File name: Pandora125s1_Cordoba_20201005_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142920.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20201005_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20201005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201005T102922.1Z 7583.437061 231 1 50.22 2 81.95 90.92 74.10 301.03 0.00 1 0.00 1 0 25 7.237e-01 7.202e-02 5.240e-01 5.892e-02 6.788887e-01 3.305501e-02 7.069808e-03 -6.000000e+00 4.137396e-01 228.40 -2.00 3.11 -2.00 321.91 0.00e+00 -3.544129e-03 1.410705e-02 6.743795e-03 -6.000000e+00 2.126505e-02 283.46 -2.00 20.00 -2.00 321.33 0.00e+00 6.680 0.002 302.00 328.00 3 2.2860e+00 1.1488e-01 8.2301e-02 -6.0000e+00 1.0310e+00 1.1618e+00 1.3382e-01 6.1078e-02 -6.0000e+00 1.1238e+00 -1.3423e+00 7.8981e-02 1.7646e-02 -6.0000e+00 6.6724e-01 4.7564e-01 4.2442e-02 8.4880e-03 -6.0000e+00 2.8542e-01 3.8225e-05 1.8652e-05 1.8169e-03 5.6563e-05 -6.0000e+00 1.8955e-02 7.9413e-03 0.0000e+00 12 8 8 10 0 0 98.21 21.63 1.23 0.00794 0.00808 23 5 1 5 0 2183.226 27.26 20.00 21.63 -68160 900000 -3584 -49833 190318 -15509 173586 -87396 95139 900000 -60882 900000 -51354 -23410 900000 67206 167946 -3326 900000 -64996 58106 900000 900000 76160 900000 261553 900000 4578 1966 -5191 900000 900000 83321 2822 -37853 3467 14872 -2270 107906 407034 102941 200203 37248 113029 193201 -17965 9818 41695 128708 19421 207732 53269 -20876 65851 28594 67502 5632 81709 -21872 130784 -40537 108380 45652 48917 -10443 32155 23474 -22509 -698 5979 49568 51843 95119 17852 66194 -1306 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-3487 4453 3211 3449 8594 4978 241 -4232 -2259 8525 -396 11117 4561 2982 999 -3897 2983 8214 4326 -384 -1987 -10801 -1819 6425 -12956 6323 -8098 9236 -160 SS 20201005T104457.0Z 7583.447882 236 1 50.04 2 78.63 88.88 76.93 298.64 0.00 1 0.00 1 0 25 4.421e-01 1.801e-02 3.204e-01 9.679e-03 5.432835e-01 5.252565e-03 5.461888e-03 -6.000000e+00 2.498560e-01 228.40 -2.00 3.11 -2.00 321.61 0.00e+00 2.551058e-03 2.665480e-03 5.741338e-04 -6.000000e+00 1.159015e-02 283.46 -2.00 20.00 -2.00 321.03 0.00e+00 4.901 0.001 302.00 328.00 3 1.6894e+00 1.9015e-02 5.3658e-02 -6.0000e+00 6.2193e-01 2.3884e-01 2.4974e-02 2.6529e-02 -6.0000e+00 6.7539e-01 -3.7919e-01 2.2466e-02 1.3585e-02 -6.0000e+00 4.0226e-01 1.5560e-01 1.0680e-02 4.2597e-03 -6.0000e+00 1.7182e-01 4.9090e-04 -1.5383e-03 3.0189e-04 5.4206e-05 -6.0000e+00 1.1539e-02 6.6960e-03 0.0000e+00 12 8 8 10 0 0 90.85 21.62 0.49 0.00670 -0.00486 126 25 1 5 0 397.103 27.26 20.01 21.62 -146135 -6600 -35869 -24866 91949 -161901 -112654 -155213 151406 -116255 