File name: Pandora125s1_Cordoba_20200502_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250303T195832.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200502_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200502 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200502T111804.6Z 7427.470887 392 1 49.30 2 84.82 68.09 160.65 211.78 0.00 1 0.00 1 0 17 8.265e-01 1.712e-01 5.616e-01 1.259e-01 6.796493e-01 7.208578e-02 1.172233e-02 -6.000000e+00 4.857462e-01 225.53 -2.00 3.11 -2.00 320.61 0.00e+00 3.455520e-02 1.780598e-02 7.930136e-03 -6.000000e+00 2.397625e-02 285.31 -2.00 20.00 -2.00 319.85 0.00e+00 9.562 0.007 302.00 328.00 3 -1.1575e+00 2.1489e-01 9.7077e-02 -6.0000e+00 1.1995e+00 2.3738e+00 2.4599e-01 3.0127e-02 -6.0000e+00 1.3133e+00 -1.5833e+00 1.2696e-01 1.4615e-02 -6.0000e+00 7.8287e-01 3.4260e-01 6.7997e-02 1.2206e-02 -6.0000e+00 3.3965e-01 4.5202e-05 8.3239e-03 3.7361e-03 1.8879e-04 -6.0000e+00 2.3277e-02 2.5528e-02 0.0000e+00 12 8 8 10 0 0 23.06 21.06 1.78 0.02553 0.08808 21 4 1 5 0 2347.443 26.73 19.98 21.06 -42038 39573 -1043 900000 -25335 134144 16240 -4776 6124 900000 4543 -24790 62202 19247 900000 280556 900000 72877 422073 -32704 900000 -39716 139877 135604 900000 -53234 77692 106303 -60504 121939 14664 900000 -2906 317084 -72579 900000 -17094 900000 8016 900000 156371 260506 8221 146271 900000 9348 900000 11734 900000 -23450 900000 -40802 900000 900000 900000 -34267 23345 93384 5122 181166 -6098 42984 21091 900000 49414 107211 25301 142021 -1560 102882 64690 -41413 52389 -28939 900000 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2676 -2382 13286 -13128 28225 -10931 24626 -21136 24910 4906 9115 10193 15000 17698 3263 2346 -15837 938 -3924 21768 -18995 25032 -15959 27289 -29261 9164 -16352 20542 -5006 13560 -11943 -4740 1549 1735 12047 -44171 22853 -15466 731 -16147 39882 17197 SS 20200502T113136.9Z 7427.480288 395 1 49.84 2 82.17 66.18 161.87 202.86 0.00 1 0.00 1 0 17 4.551e-01 2.265e-02 4.043e-01 1.785e-02 6.787218e-01 9.811820e-03 6.657154e-03 -6.000000e+00 2.551390e-01 225.53 -2.00 3.11 -2.00 322.08 0.00e+00 -1.733752e-04 5.429724e-03 1.301317e-03 -6.000000e+00 1.147808e-02 285.31 -2.00 20.00 -2.00 321.55 0.00e+00 6.840 0.003 302.00 328.00 3 -4.4099e-01 3.8439e-02 7.2856e-02 -6.0000e+00 6.3030e-01 7.3178e-01 5.0188e-02 3.3332e-02 -6.0000e+00 6.8540e-01 -9.5242e-01 4.0685e-02 1.7167e-02 -6.0000e+00 4.0951e-01 3.7930e-01 1.9106e-02 5.2179e-03 -6.0000e+00 1.7681e-01 5.7983e-04 4.6786e-04 5.3249e-04 6.8536e-05 -6.0000e+00 1.1871e-02 2.4545e-02 0.0000e+00 12 8 8 10 0 0 3.42 21.02 0.50 0.02455 0.02806 112 22 1 5 0 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-716 -1874 143 -1245 2055 -636 2165 679 2083 252 2683 2723 2448 1388 2289 1270 2840 1185 1714 2277 3811 3314 1595 4201 1490 3900 528 1873 298 795 4840 3260 2639 557 2479 1325 4891 2100 4313 1071 4708 611 -893 -2031 -752 -1749 -2404 42 905 -1837 655 -194 688 -449 1911 809 67 -1896 -2860 -506 -1073 -3219 -685 -2671 268 -2849 -605 -2277 77 -3394 -2297 365 1116 -2238 -2480 -1867 -4395 2853 -633 -1397 -376 393 -528 -1537 -390 1413 1185 926 1485 2570 4788 1345 1980 1954 1331 -231 1691 -472 3923 1130 2039 633 -3043 1971 -2137 -920 -660 -2290 -1772 SS 20200502T114931.0Z 7427.492720 400 1 50.07 2 78.72 63.56 162.83 189.64 0.00 1 0.00 1 0 25 2.966e-01 7.393e-03 1.322e-01 4.348e-03 5.211956e-01 2.306672e-03 5.238817e-03 -6.000000e+00 1.664374e-01 225.52 -2.00 3.11 -2.00 321.40 0.00e+00 2.660806e-03 1.155265e-03 4.615550e-04 -6.000000e+00 7.487707e-03 285.31 -2.00 20.00 -2.00 320.79 0.00e+00 4.937 0.001 302.00 328.00 3 -5.0144e-01 8.2329e-03 5.3081e-02 -6.0000e+00 4.1105e-01 1.2600e-01 1.1069e-02 2.5140e-02 -6.0000e+00 4.4680e-01 -1.2153e-01 1.0597e-02 1.3261e-02 -6.0000e+00 2.6712e-01 3.5201e-02 5.0518e-03 5.5144e-03 -6.0000e+00 1.1568e-01 4.3994e-03 1.0557e-03 1.3346e-04 6.0711e-05 -6.0000e+00 7.7386e-03 2.4928e-02 0.0000e+00 11 8 0 10 0 0 80.26 21.00 0.31 0.02493 0.03286 358 71 1 5 0 139.841 26.62 19.99 21.00 -108412 -97153 -108889 -99005 -118626 -98841 -122300 -69500 -92340 -62855 -78688 -31197 -60661 -36643 -36404 21028 -8296 12889 -8908 -24967 -17393 -5950 -1712 -27607 7826 -16137 7127 -28146 22770 900000 11960 -14399 511 -9304 -5324 -7968 -12778 9526 3716 5170 -3839 7087 -3765 6822 -694 3294 -1818 -974 -833 369 4428 -1348 7271 1374 2753 4889 6796 -3972 2698 -805 -1484 2630 4276 1608 2677 4267 503 2390 -13 2679 -1192 3216 42 2467 -1429 110 -1217 -1706 718 -2353 279 -2293 -184 -1862 316 -669 1247 -803 1932 379 355 307 -943 594 -633 359 -183 295 -105 382 -1663 61 -353 -150 -1339 -756 -842 -939 -286 102 -195 -175 367 -33 607 -157 456 -44 -55 -434 -535 -65 683 1036 83 570 802 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