File name: Pandora125s1_Cordoba_20180915_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141436.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v3d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20180915_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20180915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180915T101928.0Z 6832.430185 416 1 32.01 2 89.71 86.34 128.12 153.97 0.00 1 0.00 1 0 15 5.660e-02 5.446e-02 4.589e-02 4.523e-02 5.527923e+03 3.130598e+03 6.622632e+02 -6.000000e+00 3.282562e+03 282.56 -2.00 20.00 -2.00 505.29 0.00e+00 1.346010e-03 1.271313e-03 4.649776e-06 -6.000000e+00 1.617734e-03 282.56 -2.00 20.00 -2.00 500.13 0.00e+00 1.867063e-01 9.384115e-01 6.932317e-03 -6.000000e+00 1.145971e+00 227.96 -2.00 3.11 -2.00 501.80 0.00e+00 20.073 0.067 489.00 513.00 1 8.2647e+00 7.2162e-02 2.9243e-02 -6.0000e+00 8.8096e-02 1.6456e-01 1.8208e-02 1.6587e-03 -6.0000e+00 2.2525e-02 3.0477e-05 -7.4933e-03 5.0155e-03 8.0428e-05 -6.0000e+00 6.5841e-03 2.1588e-02 3.4915e-04 12 8 8 10 0 0 72.94 22.40 7.07 0.02159 -0.03039 8 2 1 4 0 4000.000 27.35 20.00 22.40 -6351 5019 -3157 1273 -1759 198 -4755 5537 -11086 2316 -1009 -3582 9198 2686 7264 4866 6588 2596 2070 -4064 3957 145 -4459 -1467 -1694 -3095 -6102 -1392 124 5192 2479 1995 4803 -6940 775 4538 -886 2750 1860 -997 389 -2011 -4460 3455 4256 1821 1536 1708 6312 -9467 9061 -8460 1043 2702 4037 2851 2023 -6650 -8262 794 -4285 -559 14360 5786 858 12771 -4702 12935 -1640 6280 -4517 -3191 442 -7398 -5153 -3051 -4212 -7250 -4069 -1752 3941 4656 3081 -2679 -3082 15722 -4550 -483 13181 7791 -724 4747 1723 15514 -4630 1397 7659 -4215 -2184 -6257 -2583 -5795 5888 -4965 -2521 -5074 -6699 4181 3596 1026 -1532 10603 -1838 -527 -8483 4560 11822 4893 -8686 8044 -3101 -6400 1851 1693 1088 2620 -1454 -3264 881 784 3071 12039 1684 1833 -5759 -652 -6911 4363 -1904 2635 -9185 11132 3238 4435 6195 2138 -8790 729 -8037 -6755 4852 -3408 1354 -1977 223 -5689 6000 -14112 2547 -1130 -4054 9041 2792 7198 4979 6741 2824 2301 -4846 4368 166 -5371 -1720 -1993 -3678 -6782 -1581 135 5271 2566 2098 5030 -7689 807 4558 -933 2762 1868 -1027 396 -2117 -4859 3509 4307 1883 1577 1722 5944 -10173 7897 -8654 971 2514 3801 2780 2017 -7268 -9183 806 -4589 -578 12780 5576 858 11177 -4827 10986 -1593 5589 -4470 -3135 423 -7704 -5233 -2996 -4122 -7229 -3906 -1644 3508 4144 2811 -2612 -3039 12889 -4571 -466 11098 6962 -711 4453 1667 12947 -4634 1285 6448 -3907 -1951 -5800 -2337 -5564 5197 -5006 -2504 -5153 -6852 3814 3307 978 -1516 9397 -1859 -529 -9272 4395 10609 4680 -9398 7248 -3080 -6523 1736 1594 1032 2448 -1412 -3218 829 733 2767 9781 1505 1638 -5615 -614 -7043 4028 -1891 2521 -9939 9866 3108 4193 5696 2013 -9056 673 -8073 SO 20180915T102345.0Z 6832.433160 420 1 32.00 2 88.80 85.78 127.72 