File name: Pandora113s1_Cordoba_20260128_L2Fit_fout2c2d20230530p1-8.txt File generation date: 20260129T043728.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 113 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora113_OF_v4d20210811.txt Instrument calibration file used: Pandora113s1_CF_v2d20230530.txt Level 1 file used: Pandora113s1_Cordoba_20260128_L1_smca1c2d20230530p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20260128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing lab cal analysis from 2021 using new measurements + creating OoB CF First and last pixel inside fitting window: 208 352 Nominal wavelengths inside fitting window [nm]: 305.0013 305.1409 305.2805 305.4201 305.5597 305.6993 305.8388 305.9783 306.1179 306.2574 306.3969 306.5364 306.6758 306.8153 306.9548 307.0942 307.2336 307.3730 307.5124 307.6518 307.7912 307.9306 308.0699 308.2093 308.3486 308.4879 308.6272 308.7665 308.9058 309.0451 309.1844 309.3236 309.4628 309.6021 309.7413 309.8805 310.0197 310.1588 310.2980 310.4372 310.5763 310.7154 310.8545 310.9936 311.1327 311.2718 311.4109 311.5499 311.6890 311.8280 311.9670 312.1060 312.2450 312.3840 312.5230 312.6619 312.8009 312.9398 313.0787 313.2176 313.3565 313.4954 313.6343 313.7732 313.9120 314.0509 314.1897 314.3285 314.4673 314.6061 314.7449 314.8836 315.0224 315.1611 315.2998 315.4385 315.5773 315.7159 315.8546 315.9933 316.1319 316.2706 316.4092 316.5478 316.6864 316.8250 316.9636 317.1022 317.2407 317.3793 317.5178 317.6563 317.7948 317.9333 318.0718 318.2103 318.3487 318.4872 318.6256 318.7640 318.9024 319.0408 319.1792 319.3176 319.4560 319.5943 319.7326 319.8710 320.0093 320.1476 320.2859 320.4241 320.5624 320.7006 320.8389 320.9771 321.1153 321.2535 321.3917 321.5299 321.6680 321.8062 321.9443 322.0824 322.2206 322.3587 322.4967 322.6348 322.7729 322.9109 323.0490 323.1870 323.3250 323.4630 323.6010 323.7390 323.8769 324.0149 324.1528 324.2908 324.4287 324.5666 324.7045 324.8423 324.9802 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-389: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260128T101851.5Z 9524.429762 61 1 47.54 2 82.55 106.75 156.56 264.98 0.00 1 0.00 1 0 25 6.337e-01 2.391e-02 3.625e-01 1.387e-02 6.997442e-01 7.684416e-03 7.279393e-03 -6.000000e+00 3.589964e-01 229.14 -2.00 3.11 -2.00 321.81 0.00e+00 2.885026e-03 4.115648e-03 3.601867e-03 -6.000000e+00 1.638237e-02 288.52 -2.00 20.00 -2.00 321.26 0.00e+00 7.138 0.003 302.00 328.00 3 1.5224e+00 2.9206e-02 7.7743e-02 -6.0000e+00 8.9569e-01 5.1292e-01 3.8697e-02 4.0126e-02 -6.0000e+00 9.6908e-01 -8.0013e-01 3.2775e-02 1.9894e-02 -6.0000e+00 5.7581e-01 3.3597e-01 1.5494e-02 5.6014e-03 -6.0000e+00 2.4953e-01 6.5183e-05 -9.1197e-04 3.8869e-04 9.5652e-05 -6.0000e+00 1.6300e-02 3.6400e-02 0.0000e+00 12 9 8 11 8 0 56.53 22.50 0.78 0.03640 0.02955 67 17 1 5 0 709.530 26.51 19.99 22.50 26.46 19.6 954.62 -131804 -74320 -108189 -76071 900000 -124981 -13921 -42237 900000 -42736 -80059 -42098 -155954 187130 -47066 -31457 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2259 1695 4182 -123 3803 -1011 2154 1469 1844 4049 320 1521 -1502 4152 2952 1597 3365 326 4231 -28 -108 101 -1873 -882 146 -206 -3340 -91 -2910 -127 -1709 2046 3233 -2008 2127 -2203 94 -1642 24 -2983 -1188 198 -3018 388 -3314 279 -149 -3440 -583 47 -1603 -4768 -1440 -2180 -89 1408 -1190 3302 -232 2381 -2164 -285 -2111 -1706 408 -1174 3312 -1224 4030 2594 3256 2812 -306 3352 -2065 1060 -962 -172 980 1305 471 13 1474 -239 1598 -1718 -1595 531 -4273 900000 SS 20260128T103604.5Z 9524.441719 66 1 47.96 2 79.03 104.64 160.00 261.90 