File name: Pandora125s1_Cordoba_20190421_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T143139.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190421_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190421T104521.0Z 7050.448160 252 1 32.00 2 89.73 75.87 66.81 266.06 0.00 1 0.00 1 0 225 5.686e-01 5.435e-01 2.448e-01 1.892e-01 2.279808e+04 1.661312e+04 1.886279e+03 -6.000000e+00 3.340219e+04 286.11 -2.00 20.00 -2.00 505.01 0.00e+00 1.271179e-01 4.785659e-03 6.417338e-03 -6.000000e+00 1.641903e-02 286.11 -2.00 20.00 -2.00 499.79 0.00e+00 2.978379e+00 4.189339e+00 1.045215e+00 -6.000000e+00 1.153803e+01 226.08 -2.00 3.11 -2.00 501.10 0.00e+00 20.040 0.066 489.00 513.00 1 8.5676e+00 3.1896e-01 1.6085e-01 -6.0000e+00 8.8721e-01 3.5672e-01 7.3858e-02 1.3054e-02 -6.0000e+00 2.2859e-01 2.2487e-06 1.5912e-01 6.4794e-03 9.8034e-04 -6.0000e+00 6.6353e-02 -3.5594e-02 -4.8757e-06 12 13 12 11 8 0 89.69 21.25 18.45 -0.03559 1.06810 8 2 1 4 0 4000.000 26.73 19.99 21.25 51327 78592 14761 64627 -7411 -15314 14822 -23655 -19769 24632 -5925 -45684 -5494 -16641 32172 9682 4849 -13989 -6995 9283 -14205 -18648 3326 -20356 21588 -22730 34809 -23837 12455 36356 48947 30702 37648 101795 44303 39055 45527 41635 95297 119088 64399 45121 92055 59053 87622 49010 112094 105174 125072 80461 169807 84179 111855 -74487 115438 128121 68114 75750 51407 92366 116711 95835 43580 173038 60032 73359 58582 52721 56429 90482 60990 93287 60970 28596 94057 3266 49862 27829 37196 -11987 9637 -24513 29479 56012 13995 -2969 28870 75098 -13821 -2328 -7807 -48587 -49743 -44725 -63229 4579 -46616 1173 -35613 -44151 -40989 12322 -34440 -8926 52882 5203 24644 14921 26825 16654 7379 57907 2710 -4170 9747 104733 42752 43520 92518 81363 13486 22416 35773 69914 -9412 27192 87715 46438 53785 43127 19665 14059 -7698 -4075 1848 -2326 -12844 -34061 -978 25183 -47511 -6298 46507 32462 -25308 3638 -9016 7260 -30501 44112 47678 15919 40295 -9117 -19612 13488 -30295 -23320 17849 -5591 -62356 -5000 -17386 21686 8647 4739 -16737 -7662 8291 -15320 -20426 2915 -22983 16371 -27195 23463 -26511 10704 25731 32993 27420 34894 54893 42430 42230 48525 47592 64771 64385 60682 52274 68256 62941 73089 62837 79650 82856 83076 85760 76068 91023 93304 -402712 92726 89059 84174 84249 70674 81327 77523 75499 55874 58805 61203 63459 57010 52935 53172 58703 50874 53318 45207 27387 43587 3481 30809 19775 22408 -11295 7295 -27263 20491 32013 12754 -3256 22744 35962 -15158 -2085 -6633 -55539 -52251 -41452 -66416 2334 -38884 616 -28606 -42284 -42422 8375 -41496 -9100 31041 5143 20556 13829 21961 14921 7181 33991 2805 -4767 10088 43681 34340 35629 47162 46503 14999 22160 29840 39959 -11486 22262 37939 29411 30740 26647 14885 10858 -7135 -3525 1456 -1833 -10714 -33673 -680 13615 -55043 -5058 22989 19055 -26974 2922 -8217 5607 -34394 SO 20190421T104943.1Z 7050.451193 256 1 32.13 2 88.83 75.30 67.70 265.52 0.00 1 0.00 1 0 50 3.026e-01 1.706e-01 1.720e-01 1.390e-01 2.049534e+04 1.150956e+04 1.181132e+03 -6.000000e+00 1.777703e+04 286.11 -2.00 20.00 -2.00 505.37 0.00e+00 -6.522213e-04 3.976953e-03 2.549590e-04 -6.000000e+00 8.725836e-03 286.11 -2.00 20.00 -2.00 499.85 0.00e+00 1.713860e-01 2.822371e+00 1.508480e-01 -6.000000e+00 6.095079e+00 226.08 -2.00 3.11 -2.00 501.60 0.00e+00 18.208 0.050 489.00 513.00 1 1.0697e+01 2.1816e-01 2.9431e-02 -6.0000e+00 4.6935e-01 1.5090e-01 5.3142e-02 3.5542e-03 -6.0000e+00 1.1978e-01 3.3309e-06 2.8856e-02 1.4076e-02 1.1799e-04 -6.0000e+00 3.5197e-02 2.8577e-02 1.4710e-04 12 9 8 11 8 0 -11.70 21.23 -0.05 0.02858 0.22873 8 2 1 4 0 4000.000 26.73 19.99 21.23 -27559 46331 9377 -10563 3645 3989 15895 20917 12080 -10695 63316 -18352 19955 -30103 20264 -6626 9630 11586 34756 1223 -7412 6807 -11818 -6836 -8910 4262 -15171 13735 -8037 35347 5343 3462 8029 -3418 -7172 -2398 7319 8076 11763 22331 27156 -19634 15 -25582 7999 -2412 48382 35693 -10929 17123 -2485 6284 11214 273613 -6517 14904 -12974 8846 28211 28359 -8043 -1655 7019 26035 -7087 18984 7453 -10266 43580 -12734 -11773 -13247 12078 844 43780 4921 -6566 15815 5490 -10012 -12059 36077 -5877 33774 -22054 28198 -2402 36053 -8431 16722 1215 12265 11052 19026 -15325 -15160 -3498 -192 22314 9627 20511 14465 13957 6734 2626 -5817 -11046 -670 -23661 38725 -9029 22983 -16476 3804 7098 18574 -23157 3881 8018 41631 119 -5579 66261 -3037 18814 -6992 -4163 -17253 31155 -17479 -30438 -16751 25887 -9094 11929 9555 45918 -4355 9152 19908 -2246 17871 -1594 26902 -19075 9045 -8743 11280 -7534 -40245 33256 9980 -13988 4240 4640 16327 20191 12558 -13765 38395 -24983 18522 -46568 19310 -8446 10607 12618 30109 1483 -9815 7834 -16380 -8968 -11799 4853 -18760 13598 -9847 28434 5951 3692 8289 -3955 -8543 -2694 7390 8062 11343 19506 22797 -26505 16 -36567 8076 -2654 31285 25510 -12151 14180 -2509 5917 10305 37248 -7393 13695 -15748 8630 22723 22842 -9307 -1784 6848 20675 -7718 15721 6848 -11180 27686 -14302 -13223 -15178 10687 823 27316 4466 -6630 12738 4920 -10563 -13133 24556 -6134 23755 -27020 20793 -2398 24540 -8991 13848 1158 10157 8902 13597 -14951 -14446 -2937 -157 14936 7644 15357 11979 11875 6187 2502 -6005 -12029 -661 -29526 25920 -9731 17990 -19252 3668 6683 15592 -29160 3654 7095 25976 112 -5570 32323 -2963 14727 -7059 -4061 -18986 20852 -18837 -37293 -18052 18502 -9388 10149 8455 28650 -4546 8410 16486 -2318 15002 -1609 20143 -22288 7901 -9125 9726 -7949 SO 20190421T105354.0Z 7050.454097 260 1 32.01 2 87.97 74.74 68.56 265.01 0.00 1 0.00 1 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