152.83 0.00 1 0.00 1 0 22 3.530e-02 3.479e-02 2.857e-02 2.825e-02 9.446115e+02 1.756675e+03 1.842956e+02 -6.000000e+00 2.046880e+03 282.56 -2.00 20.00 -2.00 505.30 0.00e+00 -8.165006e-05 7.945959e-04 5.549346e-05 -6.000000e+00 1.010327e-03 282.56 -2.00 20.00 -2.00 500.03 0.00e+00 2.259171e+00 5.808794e-01 2.448686e-02 -6.000000e+00 7.204336e-01 227.96 -2.00 3.11 -2.00 501.74 0.00e+00 18.174 0.049 489.00 513.00 1 7.9183e+00 4.4689e-02 2.6117e-02 -6.0000e+00 5.5292e-02 1.0608e-01 1.1304e-02 1.4427e-03 -6.0000e+00 1.4294e-02 4.9510e-05 1.0317e-02 3.1718e-03 4.0309e-05 -6.0000e+00 4.1187e-03 4.3254e-02 -4.1625e-04 12 9 8 11 8 0 95.13 22.40 0.83 0.04325 0.11481 8 2 1 4 0 4000.000 27.35 20.00 22.40 -1115 928 1687 1885 -2423 -1451 -1826 630 -3731 -3870 -3506 1538 1577 -742 1595 -5497 3880 752 -1457 -474 4954 -1743 4439 689 4670 2334 701 -2618 -1505 -117 -1486 -1337 -3400 6931 -6611 6985 -1132 7127 -4368 1584 -5362 -1359 -3927 2675 -266 2294 -1634 2140 7697 -1063 -2463 1450 -394 -1631 5973 -2683 -2267 -1769 -2058 4143 3845 1357 -2753 3338 2969 440 -3195 749 -1863 -880 -644 3827 -707 1973 -2230 -195 -3657 -2453 3296 354 -2840 5878 1060 3703 -1827 1476 -567 -174 4947 714 4958 9138 -2882 1058 -291 2105 3155 -2287 -1706 -2895 3516 -552 -3625 2888 -2651 -5578 -277 -3461 3561 -1450 -5609 4884 4396 -5566 9763 -4218 6003 5407 -4595 -147 1064 3729 -7462 1745 -4267 896 515 67 -307 -413 -3384 -3953 2879 -345 3022 -4417 2144 -963 1731 -3078 -921 272 755 22 13008 -637 -165 248 -6196 -1110 927 1723 1977 -2719 -1643 -2099 708 -4355 -4469 -3978 1637 1659 -794 1669 -6251 4100 838 -1686 -547 5434 -2047 4914 794 5169 2630 794 -3004 -1666 -126 -1612 -1470 -3591 7376 -7471 7504 -1199 7495 -4685 1596 -5812 -1426 -4265 2739 -281 2349 -1718 2127 7064 -1037 -2380 1331 -370 -1580 5496 -2747 -2336 -1819 -2122 4013 3742 1355 -2857 3233 2848 426 -3161 703 -1774 -824 -602 3442 -672 1833 -2150 -182 -3475 -2280 2881 319 -2659 5084 971 3331 -1748 1372 -539 -165 4472 679 4563 8134 -2898 1015 -278 1927 2794 -2094 -1531 -2624 3033 -509 -3545 2691 -2617 -5622 -262 -3360 3236 -1401 -5730 4551 4157 -5853 8848 -4407 5648 5075 -4705 -142 1006 3423 -7675 1642 -4270 851 490 64 -293 -392 -3262 -3783 2556 -317 2725 -4370 2022 -950 1681 -3159 -931 273 755 22 11369 -628 -159 234 -6244 SO 20180915T102806.0Z 6832.436181 424 1 32.00 2 87.87 85.20 127.30 151.69 0.00 1 0.00 1 0 15 2.408e-02 2.368e-02 2.187e-02 2.161e-02 4.946498e+03 1.508635e+03 3.429123e+02 -6.000000e+00 1.396586e+03 282.56 -2.00 20.00 -2.00 505.31 0.00e+00 9.040565e-04 6.105807e-04 4.502347e-05 -6.000000e+00 6.887482e-04 282.56 -2.00 20.00 -2.00 500.04 0.00e+00 1.637831e+00 4.504059e-01 3.712590e-02 -6.000000e+00 4.898222e-01 227.96 -2.00 3.11 -2.00 501.73 0.00e+00 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