File name: Pandora113s1_Cordoba_20260123_L2Fit_fout2c2d20230530p1-8.txt File generation date: 20260124T043524.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 113 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora113_OF_v4d20210811.txt Instrument calibration file used: Pandora113s1_CF_v2d20230530.txt Level 1 file used: Pandora113s1_Cordoba_20260123_L1_smca1c2d20230530p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20260123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing lab cal analysis from 2021 using new measurements + creating OoB CF First and last pixel inside fitting window: 208 352 Nominal wavelengths inside fitting window [nm]: 305.0013 305.1409 305.2805 305.4201 305.5597 305.6993 305.8388 305.9783 306.1179 306.2574 306.3969 306.5364 306.6758 306.8153 306.9548 307.0942 307.2336 307.3730 307.5124 307.6518 307.7912 307.9306 308.0699 308.2093 308.3486 308.4879 308.6272 308.7665 308.9058 309.0451 309.1844 309.3236 309.4628 309.6021 309.7413 309.8805 310.0197 310.1588 310.2980 310.4372 310.5763 310.7154 310.8545 310.9936 311.1327 311.2718 311.4109 311.5499 311.6890 311.8280 311.9670 312.1060 312.2450 312.3840 312.5230 312.6619 312.8009 312.9398 313.0787 313.2176 313.3565 313.4954 313.6343 313.7732 313.9120 314.0509 314.1897 314.3285 314.4673 314.6061 314.7449 314.8836 315.0224 315.1611 315.2998 315.4385 315.5773 315.7159 315.8546 315.9933 316.1319 316.2706 316.4092 316.5478 316.6864 316.8250 316.9636 317.1022 317.2407 317.3793 317.5178 317.6563 317.7948 317.9333 318.0718 318.2103 318.3487 318.4872 318.6256 318.7640 318.9024 319.0408 319.1792 319.3176 319.4560 319.5943 319.7326 319.8710 320.0093 320.1476 320.2859 320.4241 320.5624 320.7006 320.8389 320.9771 321.1153 321.2535 321.3917 321.5299 321.6680 321.8062 321.9443 322.0824 322.2206 322.3587 322.4967 322.6348 322.7729 322.9109 323.0490 323.1870 323.3250 323.4630 323.6010 323.7390 323.8769 324.0149 324.1528 324.2908 324.4287 324.5666 324.7045 324.8423 324.9802 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-389: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260123T100405.4Z 9519.419506 50 1 46.32 2 84.66 109.52 137.26 128.95 0.00 1 0.00 1 0 25 5.734e-01 7.260e-02 4.989e-01 6.907e-02 8.587937e-01 4.050282e-02 9.329258e-03 -6.000000e+00 3.340100e-01 229.17 -2.00 3.11 -2.00 321.70 0.00e+00 -1.821429e-02 1.390878e-02 2.019971e-03 -6.000000e+00 1.584920e-02 288.47 -2.00 20.00 -2.00 321.01 0.00e+00 9.338 0.007 302.00 328.00 3 1.1965e+00 1.2964e-01 9.7479e-02 -6.0000e+00 8.3305e-01 1.6115e+00 1.5557e-01 4.1400e-02 -6.0000e+00 9.0576e-01 -1.6922e+00 9.7362e-02 2.2138e-02 -6.0000e+00 5.3773e-01 5.8629e-01 5.1169e-02 1.5271e-02 -6.0000e+00 2.3292e-01 