File name: Pandora125s1_Cordoba_20200412_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250324T144250.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200412_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200412 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200412T111713.8Z 7407.470299 224 1 49.63 2 81.98 74.24 40.96 271.94 0.00 1 0.00 1 0 25 5.185e-01 2.810e-02 4.764e-01 2.640e-02 6.554205e-01 1.449034e-02 6.565729e-03 -6.000000e+00 2.921688e-01 226.46 -2.00 3.11 -2.00 322.11 0.00e+00 7.790959e-05 8.317499e-03 1.423172e-03 -6.000000e+00 1.328168e-02 286.60 -2.00 20.00 -2.00 321.56 0.00e+00 6.699 0.002 302.00 328.00 3 1.2137e+00 5.8429e-02 7.1498e-02 -6.0000e+00 7.2466e-01 7.0185e-01 7.4057e-02 3.3116e-02 -6.0000e+00 7.8808e-01 -9.8109e-01 5.4875e-02 1.5939e-02 -6.0000e+00 4.6941e-01 3.9644e-01 2.6067e-02 4.5941e-03 -6.0000e+00 2.0151e-01 1.3165e-04 -1.2810e-03 8.0415e-04 6.4173e-05 -6.0000e+00 1.3551e-02 3.6622e-03 0.0000e+00 12 9 9 12 4 4 85.39 999.00 0.61 0.00366 -0.00596 67 13 1 5 0 740.572 26.73 20.01 999.00 -60618 900000 -1142 -102086 -45516 -55215 -115685 -147198 900000 -109126 -60661 -49720 57065 107433 38436 -16754 71545 54794 -6254 -28067 122023 -57845 -1819 -62227 155903 10995 -19703 197324 54982 83727 196989 234313 76176 49067 57333 -49061 -1519 60892 45814 32307 34585 2939 70033 49543 79855 49954 -1127 20986 45462 -17585 83650 68575 67697 35768 16568 36183 39530 53657 29814 9786 -2506 -2109 30708 15225 43514 35073 13727 18745 14100 11 9799 -4008 -10407 -1242 20787 23457 -12272 -11501 8023 -2782 9054 715 4176 -3297 -2925 1361 870 1766 541 -1631 -908 -309 -4910 6294 -12654 -3504 329 -1496 1064 -6449 -1208 4205 -5724 -2354 -927 -2039 -2092 -3188 -3334 236 -83 1640 1200 -1222 1113 -1458 294 -1231 -555 -329 1486 2282 7 19 1930 1766 -808 3598 1227 123 3522 172 -302 -266 -695 867 223 -1088 -88 -474 1374 -290 -1937 -1716 900000 -29 -4892 -1171 -1421 -4620 -8622 900000 -4939 -1669 -1280 1469 2765 989 -585 1841 1410 -230 -1290 3141 -3350 -59 -3832 4013 367 -883 5079 1415 2155 5070 6031 1961 1506 1532 -3497 -69 1688 1769 1695 1986 254 3172 2754 3206 2674 -100 1491 2574 -1937 3768 3971 4283 3337 1972 3647 3942 4603 3101 1237 -356 -319 3746 2436 5600 4788 2227 2916 2590 3 2407 -1186 -3263 -336 4110 4006 -2728 -2622 1642 -750 2552 252 1571 -1418 -1334 636 431 941 292 -873 -451 -142 -2249 2616 -7067 -2075 229 -1222 940 -6255 -1051 3121 -4249 -1681 -706 -1677 -1915 -3159 -3623 279 -110 2298 1711 -1736 1462 -1878 373 -1762 -841 -523 2322 3413 11 27 2621 2321 -1047 4897 1934 224 6821 367 -683 -638 -1799 2338 620 -3114 -250 -1302 3477 -744 -4869 SS 20200412T113337.8Z 7407.481687 229 1 51.54 2 78.64 71.91 44.35 269.78 0.00 1 0.00 1 0 25 9.281e-01 6.270e-02 3.423e-01 2.246e-02 4.902424e-01 1.213781e-02 6.472899e-03 -6.000000e+00 5.366902e-01 226.46 -2.00 3.11 -2.00 321.35 0.00e+00 2.146730e-02 5.640901e-03 1.811392e-03 -6.000000e+00 2.504032e-02 286.60 -2.00 20.00 -2.00 320.67 0.00e+00 4.905 0.001 302.00 328.00 3 2.5990e+00 4.2813e-02 5.3415e-02 -6.0000e+00 1.3406e+00 8.7406e-01 5.3214e-02 3.4510e-02 -6.0000e+00 1.4676e+00 -1.1774e+00 3.9430e-02 2.0503e-02 -6.0000e+00 8.5990e-01 4.8601e-01 1.9491e-02 2.3631e-02 -6.0000e+00 3.6488e-01 1.7528e-04 -1.3089e-03 7.1088e-04 2.9781e-04 -6.0000e+00 2.5317e-02 3.6419e-03 