File name: Pandora125s1_Cordoba_20190820_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T143027.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190820_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190820T105140.0Z 7171.452546 249 1 32.01 2 89.73 75.14 56.90 299.96 0.00 1 0.00 1 0 15 2.339e-01 1.780e-01 1.871e-01 1.684e-01 1.374787e+04 1.295667e+04 1.394204e+03 -6.000000e+00 1.358971e+04 281.99 -2.00 20.00 -2.00 505.33 0.00e+00 3.148731e-03 4.747378e-03 1.345014e-04 -6.000000e+00 6.713474e-03 281.99 -2.00 20.00 -2.00 500.07 0.00e+00 -2.532215e+00 3.489223e+00 3.302876e-02 -6.000000e+00 4.794305e+00 226.83 -2.00 3.11 -2.00 501.76 0.00e+00 20.123 0.067 489.00 513.00 1 1.0759e+01 2.6592e-01 2.9608e-02 -6.0000e+00 3.6699e-01 2.0243e-01 6.8299e-02 1.9989e-03 -6.0000e+00 9.5230e-02 2.7679e-06 -2.3254e-03 1.7705e-02 1.4662e-04 -6.0000e+00 2.7251e-02 -1.0185e-01 1.1548e-04 12 9 8 11 8 0 89.18 21.47 13.28 -0.10185 -0.11798 8 2 1 4 0 4000.000 27.05 20.01 21.47 -6467 1019 -7915 3244 28362 -6240 15951 -14084 23205 -20342 492 -16946 -1416 21225 84707 7588 62635 -1003 -9187 -1625 249 402 1818 36231 -211 -17735 -20337 802 29305 13406 -12116 11130 -13405 -9589 14518 -2254 2835 4727 18505 26140 -3474 5174 22831 -17070 4343 -13457 1842 2105 -4689 12335 9872 17264 -7396 25536 -12303 59685 14316 -16497 13137 29211 69106 -20563 3101 -5774 -27025 2543 25094 -6748 14370 -2514 -3128 43685 417 27939 900000 1476 -5191 1408 -3815 43185 5579 50381 -15798 35088 11783 27327 8041 -24593 -21676 7459 22193 28297 28781 14766 24313 -15071 41732 -19896 61822 6652 8474 -23664 19253 -512 14428 8149 -2996 10534 -5137 -22456 28184 23974 -10678 30271 -22218 44590 5496 -11617 4149 -15681 -4391 -3543 33427 2117 -7090 -17842 -367 17336 32875 -10882 10265 -11021 62262 51470 2810 -7260 -275 -5662 -16805 -27829 -5296 61903 13484 1635 34845 24401 681 -9246 6495 -7080 1039 -9021 3405 23818 -7579 15787 -19009 21575 -28979 560 -22617 -1592 18779 39379 7624 36632 -1129 -11435 -1901 288 465 2071 29339 -247 -22673 -26558 914 24610 12867 -14718 10682 -15294 -10809 14369 -2448 2922 4744 16026 20841 -3724 5121 19144 -21588 4478 -16649 1950 2199 -5157 11191 8957 14239 -7727 19306 -13868 33639 12988 -20636 12280 23289 37048 -27136 3240 -6587 -37893 2622 20352 -7421 12642 -2592 -3225 28224 418 21508 900000 1481 -5495 1374 -3881 27308 5138 29780 -18242 24599 10529 21036 7516 -31778 -27116 6973 17999 21783 22156 12991 19050 -16988 25815 -22154 29744 5487 6872 -27000 14821 -500 12495 7618 -3130 9557 -5437 -28399 21696 19444 -12329 23302 -29015 30035 5515 -13893 4220 -19185 -4708 -3701 23894 2066 -7602 -21338 -368 14537 23500 -11967 9031 -11817 31668 29009 2588 -7485 -268 -5915 -19867 -37107 -5678 34038 12048 1641 24907 19119 665 -9787 5804 