7.8516e-06 -2.3664e-04 1.9170e-03 2.0748e-04 -6.0000e+00 1.5298e-02 3.6965e-02 0.0000e+00 12 8 8 10 0 0 48.19 22.46 1.68 0.03696 0.03519 16 4 1 5 0 2894.870 26.51 20.00 22.46 25.45 19.4 950.15 -11384 192274 25494 32910 900000 27446 17112 156515 900000 -54969 -19637 -81811 141263 900000 -43695 900000 -41347 170806 -19518 900000 63809 84711 900000 -16360 175658 -30387 -5624 900000 79343 900000 -30443 -38945 -45697 900000 -12272 -38769 900000 276926 13300 -5245 73944 900000 105721 136689 52439 -24023 149985 900000 -31765 900000 -14911 -40107 900000 -10410 34311 10700 -14323 79607 24689 22529 119933 143590 -9862 117255 676 -95 24391 -11933 -19430 -2735 34679 11864 -11005 13461 8467 -4333 -44397 900000 -31881 -20911 -3239 -12767 -4663 12041 62731 19031 33484 -12615 15060 1362 1871 5458 16688 45443 -9380 41911 10166 15159 4261 9988 5621 -16470 8010 -11152 -8088 -16329 -3976 6013 -11172 7787 292 -2156 -3830 8 8914 -4290 13134 -12268 -4370 -4726 2644 4130 91 -596 8518 775 271 -1360 1816 -192 4038 3542 4144 -3388 -184 -4969 -671 3548 675 3063 -940 1234 -932 -3853 900000 -956 12915 1712 2211 900000 1844 1149 10513 900000 -6154 -1539 -11906 9489 900000 -5625 900000 -5786 11473 -2185 900000 4286 5690 900000 -1648 11799 -4252 -598 900000 5329 900000 -2897 -4578 -6395 900000 -1236 -4557 900000 18601 1266 -734 5870 900000 7101 9181 4803 -4034 10074 900000 -5334 900000 -2337 -8980 900000 -2039 5028 1917 -3447 8264 4221 3577 8056 9645 -2108 7876 148 -21 4468 -2872 -5329 -719 7835 3320 -3942 3945 2378 -1217 -14911 900000 -9929 -6640 -1029 -4788 -1853 4448 16088 7350 12881 -7343 6744 686 890 2533 6522 13042 -4515 15099 5406 8910 3220 7883 4688 -16041 5425 -8177 -5704 -13527 -3093 4443 -10506 6713 312 -2703 -5360 12 11277 -5955 14703 -17647 -6066 -6983 3804 5803 127 -797 10156 972 332 -1629 2340 -264 6260 6265 7979 -7509 -424 -13018 -1808 9453 1877 8385 -2609 3136 -2234 -8885 900000 SS 20260123T101645.8Z 9519.428308 53 1 47.48 2 82.11 107.95 135.25 125.66 0.00 1 0.00 1 0 17 4.097e-01 1.731e-02 2.723e-01 8.392e-03 6.754493e-01 4.613561e-03 7.783219e-03 -6.000000e+00 2.310038e-01 229.17 -2.00 3.11 -2.00 321.67 0.00e+00 6.892730e-03 2.454519e-03 7.321845e-03 -6.000000e+00 1.033475e-02 288.47 -2.00 20.00 -2.00 321.09 0.00e+00 6.793 0.003 302.00 328.00 3 1.1691e+00 1.7338e-02 8.0418e-02 -6.0000e+00 5.7532e-01 3.8719e-01 2.3056e-02 5.4342e-02 -6.0000e+00 6.2194e-01 -5.8859e-01 2.0317e-02 2.4529e-02 -6.0000e+00 3.7122e-01 2.4465e-01 9.6292e-03 5.7984e-03 -6.0000e+00 1.6117e-01 1.2931e-04 6.7990e-05 2.3407e-04 1.4725e-04 -6.0000e+00 1.0303e-02 3.6667e-02 0.0000e+00 12 9 8 11 8 0 -16.23 22.46 0.70 0.03667 0.03718 96 25 1 5 0 494.520 26.51 20.00 22.46 26.10 