File name: Pandora125s1_Cordoba_20200906_L2Fit_fwvt1c5d20170323p1-8.txt File generation date: 20250311T143053.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200906_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200906 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2356 492.3572 492.4787 492.6001 492.7216 492.8431 492.9645 493.0859 493.2073 493.3287 493.4501 493.5714 493.6927 493.8141 493.9354 494.0566 494.1779 494.2992 494.4204 494.5416 494.6628 494.7840 494.9052 495.0263 495.1474 495.2686 495.3897 495.5107 495.6318 495.7529 495.8739 495.9949 496.1159 496.2369 496.3579 496.4788 496.5997 496.7206 496.8415 496.9624 497.0833 497.2041 497.3250 497.4458 497.5666 497.6874 497.8081 497.9289 498.0496 498.1703 498.2910 498.4117 498.5323 498.6530 498.7736 498.8942 499.0148 499.1354 499.2560 499.3765 499.4970 499.6175 499.7380 499.8585 499.9790 500.0994 500.2198 500.3403 500.4606 500.5810 500.7014 500.8217 500.9420 501.0624 501.1826 501.3029 501.4232 501.5434 501.6636 501.7838 501.9040 502.0242 502.1444 502.2645 502.3846 502.5047 502.6248 502.7449 502.8649 502.9850 503.1050 503.2250 503.3450 503.4649 503.5849 503.7048 503.8247 503.9446 504.0645 504.1844 504.3042 504.4241 504.5439 504.6637 504.7835 504.9032 505.0230 505.1427 505.2624 505.3821 505.5018 505.6215 505.7411 505.8607 505.9803 506.0999 506.2195 506.3391 506.4586 506.5781 506.6976 506.8171 506.9366 507.0561 507.1755 507.2949 507.4143 507.5337 507.6531 507.7725 507.8918 508.0111 508.1304 508.2497 508.3690 508.4882 508.6074 508.7267 508.8459 508.9650 509.0842 509.2034 509.3225 509.4416 509.5607 509.6798 509.7988 509.9179 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200906T103827.0Z 7554.443368 228 1 49.97 2 88.02 81.50 63.92 299.75 0.00 1 0.00 1 0 36 1.363e-02 1.344e-02 1.147e-03 1.140e-03 9.468293e+03 7.814786e+01 5.721812e+02 -6.000000e+00 7.899511e+02 282.38 -2.00 20.00 -2.00 505.43 0.00e+00 2.513220e-03 3.250636e-05 1.347454e-04 -6.000000e+00 3.896879e-04 282.38 -2.00 20.00 -2.00 501.21 0.00e+00 7.960629e-01 2.235271e-02 8.704556e-02 -6.000000e+00 2.771392e-01 227.61 -2.00 3.11 -2.00 502.69 0.00e+00 16.125 0.034 489.00 513.00 1 5.7045e+00 1.7170e-03 2.4129e-02 -6.0000e+00 2.1286e-02 -5.4957e-02 4.2554e-04 2.2568e-03 -6.0000e+00 5.4745e-03 6.3988e-04 4.5548e-03 1.2536e-04 7.5575e-05 -6.0000e+00 1.5895e-03 7.7465e-03 -6.7000e-05 12 8 8 10 0 0 98.73 20.77 9.64 0.00775 0.03934 18 4 1 4 0 2775.846 26.41 19.99 20.77 -4033 -2480 -1489 -99 737 1910 1706 1570 1387 309 69 -981 -1226 -1954 -1708 -1222 -328 370 745 831 707 978 960 1210 1126 837 666 -138 -1542 -2050 -2310 -1373 338 1004 891 877 774 173 55 46 487 798 1622 1857 1859 1730 1396 244 -400 -1502 -2129 -2018 -2151 1100 -307 860 944 1466 1598 1707 1644 1784 1751 1259 688 -116 -308 -861 -1194 -1653 -1558 -1302 -605 -875 -1054 -1585 -1964 -2087 -2615 -1980 -1801 -1397 -1303 -992 -777 -611 -748 -308 -399 322 824 1282 1563 1178 557 161 -600 -1897 -2149 -2525 -1961 -954 354 511 -217 -308 -1105 -1086 -369 66 688 1313 2140 2503 2471 2698 2325 2220 1288 796 324 565 777 1231 945 707 858 299 634 -101 -603 -1404 -1531 -1545 -897 -333 107 164 593 702 674 930 550 471 151 -829 -1735 -2369 -2276 -3403 -2116 -1300 -88 667 1743 1581 1462 1287 287 63 -900 -1117 -1785 -1563 -1128 -307 352 717 808 692 958 946 1197 1119 833 657 -135 -1496 -1968 -2226 -1336 333 942 848 836 734 164 52 44 463 767 1568 1812 1825 1698 1363 237 -383 -1424 -1993 -1873 -2017 1022 -298 844 939 1459 1594 1708 1655 1802 1770 1273 692 -117 -306 -849 -1173 -1624 -1534 -1291 -603 -880 -1058 -1581 -1942 -2050 -2575 -1943 -1778 -1387 -1307 -1004 -790 -623 -764 -314 -408 330 849 1327 1610 1200 557 158 -579 -1819 -2044 -2421 -1911 -954 363 504 -218 -310 -1116 -1097 -373 68 709 1359 2218 2606 2598 2857 2484 2369 1373 841 340 590 813 1290 998 751 911 319 674 -107 -638 -1484 -1618 -1647 -966 -364 118 185 675 759 735 1018 605 518 165 -903 -1879 -2561 -2468 SQ 20200906T104206.9Z 7554.445913 232 1 49.71 2 87.25 81.01 64.59 299.10 0.00 1 0.00 1 0 29 1.002e-02 9.891e-03 6.053e-04 6.018e-04 1.023875e+04 4.197300e+01 6.449049e+02 -6.000000e+00 5.805578e+02 282.38 -2.00 20.00 -2.00 505.45 0.00e+00 2.281709e-03 1.701891e-05 1.294740e-04 -6.000000e+00 2.863807e-04 282.38 -2.00 20.00 -2.00 501.17 0.00e+00 8.433351e-01 1.175135e-02 8.637538e-02 -6.000000e+00 2.036625e-01 227.61 -2.00 3.11 -2.00 502.66 0.00e+00 14.139 0.023 489.00 513.00 1 4.8182e+00 8.9839e-04 2.1302e-02 -6.0000e+00 1.5643e-02 -6.9261e-02 2.2434e-04 2.2243e-03 -6.0000e+00 4.0228e-03 2.0357e-03 3.6199e-03 6.5388e-05 7.9238e-05 -6.0000e+00 1.1681e-03 1.6864e-02 -1.1814e-04 12 8 8 10 0 0 93.77 20.77 6.37 0.01686 0.04197 63 13 1 4 0 788.950 26.51 20.00 20.77 -2398 -1594 -623 109 857 1395 1484 1435 1055 562 -80 -532 -983 -1048 -1224 -862 -268 409 535 492 597 665 714 1009 950 611 698 -161 -1079 -1663 -1525 -1054 2 491 687 545 339 26 -274 -30 198 603 929 1264 1250 1270 915 504 -265 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-363 52 612 1102 1547 1857 2065 2222 2085 1508 942 617 308 464 749 885 955 756 560 470 562 23 -631 -992 -1219 -1139 -576 -247 22 414 547 573 535 623 597 480 134 -668 -1375 -1814 -1625 SQ 20200906T104454.0Z 7554.447847 234 1 49.90 2 86.66 80.64 65.11 298.62 0.00 1 0.00 1 0 29 7.772e-03 7.697e-03 4.079e-04 4.064e-04 1.023052e+04 2.813990e+01 6.600862e+02 -6.000000e+00 4.503783e+02 282.38 -2.00 20.00 -2.00 505.41 0.00e+00 1.990384e-03 1.149778e-05 1.177148e-04 -6.000000e+00 2.221402e-04 282.38 -2.00 20.00 -2.00 501.06 0.00e+00 8.344178e-01 7.970815e-03 8.198621e-02 -6.000000e+00 1.579361e-01 227.61 -2.00 3.11 -2.00 502.55 0.00e+00 12.793 0.017 489.00 513.00 1 4.3289e+00 6.0980e-04 1.9320e-02 -6.0000e+00 1.2132e-02 -6.7427e-02 1.5283e-04 2.1224e-03 -6.0000e+00 3.1182e-03 4.0117e-03 2.6587e-03 4.4264e-05 7.8080e-05 -6.0000e+00 9.0610e-04 -6.7985e-04 1.6713e-05 12 8 8 10 0 0 90.83 20.77 4.37 -0.00068 0.01776 96 19 1 4 0 519.718 26.41 20.00 20.77 -1813 -1154 -350 240 702 1277 1296 1157 983 474 50 -311 -631 -855 -891 -671 -234 314 385 430 495 430 580 746 653 489 494 -116 -906 -1243 -1255 -835 -122 411 398 294 269 10 -190 -71 157 340 712 839 957 942 655 263 -263 -858 -1290 -1553 -1336 -662 -149 352 510 557 704 767 1026 969 839 819 370 -17 -168 -453 -779 -872 -804 -689 -441 -225 -491 -1017 -1237 -1248 -1295 -1138 -1021 -1017 -737 -455 -426 -462 -352 -328 -261 0 415 789 823 661 369 2 -407 -827 -1338 -1554 -1377 -751 24 140 -194 -406 -614 -709 -383 59 448 839 1161 1358 1492 1648 1608 1178 780 492 279 292 663 745 628 638 430 390 481 175 -386 -588 -890 -824 -384 -62 85 272 452 491 414 420 460 289 68 -486 -1053 -1256 -1232 -1555 -1009 -313 221 659 1218 1253 1125 953 457 48 -295 -594 -803 -840 -640 -227 293 365 412 476 415 562 726 638 478 479 -111 -856 -1158 -1169 -788 -118 405 398 295 268 10 -188 -70 157 342 723 861 986 970 670 266 -262 -840 -1244 -1488 -1287 -647 -149 359 527 548 694 758 1018 966 837 814 366 -17 -172 -460 -786 -877 -810 -699 -428 -220 -479 -985 -1185 -1251 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