File name: Pandora125s1_Cordoba_20191125_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250324T140021.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v4d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20191125_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20191125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191125T090943.1Z 7268.381748 350 1 32.13 2 89.75 114.39 82.22 99.63 0.00 1 0.00 1 0 50 1.757e-01 1.541e-01 1.417e-01 1.320e-01 -3.648093e+03 8.268226e+03 1.156850e+03 -6.000000e+00 1.033358e+04 285.84 -2.00 20.00 -2.00 505.19 0.00e+00 1.199278e-02 3.802101e-03 7.683343e-04 -6.000000e+00 5.073482e-03 285.84 -2.00 20.00 -2.00 499.85 0.00e+00 5.331827e+00 2.729737e+00 4.157793e-01 -6.000000e+00 3.572757e+00 229.02 -2.00 3.11 -2.00 501.50 0.00e+00 20.050 0.066 489.00 513.00 1 9.9170e+00 2.1209e-01 4.5875e-02 -6.0000e+00 2.7472e-01 1.0818e-01 5.1584e-02 5.7111e-03 -6.0000e+00 7.0641e-02 3.4069e-06 3.5260e-02 1.4384e-02 4.2780e-04 -6.0000e+00 2.0513e-02 -2.6066e-01 2.4687e-03 12 8 8 10 0 0 -205.53 21.02 -1.32 -0.26066 -0.01608 8 2 1 4 0 4000.000 26.73 20.02 21.02 31904 -7886 26990 -4729 -5480 4436 -221 -8903 3303 -17753 2736 16374 -1691 -14213 -4928 11326 38053 28269 7755 8218 1547 6391 1313 -16078 -21146 26840 2336 -4082 -4309 6584 -9268 6345 -694 19700 -2201 -14935 18623 -6316 19951 5857 8374 7200 2275 6559 6137 6191 2732 1538 4508 -3907 -2256 -5690 -22583 -28764 -2322 18927 13273 9152 12543 -1031 12627 -304 17570 -7759 35498 13709 18709 2412 22017 -4627 25350 -4085 15183 44839 -3254 12650 -36976 -1204 -4613 -178 -26423 -3857 5042 -19246 1708 -9498 -4402 -25691 -3336 -23333 43180 -13877 -11182 -474 6457 1432 -6274 10830 8839 24166 4899 22091 7930 25874 -4562 19252 -9117 28791 21053 1775 63899 12361 32984 33984 -8134 -890 -789 2195 1297 -267 -6020 22306 -11163 -510 30205 -3800 -16538 -13062 16461 8780 48505 17343 27363 16218 21334 19262 -9217 9603 -10741 40809 -2826 22570 -24557 -6184 6439 -23451 -9290 2428 900000 26259 -9922 24436 -5950 -6958 5059 -260 -11201 3612 -23589 2927 15210 -1889 -18215 -5853 11586 29978 24597 8297 8794 1783 7064 1529 -22118 -27578 23038 2500 -4608 -4914 6891 -11660 6938 -748 18763 -2372 -18190 17737 -7148 17633 6061 8575 7528 2502 6858 6351 6272 2797 1558 4373 -4127 -2383 -6378 -30669 -42164 -2628 17340 12876 9272 12303 -1155 12249 -331 15718 -8781 25635 12116 15527 2339 17560 -4837 19673 -4227 12765 27548 -3192 10499 -50217 -1142 -4525 -167 -32182 -3741 4456 -21574 1546 -9624 -4270 -31291 -3308 -28671 27459 -15555 -12053 -449 5568 1266 -5883 8521 7145 16931 4172 15715 6410 17291 -4131 13903 -8942 19860 16111 1684 33059 10792 23464 23809 -8591 -863 -757 2034 1216 -256 -6164 17311 -12152 -500 21813 -3850 -18895 -14219 13129 7476 27709 13646 19760 13285 16786 15571 -9934 8591 -11808 26831 -2863 17516 -29909 -6132 5552 -27298 -9513 2251 900000 SO 20191125T091352.0Z 7268.384630 354 1 32.01 2 88.94 113.85 81.37 99.14 0.00 1 0.00 1 0 22 1.092e-01 1.014e-01 7.640e-02 7.357e-02 1.892761e+04 6.193222e+03 1.760279e+03 -6.000000e+00 6.416154e+03 285.84 -2.00 20.00 -2.00 505.38 0.00e+00 7.794296e-05 2.117410e-03 8.025750e-05 -6.000000e+00 3.178323e-03 285.84 -2.00 20.00 -2.00 499.90 0.00e+00 1.484097e+00 1.540703e+00 3.169829e-02 -6.000000e+00 2.231429e+00 229.02 -2.00 3.11 -2.00 501.63 0.00e+00 18.467 0.052 489.00 513.00 1 9.9678e+00 1.1882e-01 2.6534e-02 -6.0000e+00 1.7209e-01 1.1033e-01 2.9148e-02 1.7797e-03 -6.0000e+00 4.4163e-02 6.1692e-06 1.5673e-02 7.4337e-03 1.5782e-04 -6.0000e+00 1.2914e-02 7.3003e-02 -6.3682e-04 12 9 8 11 8 0 99.31 21.06 3.52 0.07300 0.18172 8 2 1 4 0 4000.000 26.73 20.02 21.06 5583 16909 -2537 7469 -6259 -8986 10543 -9076 -1420 -11950 15088 -4306 11531 -8834 6131 2267 -1916 4631 -7020 7990 -4260 22609 -13401 13160 -3872 22649 -12008 -5951 -1453 2934 -3425 -6739 14400 -13540 25510 312 2134 4053 9019 -2102 -14538 3998 3128 -877 -5351 2547 4489 2334 -1439 16122 1478 6976 -10073 900000 -2498 -5413 -8035 -13665 19320 -9495 13552 -2271 14329 -1619 14419 -625 19975 -5059 9909 -5187 1971 2858 2966 2862 -3873 -704 -2906 -4578 -7486 9786 -6754 18821 -7685 22374 5451 739 -5890 5700 13383 19781 36775 -10377 11891 3421 14472 1041 -13900 10977 2685 -16603 26609 -3074 7444 -1036 -2506 13909 -18556 20116 -9248 -2618 294 9569 11732 10798 -10977 -10987 2805 -6181 -5523 -14306 12398 -5449 -11807 -18619 3522 -1642 13085 6371 15709 -7753 -7672 7752 -8909 14000 -7538 11815 -4628 8168 14257 19519 5343 2454 -3113 9678 -1513 -4159 12620 -17415 2201 5377 14954 -2809 7682 -7544 -11302 10981 -11475 -1646 -15187 14430 -4937 11180 -10475 6306 2465 -2222 5127 -8830 8689 -5246 21328 -18172 13707 -4769 21217 -14350 -7135 -1628 3114 -3904 -8123 14433 -16749 23397 335 2229 4487 8666 -2259 -17810 4105 3268 -959 -6106 2661 4528 2355 -1469 13457 1402 6242 -10827 900000 -2610 -5916 -9072 -16330 16591 -10890 12370 -2428 12907 -1691 12642 -627 16074 -5164 8628 -5233 1859 2694 2814 2715 -3884 -672 -2792 -4426 -7418 8168 -6693 14580 -7846 17064 4943 701 -5942 5100 11090 15442 24292 -10906 9783 2958 10776 857 -12938 7844 2080 -15853 17098 -2788 6348 -989 -2453 11526 -21172 15583 -9664 -2578 282 8389 10074 9402 -11997 -12140 2712 -6495 -5672 -15721 10275 -5366 -12407 -21020 3194 -1568 10765 5585 12452 -7682 -7509 6471 -8828 11181 -7605 10004 -4697 7407 12328 16175 5133 2431 -3252 8833 -1526 -4246 10761 -19974 2088 SO 20191125T091758.0Z 7268.387477 358 1 32.01 2 88.14 113.32 80.53 98.65 0.00 1 0.00 1 0 22 5.503e-02 5.479e-02 3.718e-02 3.638e-02 7.133448e+03 2.724324e+03 4.986072e+02 -6.000000e+00 3.231111e+03 285.84 -2.00 20.00 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