0.0000e+00 12 9 9 12 12 4 99.94 999.00 0.62 0.00364 -0.00619 80 16 1 5 0 620.852 26.83 20.01 999.00 900000 206603 900000 213625 546617 179315 900000 121276 900000 900000 45086 98517 81192 900000 82233 900000 178739 347292 187786 900000 157706 188736 282191 126853 160883 128169 75035 27182 124699 58755 -118141 60419 215577 114651 900000 124300 97989 120684 87595 84573 39333 92713 12691 107247 34000 105629 63961 80987 37890 93401 83484 64381 51457 43203 38152 21962 47773 1332 45801 7861 61246 12155 65710 18477 41999 21212 14096 25626 6475 28053 480 12966 -665 14140 -1398 16112 -17625 13878 7124 3395 5882 -5231 -3818 -5444 -5718 -13845 2854 -8686 -76 -5965 5623 -367 2396 2827 2419 -6753 -2707 -662 -4110 2700 -6578 -391 -5015 2641 -5240 -897 2003 -1344 -1668 -53 -892 -42 -1933 -2259 -889 -4217 1953 -663 1608 -477 2166 1690 2304 -161 1368 4785 -147 3625 1185 2098 993 2796 98 2959 343 -843 -428 -814 249 1295 196 -3604 -2368 900000 5505 900000 4962 11950 4047 900000 3849 900000 900000 2385 2918 3321 900000 5333 900000 5471 7592 5474 900000 5861 4676 6169 4807 4124 4251 4016 2213 3666 3411 -45153 4464 4713 5908 900000 4755 4820 5088 5745 6339 4914 7207 2250 7555 5010 7697 7095 7541 5400 7932 8143 8120 7745 7302 6833 4524 7431 331 6969 1712 8034 2827 9998 4993 9402 5583 3865 6069 1935 7615 189 4653 -269 4663 -514 4426 -6132 3417 2018 1168 2292 -2565 -2003 -3170 -3523 -9864 1815 -6421 -52 -4202 3291 -209 1292 1495 1398 -4914 -2184 -600 -4249 2642 -6656 -353 -4314 2102 -4880 -854 1951 -1443 -1941 -67 -1252 -61 -3018 -3380 -1225 -5702 2486 -911 2314 -745 3335 2691 3529 -244 1961 6370 -197 4751 1764 3460 1796 5227 206 6354 805 -2113 -1093 -2123 644 3218 466 -8398 -5254 SS 20200412T115243.7Z 7407.494950 238 1 49.41 2 74.81 69.08 48.29 267.43 0.00 1 0.00 1 0 25 1.345e-01 7.856e-03 1.349e-01 5.140e-03 4.165148e-01 2.638107e-03 4.283774e-03 -6.000000e+00 7.546176e-02 226.46 -2.00 3.11 -2.00 320.79 0.00e+00 3.685030e-04 1.049005e-03 3.834676e-04 -6.000000e+00 3.401300e-03 286.60 -2.00 20.00 -2.00 320.07 0.00e+00 3.744 0.000 302.00 328.00 3 2.1085e+00 8.4901e-03 4.0659e-02 -6.0000e+00 1.8673e-01 5.1991e-02 1.0642e-02 1.9639e-02 -6.0000e+00 2.0290e-01 -4.7111e-02 9.0822e-03 9.8323e-03 -6.0000e+00 1.2131e-01 8.6842e-03 4.5450e-03 2.8447e-03 -6.0000e+00 5.1956e-02 1.0988e-03 -9.9605e-04 1.5837e-04 3.3003e-05 -6.0000e+00 3.4792e-03 2.4836e-03 0.0000e+00 12 9 1 12 12 4 98.81 999.00 0.35 0.00248 -0.00500 129 26 1 5 0 382.965 26.73 20.01 999.00 -56911 -74338 7727 -9744 -46935 46170 12531 6645 -30475 14544 -16422 -66008 -11370 -26122 -21435 15947 -10348 10274 -24211 16620 -9373 -14392 -1856 -10565 -2412 -3917 -8427 -8297 11029 -26290 4572 -20228 17581 -8440 -5534 -9895 -12602 4149 1753 1738 60 -3422 -2769 2381 -748 1729 -274 2916 -2863 3575 -1597 241 4639 1704 3237 1096 5442 -593 4042 -1117 4358 1616 4590 1983 3406 1845 293 304 1169 1919 865 2202 -2355 1813 -2756 2423 -815 633 -1445 -13 499 -1936 -624 -766 -966 -411 -780 -1130 846 -593 320 229 64 882 802 1042 -554 482 -370 -543 -467 -594 -1776 -24 -629 -881 -1050 -654 -540 385 -354 -16 330 252 340 156 660 -120 596 -178 -126 -607 91 388 754 930 -6 1410 -52 426 776 512 -169 -50 -372 -418 -711 497 211 -214 321 -310 -398 -911 -1729 85 -127 -800 287 113 72 -550 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