File name: Pandora125s1_Cordoba_20190905_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141521.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20190905_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20190905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190905T103238.0Z 7187.439329 425 1 32.01 2 89.72 81.79 129.20 160.79 0.00 1 0.00 1 0 120 3.463e-01 2.372e-01 2.247e-01 1.762e-01 -8.344904e+03 1.063544e+04 2.946623e+03 -6.000000e+00 2.002401e+04 282.34 -2.00 20.00 -2.00 504.96 0.00e+00 5.434330e-02 4.626903e-03 1.793922e-03 -6.000000e+00 1.003123e-02 282.34 -2.00 20.00 -2.00 499.32 0.00e+00 8.548224e+00 3.698378e+00 4.142563e-01 -6.000000e+00 7.186449e+00 227.53 -2.00 3.11 -2.00 500.76 0.00e+00 20.099 0.067 489.00 513.00 1 8.2342e+00 2.8267e-01 5.8958e-02 -6.0000e+00 5.4927e-01 1.8169e-01 7.2195e-02 4.6584e-03 -6.0000e+00 1.4657e-01 7.1269e-06 1.5142e-01 1.0625e-02 6.0643e-04 -6.0000e+00 4.0406e-02 7.8574e-01 -6.6773e-03 12 13 12 11 768 0 86.29 21.46 11.58 0.78574 1.83606 8 2 1 4 0 4000.000 27.05 19.94 21.46 900000 36901 47471 28996 103848 -3597 64910 -17233 3927 7691 69027 -3968 21805 2716 21137 17299 -1952 84718 -12371 14978 -12149 -16631 -33497 52886 -26844 12373 -2168 56531 8047 12351 22638 3083 76799 -16368 94966 -21500 80530 -7630 58426 -7373 24028 1733 -2932 21873 -34170 11876 -8466 26334 -6681 -6536 -1371 2529 -33046 900000 -241 666 -4984 8480 7425 27062 34718 6887 11685 -26301 22860 -9646 -16034 -12307 56044 5024 28855 9838 11003 51012 63207 9812 -7993 88303 -30790 50347 -5686 11705 -23562 53394 -10593 1557 57850 11698 21177 -9805 15427 -27594 6549 -30577 3111 27157 -28284 -22806 44879 -29519 17447 -24199 -23926 -6094 -1278 41939 -285 -1828 -5005 66878 10415 -9680 -7907 32528 35704 24972 59178 37294 39067 2077 20494 -3243 -1950 13296 106070 -696 47517 11204 94655 -19326 24999 16797 12152 39561 -5426 17924 29609 2823 -30586 26927 -21937 58442 -16565 -7739 28378 -27749 52135 22770 12273 900000 34152 37977 26835 43983 -4344 38691 -22978 4189 7842 37897 -4481 18812 2812 18236 15738 -2204 41196 -16107 14802 -15437 -21393 -49392 32354 -36634 11645 -2415 35470 8205 12012 19886 3337 40960 -21182 46180 -32152 49266 -10643 42846 -10495 24876 2218 -3878 22330 -60925 13490 -12051 27264 -9895 -9869 -1991 3564 -67000 900000 -357 977 -7668 11217 9715 28406 32948 8418 13274 -42735 22352 -12899 -22594 -16457 37070 5418 24064 9761 10601 32274 34536 8888 -8390 34283 -38076 26786 -5150 8752 -25072 26871 -10509 1433 31610 10429 17357 -10856 12866 -33727 5368 -34294 2371 15620 -27249 -20004 19360 -26317 9784 -21225 -22018 -4995 -1065 24122 -262 -1761 -5038 32696 8836 -9882 -7845 21516 23103 18313 31484 25204 26403 2061 17092 -3450 -2047 11853 36605 -680 28014 9344 34026 -21675 17973 13043 9785 23892 -5071 13144 19159 