File name: Pandora125s1_Cordoba_20190819_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141523.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190819_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190819T105246.0Z 7170.453310 249 1 32.02 2 89.72 74.75 62.10 288.21 0.00 1 0.00 1 0 71 2.139e-01 1.787e-01 1.589e-01 1.459e-01 1.195663e+04 1.073746e+04 9.750678e+02 -6.000000e+00 1.236392e+04 281.97 -2.00 20.00 -2.00 505.31 0.00e+00 -8.172224e-04 4.095704e-03 1.621840e-04 -6.000000e+00 6.135427e-03 281.97 -2.00 20.00 -2.00 500.21 0.00e+00 -1.466249e+00 2.948509e+00 6.158888e-02 -6.000000e+00 4.403618e+00 226.79 -2.00 3.11 -2.00 501.88 0.00e+00 20.122 0.067 489.00 513.00 1 9.5494e+00 2.2616e-01 3.0081e-02 -6.0000e+00 3.3688e-01 1.5208e-01 5.6788e-02 2.3617e-03 -6.0000e+00 8.8810e-02 9.2063e-06 2.4013e-02 1.5298e-02 1.3251e-04 -6.0000e+00 2.4935e-02 2.9642e-01 -2.8001e-03 12 9 8 11 8 0 99.50 21.39 17.79 0.29642 0.46298 8 2 1 4 0 4000.000 26.94 20.01 21.39 900000 16772 6960 -7350 -1570 6226 -5404 -4123 10626 -24073 8000 -21167 28449 24635 7683 -1076 10994 -17206 20132 3111 2226 17222 -11349 3956 7438 -4498 27096 32868 -12227 -7487 -641 -6030 3627 17530 10948 1314 -6108 -18211 21541 -16331 23120 -11168 12600 -2042 13635 2284 12067 -10433 -2873 28453 24599 17288 1278 -25171 11094 32337 -5849 47879 -35159 15239 19662 4521 6880 -775 396 -1001 55962 -2325 20510 -18071 27847 -26802 41823 -6714 40419 -14706 -419 -10790 30960 1888 1252 19963 -1442 55731 4356 -18230 4895 -2324 -4478 35471 5024 40105 23594 -28173 28104 2059 17494 -14918 9673 -18139 55484 -15679 34068 -6998 27919 -1825 -5776 12802 5322 12325 -29540 30669 -26066 68031 -8283 47386 -11062 1371 -5235 22509 -2114 31821 8578 4945 30232 -13994 31566 -1502 54235 -16009 10774 33892 -8389 -7988 -3237 873 -5508 31652 -14280 35520 -5388 9924 -521 27149 6304 4830 -9333 5452 -25838 900000 14386 6783 -8501 -1755 6554 -6461 -4876 10771 -34100 8109 -28333 22922 20489 7588 -1175 10858 -23032 18837 3477 2517 16785 -14748 4422 8023 -4983 23592 26483 -13837 -8659 -692 -6393 3587 16858 10433 1378 -6839 -22779 17963 -19843 19004 -13037 11708 -2214 12669 2367 11212 -11931 -2977 21014 18461 13799 1202 -31485 9912 23883 -6411 30799 -51936 13615 16864 4524 6721 -813 405 -1025 31999 -2354 16370 -21096 20567 -34482 27402 -7199 26964 -16818 -409 -11568 21760 1777 1193 15934 -1443 31867 4203 -22150 4723 -2409 -4747 25353 4907 27710 19113 -37588 20757 1913 13546 -15639 7835 -19448 29082 -17370 23944 -7669 21950 -1935 -6330 11590 5199 11305 -41524 23747 -35709 36469 -9571 31611 -13309 1453 -5862 18770 -2216 23502 7971 4771 22689 -16337 23314 -1539 31657 -18690 9498 23417 -8794 -8374 -3278 863 -5905 23754 -17181 26234 -6033 9576 -558 21992 6233 4776 -10451 5196 -33549 SO 20190819T105706.0Z 7170.456319 253 1 32.00 2 88.84 74.18 62.97 287.53 0.00 1 0.00 1 0 71 1.369e-01 1.058e-01 8.991e-02 8.555e-02 9.549627e+03 6.619776e+03 9.276428e+02 -6.000000e+00 7.917041e+03 281.97 -2.00 20.00 -2.00 505.38 0.00e+00 4.877807e-03 2.431709e-03 2.849267e-04 -6.000000e+00 3.906656e-03 281.97 -2.00 20.00 -2.00 500.17 0.00e+00 2.354448e+00 1.800867e+00 5.467893e-02 -6.000000e+00 2.769376e+00 226.79 -2.00 3.11 -2.00 501.84 0.00e+00 18.289 0.050 489.00 513.00 1 8.9221e+00 1.3915e-01 2.7515e-02 -6.0000e+00 2.1285e-01 9.3536e-02 3.4343e-02 1.9803e-03 -6.0000e+00 5.4467e-02 1.5972e-05 -6.6684e-03 9.5861e-03 1.3552e-04 -6.0000e+00 1.5922e-02 7.7468e-02 -3.9499e-05 12 8 8 10 0 0 -87.36 21.41 -4.45 0.07747 0.03121 8 2 1 4 0 4000.000 26.94 20.02 21.41 12789 4910 2572 -13371 24320 853 -4485 2382 -2261 13464 7338 11137 3753 -40 6453 13559 -525 15651 -14124 1106 -13046 13052 4716 2480 9087 -11834 23522 -17398 -3873 -2649 -8037 -1482 11237 -8803 -9713 -14243 470 -8139 -1119 -484 16114 14126 -5228 -4738 -15776 1437 1842 4324 12326 2480 9063 20932 2566 34061 -2937 25060 -5677 8932 5498 -5595 1748 -8169 -17482 528 5430 3852 9549 -5977 -13630 -1394 -6525 7529 -3291 1392 -462 9334 -2083 4776 4763 -5881 -3574 -10734 13908 7213 -6962 -2777 1241 1561 -3669 -1096 7338 -9672 -9075 -5638 76951 77425 -3462 -13926 2856 4013 -6228 2042 -2378 6491 3791 19507 8620 7533 -11630 5377 3777 4269 3706 -8651 19354 -12782 -11082 -10096 12726 -10145 18090 19138 5331 -1547 11766 -8345 -17102 16090 9285 1673 -999 6884 -16987 -1011 -5493 25888 -3510 11093 -4907 2795 -47 10370 -14640 11676 1269 6173 5163 8499 5316 11206 4751 2626 -16504 21125 955 -5365 2668 -2636 13234 7548 10862 3889 -43 6441 12707 -576 14906 -18402 1248 -16998 13127 5174 2796 9624 -14134 21328 -21387 -4058 -2927 -8533 -1491 11130 -10022 -11329 -17409 492 -9209 -1173 -504 14294 12925 -5879 -5361 -20054 1536 1943 4379 11277 2442 8166 16520 2438 24027 -3076 20303 -6344 8672 5530 -6291 1832 -9471 -22223 557 5386 3821 8804 -6345 -15422 -1383 -6790 6836 -3355 1362 -459 8280 -2037 4303 4258 -5833 -3469 -11245 11463 6398 -7148 -2735 1170 1461 -3613 -1056 6560 -10336 -9635 -5710 33322 32446 -3167 -13811 2354 3251 -5655 1754 -2209 5667 3442 15123 7405 6524 -12266 4845 3509 3996 3520 -9365 15951 -14641 -12539 -11282 11200 -11054 14657 15238 4877 -1524 10190 -8859 -19828 13373 8236 1589 -963 6058 -18864 -961 -5525 19347 -3580 9917 -5209 2772 -48 9633 -17485 10683 1277 5821 4832 7598 4901 SO 20190819T110117.0Z 7170.459225 257 1 32.00 2 87.98 73.62 63.81 286.87 0.00 1 0.00 1 0 15 7.929e-02 7.446e-02 4.768e-02 4.661e-02 7.635524e+03 3.402445e+03 4.928519e+02 -6.000000e+00 4.587250e+03 281.97 -2.00 20.00 -2.00 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