File name: Pandora113s1_Cordoba_20251021_L2Fit_fwvt1c2d20230530p1-8.txt File generation date: 20251022T041239.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 113 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora113_OF_v4d20210811.txt Instrument calibration file used: Pandora113s1_CF_v2d20230530.txt Level 1 file used: Pandora113s1_Cordoba_20251021_L1_smca1c2d20230530p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20251021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing lab cal analysis from 2021 using new measurements + creating OoB CF First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0619 492.1804 492.2989 492.4174 492.5359 492.6544 492.7728 492.8912 493.0097 493.1280 493.2464 493.3648 493.4831 493.6014 493.7197 493.8380 493.9563 494.0745 494.1928 494.3110 494.4292 494.5474 494.6655 494.7837 494.9018 495.0199 495.1380 495.2561 495.3742 495.4922 495.6102 495.7282 495.8462 495.9642 496.0822 496.2001 496.3180 496.4359 496.5538 496.6717 496.7895 496.9074 497.0252 497.1430 497.2608 497.3785 497.4963 497.6140 497.7317 497.8494 497.9671 498.0847 498.2024 498.3200 498.4376 498.5552 498.6728 498.7903 498.9079 499.0254 499.1429 499.2604 499.3778 499.4953 499.6127 499.7301 499.8475 499.9649 500.0823 500.1996 500.3169 500.4342 500.5515 500.6688 500.7861 500.9033 501.0205 501.1377 501.2549 501.3721 501.4892 501.6064 501.7235 501.8406 501.9576 502.0747 502.1918 502.3088 502.4258 502.5428 502.6598 502.7767 502.8936 503.0106 503.1275 503.2444 503.3612 503.4781 503.5949 503.7117 503.8285 503.9453 504.0621 504.1788 504.2955 504.4122 504.5289 504.6456 504.7623 504.8789 504.9955 505.1121 505.2287 505.3453 505.4618 505.5783 505.6949 505.8114 505.9278 506.0443 506.1607 506.2772 506.3936 506.5100 506.6263 506.7427 506.8590 506.9753 507.0916 507.2079 507.3242 507.4404 507.5567 507.6729 507.7891 507.9052 508.0214 508.1375 508.2537 508.3698 508.4859 508.6019 508.7180 508.8340 508.9500 509.0660 509.1820 509.2980 509.4139 509.5298 509.6457 509.7616 509.8775 509.9934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-254: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 255-408: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251021T093822.2Z 9425.401646 32 1 10.43 2 88.87 102.07 86.41 103.02 0.00 1 0.00 1 0 22 6.895e-03 6.808e-03 3.185e-03 3.177e-03 2.137414e+04 2.377356e+02 1.395314e+03 -6.000000e+00 3.847129e+02 284.13 -2.00 20.00 -2.00 505.41 0.00e+00 2.270747e-03 8.803975e-05 1.379997e-04 -6.000000e+00 1.928150e-04 284.13 -2.00 20.00 -2.00 500.86 0.00e+00 1.528428e+00 6.152414e-02 1.278654e-01 -6.000000e+00 1.362509e-01 228.66 -2.00 3.11 -2.00 502.39 0.00e+00 18.341 0.051 489.00 513.00 1 5.4184e+00 4.7061e-03 2.8655e-02 -6.0000e+00 1.0448e-02 -4.1183e-02 1.1774e-03 3.5527e-03 -6.0000e+00 2.7156e-03 5.8455e-04 3.7263e-03 2.7748e-04 1.4826e-04 -6.0000e+00 7.1114e-04 9.7975e-03 1.5813e-04 12 9 9 12 1 1 999.00 22.52 5.06 0.00980 0.03564 2 4 1 4 0 3476.630 26.62 20.00 22.52 17.34 18.7 916.24 -2033 -1324 -602 -245 163 1091 144 419 1034 116 526 -740 -275 -440 -1065 -465 -464 91 3 676 198 502 363 524 575 1188 262 452 170 -928 -940 -626 -496 48 364 575 326 19 207 -339 61 -601 518 136 626 1388 468 853 537 -447 -754 -1398 -783 -1385 -484 -243 103 185 787 271 745 944 622 1107 184 383 94 625 -322 -417 -388 -1140 -463 -369 -694 -98 74 -402 -713 -480 -423 -881 -910 -168 186 66 -821 -409 263 -941 207 -56 1251 653 1148 1139 482 201 233 -576 -499 -2086 -1528 -447 -140 -12 133 82 -664 -547 -953 271 -49 -25 429 445 1415 1173 857 1469 469 212 -507 -393 -127 520 374 127 458 796 397 327 -171 -394 -341 -659 -663 -320 -28 -730 269 571 68 876 186 382 398 408 362 -591 -654 -1346 -1247 900000 -1827 -1214 -567 -231 158 1067 140 411 1004 113 502 -707 -266 -423 -1028 -437 -445 89 3 664 197 498 362 525 581 1196 265 453 168 -901 -896 -597 -482 48 363 581 330 20 206 -338 61 -606 523 140 650 1440 478 884 551 -454 -751 -1368 -768 -1366 -482 -242 105 188 801 278 761 966 643 1143 192 395 96 626 -322 -412 -391 -1119 -465 -365 -696 -99 74 -397 -695 -474 -414 -866 -898 -162 181 65 -825 -411 262 -942 