2354 -34744 16649 -21449 25210 -15244 -6677 17546 -30723 26238 15388 9176 SO 20190905T103659.0Z 7187.442350 429 1 32.00 2 88.80 81.22 128.89 159.58 0.00 1 0.00 1 0 64 1.579e-01 1.391e-01 1.127e-01 1.050e-01 4.857270e+03 7.795911e+03 1.823399e+03 -6.000000e+00 9.152491e+03 282.34 -2.00 20.00 -2.00 505.32 0.00e+00 2.418828e-02 2.891227e-03 1.406534e-03 -6.000000e+00 4.513582e-03 282.34 -2.00 20.00 -2.00 499.86 0.00e+00 1.038663e+01 2.262276e+00 2.975497e-01 -6.000000e+00 3.204476e+00 227.53 -2.00 3.11 -2.00 501.44 0.00e+00 18.194 0.050 489.00 513.00 1 8.2875e+00 1.7302e-01 4.7144e-02 -6.0000e+00 2.4623e-01 -1.8326e-02 4.2776e-02 3.2111e-03 -6.0000e+00 6.3133e-02 1.2783e-05 3.0615e-02 9.9370e-03 5.3375e-04 -6.0000e+00 1.8406e-02 -2.5763e-02 4.7743e-04 12 9 8 11 8 0 97.98 21.40 4.87 -0.02576 0.18660 8 2 1 4 0 4000.000 26.94 19.96 21.40 25400 21349 25134 28082 3169 24644 16487 17259 -1973 -5662 -4905 12932 -6733 -10624 16407 26238 5040 3521 6244 6568 -14459 -11600 -12435 14613 -3031 15499 156 5622 9276 -14683 4095 2334 -23524 -8590 8982 -5738 22097 -12041 18243 5631 10700 14634 -1920 10916 -7947 -1384 2081 -4535 -6468 -16003 -21579 -14560 -24546 -8869 -7276 -8549 24 -6698 -10298 26037 7249 6347 5557 2043 -6698 272 1482 30684 8686 14581 11609 -16075 8417 3028 -18137 -3392 7953 15968 -4294 3008 12111 -8814 7964 23337 -14692 -3560 1551 42888 5334 44761 -14380 28574 -18321 -11067 19243 -12272 20665 -7353 4377 5641 -14585 -6108 -14315 9638 -28072 3913 20766 3403 -13708 13441 -20149 2722 -3158 -6508 6629 4377 -1143 -11620 11021 2392 -5598 4004 10230 -8348 -6676 4289 25744 17816 30135 -3419 -4294 11506 20747 24282 42766 21334 10150 28128 2757 13987 -3667 -7193 -9040 11876 -12770 1214 -20382 38969 46685 21373 19361 22559 24942 3644 22810 16339 16620 -2250 -6564 -5548 12090 -7616 -12515 14880 21833 5231 3720 6421 6754 -18519 -14641 -16044 14482 -3571 14925 170 5677 8932 -18120 4288 2553 -31048 -9792 9321 -6294 20039 -14241 16260 5839 10821 14549 -2287 11507 -10080 -1625 2319 -5286 -7538 -20298 -29035 -18592 -35552 -11250 -9229 -11064 28 -8554 -13679 24099 8077 7071 6143 2293 -8037 298 1575 23930 8337 13122 10745 -19563 7935 2958 -21451 -3401 7020 12864 -4196 2706 9860 -8763 6621 16400 -14858 -3173 1302 23892 4389 25318 -14912 19346 -19627 -10812 13523 -11464 13460 -6175 3226 4110 -13125 -5077 -12882 6773 -28629 2918 13348 2683 -13275 10253 -22103 2426 -3031 -6526 5851 3938 -1078 -12050 9067 2152 -5517 3637 8855 -8800 -6980 4043 19637 14658 21694 -3399 -4269 9762 16181 18521 27489 17187 9221 21455 2717 12347 -3866 -7829 -9916 10382 -14009 1144 -23931 25716 29208 SO 20190905T104112.0Z 7187.445278 433 1 32.01 2 87.91 80.66 128.57 158.42 0.00 1 0.00 1 0 22 9.180e-02 8.066e-02 6.653e-02 6.474e-02 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