19.4 953.64 -105291 -151064 -37863 -33209 -185232 -133562 -183376 14470 -127467 -1458 -41828 -136721 14595 -79783 -41752 -117471 44173 -19822 53552 139951 -13515 28424 -21308 -35495 -37183 -10882 -989 -56562 12641 -35012 126 -30509 13317 1930 15517 -19810 8082 55319 -10420 23016 1855 34306 33004 15215 19252 1809 30423 3606 33099 23433 15533 30177 18002 22802 10869 13042 -418 14535 20094 6345 11702 786 12108 5396 13881 11160 8663 7481 1540 3030 6608 4659 4653 4222 6979 5410 234 -5634 -3486 -7714 1578 -1805 -808 -2309 -1366 -530 -1348 -1516 1297 1984 465 207 114 -4028 -2897 -4269 -1641 -2193 -337 533 -1731 -1002 -2604 -576 -1621 -2952 -1836 -3660 -1053 -1153 41 621 360 654 -18 -469 -1337 308 -205 1179 602 692 2083 1674 674 1663 497 -61 1613 722 119 443 143 -226 -579 -70 341 -165 721 159 -25 -667 -750 -834 900000 -1489 -3935 -372 -299 -6065 -2385 -5459 118 -2561 -12 -411 -3358 119 -1781 -889 -5857 542 -503 701 1146 -365 489 -593 -1083 -1218 -312 -26 -2273 269 -1232 4 -1317 480 79 597 -914 318 1540 -613 1165 133 1915 1965 1121 1375 156 2015 319 2266 1848 1433 2695 2009 2630 1512 1844 -70 2109 2692 940 1628 129 1991 1088 2882 2450 1876 1620 369 809 1967 1536 1579 1401 2103 1498 61 -1467 -918 -2434 546 -758 -383 -1215 -752 -309 -777 -923 791 1308 300 125 64 -2275 -1675 -2837 -1245 -1786 -311 540 -1813 -978 -2309 -495 -1409 -2825 -1698 -3633 -1090 -1311 52 882 552 1015 -28 -679 -1864 422 -297 1791 973 1123 3219 2493 986 2329 682 -80 2299 1068 203 842 294 -491 -1335 -172 894 -448 1977 442 -69 -1738 -1827 -1919 900000 SS 20260123T103232.7Z 9519.439268 58 1 24.06 2 78.90 106.04 132.62 121.88 0.00 1 0.00 1 0 17 2.727e-01 9.473e-03 6.442e-02 3.092e-03 5.299416e-01 1.598536e-03 5.594449e-03 -6.000000e+00 1.538055e-01 229.17 -2.00 3.11 -2.00 320.65 0.00e+00 2.326378e-03 6.415275e-04 2.228813e-03 -6.000000e+00 6.880600e-03 288.47 -2.00 20.00 -2.00 319.96 0.00e+00 5.009 0.001 302.00 328.00 3 1.3903e+00 5.0947e-03 5.4628e-02 -6.0000e+00 3.8305e-01 6.0569e-02 6.4683e-03 2.7664e-02 -6.0000e+00 4.1408e-01 -1.1990e-01 5.6701e-03 1.3930e-02 -6.0000e+00 2.4716e-01 4.6238e-02 2.8395e-03 4.0224e-03 -6.0000e+00 1.0732e-01 6.3292e-04 6.0076e-04 8.4942e-05 5.5051e-05 -6.0000e+00 6.8592e-03 3.6132e-02 0.0000e+00 12 9 9 12 1 1 57.55 22.45 0.48 0.03613 0.04065 88 46 1 5 0 270.310 26.51 20.00 22.45 28.02 19.3 960.46 -118350 -48809 -111998 -48405 -128459 -98731 -53873 -101148 -17253 -91993 -66474 -90302 -40281 -39761 -41283 -3055 -33662 7576 -25405 6331 -15169 -17717 4185 -21319 4493 -16347 5296 -16642 -13827 -6435 -16816 7869 -10105 8087 -8987 -6708 -7843 -7358 6832 198 5153 -74 6677 4312 4683 5512 2143 6502 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