204 -56 1233 654 1141 1108 468 188 216 -524 -447 -1886 -1390 -406 -134 -12 132 83 -677 -554 -968 274 -49 -25 435 452 1428 1200 873 1511 491 220 -521 -405 -129 524 381 128 461 800 401 330 -173 -395 -338 -653 -661 -324 -29 -754 280 604 74 930 200 414 431 440 388 -631 -689 -1420 -1320 900000 SQ 20251021T094118.1Z 9425.403682 36 1 38.40 2 88.26 101.69 85.81 102.67 0.00 1 0.00 1 0 22 5.056e-03 4.995e-03 6.885e-04 6.868e-04 1.906517e+04 5.096779e+01 1.257318e+03 -6.000000e+00 2.821112e+02 284.13 -2.00 20.00 -2.00 505.40 0.00e+00 2.075012e-03 1.905321e-05 1.288026e-04 -6.000000e+00 1.413768e-04 284.13 -2.00 20.00 -2.00 500.81 0.00e+00 1.448230e+00 1.337885e-02 1.156373e-01 -6.000000e+00 9.984554e-02 228.66 -2.00 3.11 -2.00 502.35 0.00e+00 16.752 0.039 489.00 513.00 1 4.1860e+00 1.0249e-03 2.5897e-02 -6.0000e+00 7.6574e-03 -3.3141e-02 2.5591e-04 3.2048e-03 -6.0000e+00 1.9884e-03 2.5234e-03 2.4446e-03 6.1057e-05 1.3202e-04 -6.0000e+00 5.2124e-04 -1.6161e-02 3.6897e-04 12 9 9 12 1 1 99.58 22.51 3.73 -0.01616 0.00080 44 15 1 4 0 853.170 26.62 20.00 22.51 17.43 18.6 916.48 -1347 -1001 -418 26 262 640 788 628 666 353 3 -345 -403 -682 -675 -567 -425 -119 176 311 170 463 267 469 573 638 572 121 1 -700 -806 -597 -405 41 280 209 122 96 -8 -135 -158 -39 196 418 792 654 556 425 244 -107 -505 -993 -1060 -935 -580 -278 142 182 394 295 636 637 692 639 385 471 216 202 -278 -363 -500 -584 -454 -242 -56 -6 -197 -515 -695 -575 -650 -636 -529 -255 -378 -104 -197 -215 -113 -246 127 296 645 738 848 817 534 562 32 -173 -768 -1176 -1118 -790 -360 -134 153 -177 -274 -385 -260 -177 -169 -7 125 497 603 917 1003 766 411 113 -30 -192 -54 404 378 372 234 197 62 127 -178 -305 -253 -607 -496 -330 -30 -23 91 443 373 573 347 400 375 287 108 -468 -699 -947 -765 900000 -1237 -940 -390 25 258 623 778 625 661 348 3 -334 -386 -649 -642 -542 -413 -118 173 310 171 465 269 475 584 652 583 123 1 -683 -774 -572 -396 42 281 213 125 97 -8 -135 -158 -40 199 428 819 682 581 441 251 -108 -500 -993 -1043 -917 -577 -275 144 189 411 300 644 648 707 656 396 480 218 207 -282 -366 -499 -580 -452 -243 -57 -6 -195 -518 -689 -562 -632 -618 -516 -250 -375 -102 -194 -212 -112 -242 124 288 633 730 838 793 517 523 29 -158 -693 -1057 -1015 -718 -342 -130 154 -176 -273 -382 -257 -177 -170 -7 128 508 617 945 1020 792 429 117 -30 -192 -55 408 375 372 236 199 63 129 -179 -304 -250 -597 -490 -331 -31 -24 94 463 396 615 377 425 399 305 114 -503 -741 -999 -809 900000 SQ 20251021T094414.7Z 9425.405726 40 1 33.26 2 87.65 101.31 85.21 102.31 0.00 1 0.00 1 0 22 4.250e-03 4.200e-03 1.618e-04 1.615e-04 1.676351e+04 1.175472e+01 1.115098e+03 -6.000000e+00 2.371247e+02 284.13 -2.00 20.00 -2.00 505.38 0.00e+00 1.767464e-03 4.470873e-06 1.124416e-04 -6.000000e+00 1.188471e-04 284.13 -2.00 20.00 -2.00 500.74 0.00e+00 1.316412e+00 3.151605e-03 1.016272e-01 -6.000000e+00 8.395719e-02 228.66 -2.00 3.11 -2.00 502.28 0.00e+00 15.127 0.028 489.00 513.00 1 1.5524e+00 2.4135e-04 2.3121e-02 -6.0000e+00 6.4384e-03 -2.6341e-02 6.0652e-05 2.8186e-03 -6.0000e+00 1.6727e-03 4.4696e-02 2.3757e-03 1.4621e-05 1.2102e-04 -6.0000e+00 4.3823e-04 1.1908e-02 1.7186e-04 12 9 1 12 1 1 62.43 22.51 3.14 0.01191 0.02839 558 209 1 4 0 59.490 26.62 20.00 22.51 17.49 18.6 916.77 -993 -672 -329 30 334 606 713 644 535 306 56 -197 -423 -523 -571 -465 -237 -59 142 205 228 298 383 476 574 586 368 123 -113 -491 -685 -566 -304 23 202 114 96 63 -61 -161 -143 -41 87 292 456 521 509 416 182 -132 -486 -780 -922 -846 -599 -190 21 184 269 326 432 495 520 535 472 351 207 29 -163 -317 -456 -506 -418 -261 -83 -51 -240 -408 -514 -557 -560 -534 -472 -370 -189 -113 -184 -240 -202 -67 60 247 476 627 675 660 591 421 84 -285 -702 -964 -962 -709 -364 -125 -102 -233 -295 -307 -185 -135 -139 -14 152 327 571 787 897 763 475 156 -36 -40 -10 344 336 259 213 223 114 123 -4 -163 -342 -424 -359 -208 -55 13 148 334 294 283 292 384 321 264 27 -257 -569 -742 -668 900000 -920 -636 -313 29 327 604 705 642 533 302 56 -195 -415 -509 -555 -454 -229 -58 144 205 230 301 388 484 587 601 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