SO 20190820T105602.0Z 7171.455579 253 1 32.01 2 88.83 74.57 57.70 299.12 0.00 1 0.00 1 0 50 1.720e-01 1.498e-01 1.184e-01 1.114e-01 2.565457e+03 7.506858e+03 6.722534e+01 -6.000000e+00 9.949516e+03 281.99 -2.00 20.00 -2.00 505.37 0.00e+00 1.634966e-03 3.190270e-03 3.005018e-05 -6.000000e+00 4.917308e-03 281.99 -2.00 20.00 -2.00 500.14 0.00e+00 5.432941e+00 2.302309e+00 4.835507e-02 -6.000000e+00 3.507007e+00 226.83 -2.00 3.11 -2.00 501.83 0.00e+00 18.271 0.050 489.00 513.00 1 1.0060e+01 1.7827e-01 2.6463e-02 -6.0000e+00 2.6913e-01 2.7007e-02 4.2370e-02 1.6802e-03 -6.0000e+00 6.9576e-02 4.2665e-06 4.7886e-02 1.2623e-02 2.0715e-05 -6.0000e+00 2.0062e-02 -7.3512e-02 1.0072e-04 12 9 8 11 8 0 98.98 21.48 1.34 -0.07351 0.25865 8 2 1 4 0 4000.000 27.05 20.02 21.48 3370 12428 7903 1460 -13010 43017 -19302 25215 -3750 7824 -11943 7224 20191 -14051 -2022 7413 -3327 -1708 334 -30439 11748 -5104 21171 -13042 35216 -6893 32054 43 9434 2571 24243 20235 -7154 21172 -6631 11377 2460 21672 -7900 12994 -5188 4717 -5016 7015 7544 -7125 6941 -6434 -784 -14796 456 -12322 3018 1364 44690 -15960 -8423 -9255 6172 22063 -14821 8634 -1909 12409 -20482 28435 11245 -5135 2256 23235 -18091 8876 21169 29397 7024 846 10764 -20147 24081 -20742 15862 -11086 19301 -10492 10468 -6199 19581 11374 16732 -7875 -10449 17581 -14147 10177 -10091 34400 -5126 3048 -4624 -1882 -21040 9651 4757 61983 30575 -14519 -10402 -7272 18171 -10333 18417 -14109 50491 8903 17017 13189 -11722 -11279 -2509 2077 -14107 4028 -1174 32125 22573 29729 -1088 19387 8644 12870 -13750 9079 -8880 29534 -11515 2719 39198 -7059 -3893 -17731 20014 10920 1801 -26369 -1447 -4929 631 12289 18980 3411 11840 8079 1623 -16913 32017 -26625 22021 -4317 7920 -14578 7240 17834 -17709 -2308 7872 -3995 -2034 391 -44581 12358 -6382 20380 -16136 29007 -7776 26084 43 8668 2573 21894 17855 -8395 18682 -7661 10867 2551 18532 -9127 12293 -5947 4934 -5795 7148 7550 -8101 6693 -6907 -777 -16691 443 -13899 2993 1402 30084 -19745 -9655 -10692 6120 18666 -18067 8247 -1997 11063 -24967 20952 9718 -5185 2114 17755 -21065 7913 16562 20859 6134 777 8911 -22726 17525 -23774 12698 -11699 15100 -11072 8951 -6260 15319 9726 13699 -8310 -11312 14234 -15444 8517 -10098 21592 -4709 2579 -4290 -1746 -24308 8340 4328 31576 21138 -15717 -10882 -7475 14712 -11280 15246 -16301 30774 8261 14551 11638 -13116 -12415 -2511 1983 -15913 3811 -1175 23087 17865 21906 -1089 15697 7706 10888 -15135 8011 -9532 22031 -13199 2745 27814 -8027 -4321 -22743 17661 10529 1884 -35982 -1513 -5290 642 11291 16575 SO 20190820T110013.0Z 7171.458484 257 1 32.01 2 87.97 74.01 58.47 298.33 0.00 1 0.00 1 0 22 1.009e-01 9.417e-02 8.054e-02 7.815e-02 1.875514e+04 6.406470e+03 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