File name: Pandora125s1_Cordoba_20190424_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T142802.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190424_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190424T104724.1Z 7053.449584 251 1 32.13 2 89.73 74.68 31.65 279.66 0.00 1 0.00 1 0 169 8.516e-01 4.587e-01 6.377e-01 4.308e-01 -3.269385e+04 2.663573e+04 2.382674e+03 -6.000000e+00 5.430920e+04 285.91 -2.00 20.00 -2.00 505.12 0.00e+00 -8.979020e-03 1.444305e-02 5.759768e-04 -6.000000e+00 2.722851e-02 285.91 -2.00 20.00 -2.00 499.82 0.00e+00 1.022964e+00 1.043195e+01 4.475903e-01 -6.000000e+00 1.872285e+01 225.94 -2.00 3.11 -2.00 501.61 0.00e+00 20.047 0.066 489.00 513.00 1 1.1643e+01 8.1214e-01 4.8195e-02 -6.0000e+00 1.4384e+00 2.4024e-01 2.1078e-01 9.4536e-03 -6.0000e+00 3.6672e-01 7.2252e-07 -5.8654e-02 4.4192e-02 5.0435e-04 -6.0000e+00 1.1177e-01 4.0575e-02 1.4647e-04 12 9 8 11 8 0 97.44 21.42 18.83 0.04057 -0.36627 8 2 1 4 0 4000.000 26.94 20.01 21.42 900000 75057 900000 -14010 -14849 5482 131762 49297 -10767 900000 1774 126670 -15418 11302 104899 900000 -17381 282391 31114 46111 68610 16017 4765 42732 -22427 1841 70819 -12118 900000 -62205 900000 22534 10050 36248 67803 -10191 -33366 148920 30734 900000 36025 95834 -22521 120422 4000 32879 13978 120038 -11827 347603 -1176 273343 26072 900000 57904 -11439 42254 -41752 900000 28046 85118 -5322 900000 31691 900000 69462 900000 1364 10765 140536 -12695 900000 -23355 222472 -16373 155356 26221 900000 12214 900000 3130 113439 224385 -49430 -32098 -17715 49816 18171 900000 -6502 900000 6657 900000 20680 75383 29816 33231 -20798 -35036 900000 52625 103104 40506 44509 94060 149150 2117 900000 34183 67581 48740 -345 900000 13589 109851 26233 75937 -8441 900000 -37357 900000 900000 134543 65725 -8881 55063 104081 86773 -46585 900000 -32113 36815 132491 144176 197767 900000 -295 11549 40672 42505 -8523 -30645 67204 -40396 49558 21502 900000 54879 71842 900000 43000 900000 -19264 -20984 6491 55356 39538 -16037 900000 2371 53217 -24143 13381 48076 900000 -26552 118638 29708 38745 47167 18963 6369 39169 -36118 2321 44629 -17394 900000 -143734 900000 21301 10556 29188 40354 -13558 -57239 62564 27976 900000 30270 43617 -33116 50592 4481 27626 14191 50430 -15321 146035 -1317 114837 20994 900000 32436 -12815 28107 -65779 900000 22584 38740 -5962 900000 24409 900000 36478 900000 1385 9799 59042 -14222 900000 -28618 93465 -18917 65268 20196 900000 10690 900000 2959 47658 94269 -81335 -44950 -21707 31393 15904 900000 -7512 900000 6992 900000 19548 42226 27140 30249 -33495 -66236 900000 40533 46926 34035 35840 46102 62661 2520 900000 27525 37856 32422 -375 900000 13321 46151 23879 42537 -10934 900000 -61469 900000 900000 56524 36817 -10572 34700 43727 39493 -79915 900000 -47219 27066 55662 60571 83086 900000 -289 10108 27055 28274 -9549 -42916 35292 -62227 31230 18067 900000 32662 35213 SO 20190424T105144.0Z 7053.452593 255 1 32.00 2 88.84 74.11 32.54 278.87 0.00 1 0.00 1 0 43 8.906e-01 4.716e-01 6.396e-01 4.303e-01 5.913332e+04 3.993442e+04 3.557283e+03 -6.000000e+00 5.334796e+04 285.91 -2.00 20.00 -2.00 505.27 0.00e+00 -7.317497e-03 1.283594e-02 2.406576e-04 -6.000000e+00 2.648569e-02 285.91 -2.00 20.00 -2.00 500.71 0.00e+00 -1.197449e+01 9.101033e+00 3.505540e-01 -6.000000e+00 1.883469e+01 225.94 -2.00 3.11 -2.00 502.28 0.00e+00 18.244 0.050 489.00 513.00 1 1.2644e+01 6.9900e-01 3.9703e-02 -6.0000e+00 1.4450e+00 2.1955e-01 1.7184e-01 8.5598e-03 -6.0000e+00 3.7172e-01 8.8207e-07 9.4830e-03 2.8491e-02 1.9011e-04 -6.0000e+00 1.0908e-01 -1.4504e-01 2.0002e-03 12 9 8 11 8 0 72.42 21.43 -6.69 -0.14504 -0.07926 8 2 1 4 0 4000.000 26.94 19.99 21.43 112975 9724 -11558 76347 52871 29249 -3741 -1290 31874 -3661 24975 28520 66616 81768 6951 900000 -33547 -40914 -5849 57907 -19402 69665 75954 -22685 31674 -14732 84927 339349 90091 30510 900000 -28789 900000 53090 6945 28334 88630 55446 970 165609 -25849 900000 -16992 346659 9168 40069 -42449 56864 24323 53091 -194 -1732 19389 3915 276635 -55627 7233 -13347 22585 65824 900000 60675 92661 1654 38168 57551 9441 51716 17194 238280 50324 18092 38110 -12999 -35791 128072 -38175 207959 107460 71619 -39880 54415 -12763 900000 900000 -20000 216614 -18947 98065 -22834 129912 182414 -14071 -14957 40228 38140 -24936 6174 -14223 28146 3471 900000 25265 25061 -5289 157920 135211 125197 8282 52705 164928 8369 101757 46836 45356 -37754 115580 66666 126685 -50937 -29247 28949 25048 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9073 36035 6677 68526 -14393 -6654 68765 103926 900000 44196 25799 -65842 47929 1930 900000 SO 20190424T105553.0Z 7053.455475 259 1 32.00 2 87.99 73.56 33.39 278.15 0.00 1 0.00 1 0 54 6.862e-01 3.841e-01 5.528e-01 3.745e-01 -5.423780e+04 2.267018e+04 6.051120e+03 -6.000000e+00 4.228876e+04 285.91 -2.00 20.00 -2.00 505.51 0.00e+00 5.115439e-03 1.160473e-02 1.092180e-04 -6.000000e+00 2.004272e-02 285.91 -2.00 20.00 -2.00 500.25 0.00e+00 2.906916e+01 7.931254e+00 1.269080e-01 -6.000000e+00 1.398522e+01 225.94 -2.00 3.11 -2.00 502.05 0.00e+00 16.021 0.034 489.00 513.00 1 9.8218e+00 6.2276e-01 2.4633e-02 -6.0000e+00 1.0756e+00 -4.6330e-01 1.4434e-01 5.8028e-03 -6.0000e+00 2.7596e-01 1.1169e-06 3.0813e-02 2.5262e-02 1.0837e-03 -6.0000e+00 8.0265e-02 2.2459e-01 -1.5776e-03 12 8 8 10 0 0 15.10 21.42 14.62 0.22459 0.43832 8 2 1 4 0 4000.000 26.83 19.99 21.42 45340 3526 29274 72694 12025 -29440 -37448 13200 58098 -11969 25394 14268 29575 39297 147182 -13478 55858 -1806 7466 14222 1081 -34804 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