.8932 310.0336 310.1739 310.3143 310.4546 310.5949 310.7352 310.8755 311.0158 311.1561 311.2963 311.4366 311.5768 311.7171 311.8573 311.9975 312.1377 312.2779 312.4180 312.5582 312.6983 312.8385 312.9786 313.1187 313.2588 313.3989 313.5390 313.6791 313.8191 313.9592 314.0992 314.2393 314.3793 314.5193 314.6593 314.7993 314.9392 315.0792 315.2191 315.3591 315.4990 315.6389 315.7788 315.9187 316.0586 316.1984 316.3383 316.4781 316.6180 316.7578 316.8976 317.0374 317.1772 317.3170 317.4568 317.5965 317.7363 317.8760 318.0157 318.1554 318.2951 318.4348 318.5745 318.7141 318.8538 318.9934 319.1331 319.2727 319.4123 319.5519 319.6915 319.8311 319.9706 320.1102 320.2497 320.3892 320.5287 320.6683 320.8077 320.9472 321.0867 321.2262 321.3656 321.5050 321.6445 321.7839 321.9233 322.0627 322.2020 322.3414 322.4808 322.6201 322.7594 322.8988 323.0381 323.1774 323.3167 323.4559 323.5952 323.7344 323.8737 324.0129 324.1521 324.2913 324.4305 324.5697 324.7089 324.8480 324.9872 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191211T100225.8Z 7284.418354 238 1 5.63 2 77.14 109.86 107.99 280.38 0.00 1 0.00 1 0 25 2.331e-01 6.757e-03 1.566e-01 3.800e-03 5.958943e-01 2.004645e-03 7.183016e-03 -6.000000e+00 1.357111e-01 231.95 -2.00 3.76 -2.00 320.29 0.00e+00 1.619335e-03 7.144396e-04 5.773420e-04 -6.000000e+00 5.907640e-03 278.54 -2.00 20.00 -2.00 319.72 0.00e+00 4.373 0.001 302.00 328.00 3 2.1091e-02 5.9442e-03 5.5040e-02 -6.0000e+00 3.4161e-01 7.3003e-02 7.4411e-03 3.4004e-02 -6.0000e+00 3.7091e-01 -3.0902e-02 7.1153e-03 1.7141e-02 -6.0000e+00 2.1875e-01 4.9617e-03 3.6004e-03 5.2973e-03 -6.0000e+00 9.1026e-02 3.4893e-03 -3.3204e-04 1.0582e-04 5.7706e-05 -6.0000e+00 6.5605e-03 -6.8591e-03 7.0172e-05 12 9 1 12 1 1 70.26 22.46 0.22 -0.00686 -0.00935 17 34 1 5 0 303.462 26.51 19.99 22.46 -130262 12167 -123744 900000 -113049 -16673 -88165 900000 -51442 35941 -62631 24765 -41249 24343 -10976 72233 -23991 14536 -13070 12957 -11221 -15373 -11992 -20013 -21320 -9489 -14224 -9812 -1332 -5456 2018 -7644 8974 -9476 -368 -6743 1835 -4763 3770 -3054 5113 -4852 2960 -2740 2305 -2101 3369 -2284 4456 -866 3911 -1395 3893 845 1127 309 1910 -614 2334 129 3051 2322 2497 1328 1645 611 36 534 1136 807 495 530 -1015 854 -1672 -168 -99 136 -342 511 -554 -844 -2329 -1051 -1758 -498 -1023 539 318 739 173 304 -780 1201 243 522 558 724 -151 -407 -585 -400 209 -90 -932 -1347 -885 -202 103 -232 628 94 277 418 282 671 762 -11 -310 -430 -220 -37 863 -147 194 200 425 533 243 -73 276 -474 163 -144 -411 -337 269 -82 -25 -215 168 -137 177 -1930 50 -2063 900000 -1508 -86 -1045 900000 -553 173 -859 165 -672 262 -207 696 -676 307 -392 317 -358 -518 -418 -830 -972 -404 -638 -407 -51 -239 97 -479 542 -713 -24 -485 137 -462 413 -423 725 -812 479 -479 389 -379 587 -434 827 -183 877 -367 965 233 327 94 587 -192 690 39 937 798 970 575 726 263 15 237 562 459 281 311 -592 501 -915 -82 -45 64 -183 319 -371 -639 -1935 -914 -1523 -454 -982 521 305 672 147 261 -652 1026 217 536 611 892 -200 -530 -706 -468 227 -102 -1059 -1619 -1118 -271 140 -352 1030 150 436 669 424 969 1116 -17 -512 -690 -372 -61 1339 -222 279 296 610 753 386 -122 495 -901 303 -286 -871 -705 571 -177 -54 -442 344 -266 335 SU 20191211T101214.8Z 7284.425171 241 1 49.60 2 75.52 108.24 109.62 278.79 0.00 1 0.00 1 0 25 1.107e-01 4.511e-03 2.906e-02 8.090e-04 5.402110e-01 4.214301e-04 6.452554e-03 -6.000000e+00 6.407619e-02 231.95 -2.00 3.76 -2.00 320.46 0.00e+00 1.341904e-03 1.555109e-04 5.862099e-04 -6.000000e+00 2.752987e-03 278.54 -2.00 20.00 -2.00 319.87 0.00e+00 3.916 0.001 302.00 328.00 3 -8.6741e-01 1.2735e-03 4.9612e-02 -6.0000e+00 1.6101e-01 4.3974e-02 1.6038e-03 3.1173e-02 -6.0000e+00 1.7470e-01 -5.5122e-03 1.5354e-03 1.5388e-02 -6.0000e+00 1.0346e-01 -6.2146e-03 7.7263e-04 4.8044e-03 -6.0000e+00 4.3102e-02 1.3992e-02 -3.7904e-04 2.3390e-05 4.8366e-05 -6.0000e+00 3.0277e-03 -6.8294e-03 2.7630e-05 10 0 0 10 0 0 92.82 22.46 0.29 -0.00683 -0.00968 568 119 1 5 0 87.307 26.51 20.00 22.46 -46742 -16083 -40301 -15970 -56263 -29480 -44488 -35706 -37988 -28603 -29127 -18558 -18996 -12090 -15046 -10274 -12170 -8236 -6756 -5218 -6690 -2917 -4922 -3270 -6466 -7837 -6577 -5826 -6790 -3827 -3729 -2211 -1355 -4086 -3943 -4226 -2566 -2606 -1376 -2671 -1077 -1883 -1287 -1511 -183 -284 -174 -483 135 359 1550 934 1668 797 724 835 -69 261 474 875 1354 1594 1708 1270 384 586 596 876 1282 565 280 128 -125 35 -66 296 153 249 479 -173 -532 -975 -1652 -1038 -799 -565 -253 83 321 454 629 713 738 1115 523 429 504 398 -198 -344 -388 -228 190 75 -1122 -1068 -892 -639 -223 -138 -162 -204 30 67 359 647 462 196 -97 -465 -467 -39 116 254 544 325 801 1051 327 108 -25 33 114 100 -128 -385 74 -16 -181 -134 -75 -37 13 -342 -108 -359 -106 -519 -212 -414 -352 -432 -316 -340 -224 -286 -213 -332 -250 -334 -238 -206 -166 -220 -94 -172 -123 -271 -349 -290 -245 -286 -170 -193 -131 -90 -288 -265 -291 -197 -243 -155 -358 -157 -295 -209 -250 -30 -48 -30 -85 24 69 326 219 422 219 209 250 -21 80 141 259 418 543 653 534 165 241 240 363 593 301 162 76 -74 19 -33 134 65 108 233 -99 -352 -727 -1215 -804 -661 -498 -232 78 297 400 514 595 589 916 438 412 552 491 -260 -443 -463 -245 192 79 -1282 -1285 -1130 -858 -325 -202 -257 -335 49 101 555 961 697 311 -150 -753 -750 -60 188 397 811 465 1105 1520 531 178 -45 61 221 206 -279 -885 159 -35 -395 -304 -161 -76 26 SU 20191211T102215.8Z 7284.432127 244 1 49.62 2 73.85 106.59 111.29 277.15 0.00 1 0.00 1 0 25 6.400e-02 4.568e-03 1.480e-02 6.014e-04 4.950897e-01 3.121848e-04 6.032836e-03 -6.000000e+00 3.704308e-02 231.95 -2.00 3.76 -2.00 320.09 0.00e+00 6.932338e-04 1.012575e-04 4.356640e-04 -6.000000e+00 1.591591e-03 278.54 -2.00 20.00 -2.00 319.47 0.00e+00 3.536 0.000 302.00 328.00 3 -9.6750e-01 9.1312e-04 4.5054e-02 -6.0000e+00 9.3081e-02 4.2612e-02 1.1060e-03 2.8352e-02 -6.0000e+00 1.0099e-01 -3.0615e-03 9.8125e-04 1.3952e-02 -6.0000e+00 5.9811e-02 -6.9781e-03 5.0419e-04 4.0466e-03 -6.0000e+00 2.4917e-02 2.3284e-02 -4.2841e-04 1.7509e-05 4.4584e-05 -6.0000e+00 1.7504e-03 -6.7250e-03 2.3862e-05 10 0 0 10 0 0 98.71 22.45 0.29 -0.00673 -0.00994 783 164 1 5 0 63.284 26.41 19.99 22.45 -18625 -25309 -16461 -27253 -18929 -22030 -17977 -25043 -12159 -21898 -18554 -15178 -10419 -11273 -3988 -6109 -4766 -4119 -2938 -4256 -4768 -4018 -2493 -4554 -2343 -3862 -3480 -4050 -4280 -1406 -1033 179 -94 -2820 -3335 -3198 -1781 -768 -1495 -1545 -1623 -1308 -1283 -822 -386 -335 -713 57 -631 606 931 915 840 1131 540 1000 382 447 144 845 1126 1473 1566 1225 220 609 339 696 1334 622 152 14 -92 -125 -3 306 186 444 462 -359 -607 -1099 -1561 -1218 -742 -582 -229 -90 316 289 679 551 774 1058 743 410 576 297 -230 -341 -325 -281 251 15 -1063 -998 -819 -684 -64 -48 -11 -152 72 79 341 592 487 233 -150 -511 -459 -82 145 290 485 382 869 1151 277 160 -61 58 -57 99 -185 -272 79 57 -170 -117 -115 -88 -77 -192 -313 -193 -336 -199 -242 -211 -364 -175 -369 -314 -281 -225 -302 -120 -214 -180 -168 -126 -195 -224 -189 -123 -250 -136 -237 -212 -238 -247 -84 -71 14 -8 -260 -295 -288 -179 -92 -221 -268 -310 -264 -269 -174 -82 -72 -155 12 -143 144 242 262 261 375 189 360 142 164 52 301 419 601 713 608 111 291 158 332 705 343 91 9 -56 -72 -2 159 90 217 251 -229 -404 -823 -1263 -1039 -675 -563 -232 -93 322 281 609 458 611 854 666 419 669 387 -292 -425 -408 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