0.00 1 0.00 1 0 17 2.688e-01 1.083e-02 1.613e-01 6.562e-03 5.361482e-01 3.440581e-03 5.767273e-03 -6.000000e+00 1.515647e-01 229.14 -2.00 3.11 -2.00 320.88 0.00e+00 2.504728e-03 1.474334e-03 2.903257e-03 -6.000000e+00 6.879403e-03 288.52 -2.00 20.00 -2.00 320.22 0.00e+00 5.062 0.001 302.00 328.00 3 2.7757e+00 1.1255e-02 5.5967e-02 -6.0000e+00 3.7748e-01 8.3709e-02 1.4643e-02 3.0618e-02 -6.0000e+00 4.0804e-01 -1.4550e-01 1.3160e-02 1.4976e-02 -6.0000e+00 2.4373e-01 6.0532e-02 6.4848e-03 4.0055e-03 -6.0000e+00 1.0611e-01 1.4834e-04 3.1293e-04 1.8403e-04 5.8945e-05 -6.0000e+00 6.8455e-03 3.6165e-02 0.0000e+00 12 8 8 10 0 0 99.20 22.49 0.58 0.03617 0.03852 55 14 1 5 0 871.840 26.51 20.00 22.49 28.20 19.4 960.24 -80472 -51439 -108617 900000 -133583 -29415 -78946 -125179 -49024 -104202 5764 -77553 -63962 -6453 -50731 -1957 -18373 39154 -25301 3106 -27156 -19538 13150 -37580 36867 -7646 -15787 -30316 -10842 6656 -24326 12546 2315 25387 2457 2457 -13777 -1690 14737 -1837 12425 -2765 274 2317 -1447 5616 -6987 8367 -2253 7520 7690 2869 2547 2974 7957 6380 6610 -279 3509 5979 -574 6926 3061 7699 2225 2071 2206 -967 560 -149 1426 -704 2464 -357 1950 -1034 1098 -1536 -5737 -1548 -5148 226 -977 -872 -1286 -2865 1245 491 1232 219 1248 98 384 -366 -1339 -662 -1230 781 98 363 175 -1291 -1706 -1716 -85 -1829 -2478 -932 -423 -154 -67 1353 85 861 451 -63 -536 -373 578 -184 129 260 185 1447 872 629 -168 236 79 748 356 -632 -35 -316 79 -28 -100 248 147 223 -211 69 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4.572775e-03 288.52 -2.00 20.00 -2.00 319.42 0.00e+00 4.665 0.001 302.00 328.00 3 1.3882e+00 5.3309e-03 5.0493e-02 -6.0000e+00 2.5453e-01 4.1441e-02 6.5385e-03 2.4169e-02 -6.0000e+00 2.7513e-01 -8.3339e-02 5.5125e-03 1.2165e-02 -6.0000e+00 1.6423e-01 3.0113e-02 2.8369e-03 3.6235e-03 -6.0000e+00 7.1335e-02 8.9469e-04 5.9666e-04 9.4426e-05 4.0480e-05 -6.0000e+00 4.5567e-03 3.4448e-02 0.0000e+00 12 9 1 12 1 1 -12.74 22.49 0.43 0.03445 0.03893 39 53 1 5 0 233.460 26.62 20.00 22.49 28.35 19.4 960.67 -76704 -47579 -44134 -59753 -35267 -84758 -40940 -79526 -32393 -54871 -51285 -42087 -49233 -7991 -36394 -2640 -25337 -9256 -8494 -11366 -5956 -15118 -5478 -17022 -9243 -10972 -1289 -2011 -10085 1742 -12338 6553 753 2793 -4705 -8357 1942 -12376 4285 -5245 2673 2810 4713 3980 -1086 2527 -627 3988 -661 -139 1322 3291 4537 1318 3974 1296 4500 2672 826 3158 119 1922 886 4601 2112 2148 504 -85 2133 337 1230 741 1627 690 581 2 -1781 -1990 -5227 -2319 -2721 -883 -1213 -2334 -1235 -2301 -526 -629 494 658 821 692 -249 186 -1124 534 -493 566 1459 133 223 -660 -791 -623 -625 -800 -1249 -1068 -926 73 187 667 653 391 255 -418 -98 -521 -45 163 66 279 31 589 453 901 318 291 682 627 229 -386 9 -335 -110 -99 142 0 286 260 -274 -137 -664 -208 900000 -1461 -868 -835 -1292 -536 -1823 -664 -1979 -635 -1332 -1229 -1067 -1452 -213 -1442 -88 -1183 -398 -391 -569 -295 -817 -273 -1025 -562 -725 -80 -122 -629 96 -868 447 63 253 -452 -783 171 -1456 523 -787 428 487 845 744 -216 490 -127 778 -138 -30 295 800 1198 389 1221 426 1489 919 286 1038 40 671 347 1953 1007 1033 232 -38 957 173 667 439 990 417 333 1 -927 -962 -2613 -1253 -1602 -589 -915 -1924 -1061 -1990 -479 -606 485 644 773 607 -219 153 -943 486 -481 624 1687 169 285 -797 -923 -667 -679 -949 -1479 -1323 -1213 102 288 1048 1081 645 404 -622 -146 -772 -69 251 108 464 50 922 734 1395 476 414 960 965 372 -690 16 -617 -212 -203 310 -1 620 573 -599 -303 -1390 -414 900000 SS 20260128T104604.4Z 9524.448662 72 1 47.59 2 76.96 103.44 161.98 259.77 0.00 1 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