900000 -112074 144664 -103055 71449 57036 -10029 38171 -4252 15025 18965 102869 -61572 135617 -17620 69888 -28346 67247 -4165 133417 900000 12826 39661 -34518 -4393 -6520 54265 -35159 28594 -5303 32098 19601 15456 -444 22031 19538 -1961 27765 21772 11076 478 28226 3328 28064 1882 18656 -2424 12095 985 3998 228 5794 12608 2998 14295 907 14798 -3982 1203 2398 7994 777 5092 -2267 4874 830 -3522 7064 -2087 3895 -995 2291 -3927 1896 -3118 41 -2889 682 -470 863 1153 -1492 -1253 -2169 2345 -1948 984 -3204 -15 -1680 -224 -1764 -2147 -2318 -388 -568 -3787 -298 -1585 1380 -1868 697 -1210 1986 -1243 1439 -599 1349 265 -346 1728 -662 1314 -971 1945 717 2228 1272 1249 -275 1469 -125 994 -190 -200 -475 -306 675 -799 -164 -389 668 -1239 -4034 -62 -414 -252 868 -5205 -2330 -5407 1429 -3291 900000 -3172 1365 -3852 674 621 -237 596 -108 327 422 971 -2998 1280 -625 1081 -1188 1041 -124 1259 900000 439 1185 -2361 -214 -305 1451 -2654 1383 -432 2120 1568 1344 -46 1835 1683 -211 2233 1894 1109 60 2978 490 3466 319 2760 -455 1966 174 665 42 1083 2470 723 3269 230 3105 -1006 309 701 2471 286 1797 -822 1520 241 -972 1710 -596 1226 -384 1026 -2059 992 -1829 25 -1921 454 -318 560 697 -857 -712 -1239 1400 -1392 785 -3041 -15 -1751 -217 -1570 -1751 -2008 -357 -559 -4044 -327 -1904 1786 -2750 1058 -1870 2853 -1728 1847 -832 1924 408 -567 2793 -1065 2002 -1467 2736 982 2873 1804 1971 -494 2825 -257 2111 -432 -485 -1222 -806 1794 -2166 -426 -961 1541 -2817 SS 20201005T105159.0Z 7583.452766 239 1 50.00 2 77.13 87.95 78.23 297.60 0.00 1 0.00 1 0 25 3.519e-01 1.163e-02 2.233e-01 6.355e-03 4.930295e-01 3.347492e-03 4.955825e-03 -6.000000e+00 1.987389e-01 228.40 -2.00 3.11 -2.00 321.35 0.00e+00 2.793672e-03 1.573576e-03 8.037555e-04 -6.000000e+00 8.779823e-03 283.46 -2.00 20.00 -2.00 320.73 0.00e+00 4.372 0.001 302.00 328.00 3 1.6178e+00 1.1618e-02 4.8293e-02 -6.0000e+00 4.9455e-01 9.5142e-02 1.5203e-02 2.5324e-02 -6.0000e+00 5.3702e-01 -1.5166e-01 1.4092e-02 1.2083e-02 -6.0000e+00 3.1998e-01 5.4805e-02 6.7952e-03 4.5866e-03 -6.0000e+00 1.3597e-01 9.1708e-04 -1.3368e-03 1.9599e-04 4.6255e-05 -6.0000e+00 9.1065e-03 6.4013e-03 0.0000e+00 12 8 8 10 0 0 70.66 21.62 0.45 0.00640 -0.00364 176 35 1 5 0 284.057 27.26 20.00 21.62 17461 -93573 262789 -63436 -99146 -142067 16580 -130310 -34034 -32579 -10762 -95955 -28740 -15979 -62059 71240 -50840 20332 -45840 29837 -17420 26172 -26714 11645 -12333 -6198 -19841 -24172 15 -50132 52838 -5012 20888 -15427 24611 -9266 -2027 -3356 11181 1606 4509 4328 -4012 10274 -4635 16804 -10259 11547 -695 7528 1885 8870 -2140 8367 3496 1324 6525 -4685 5206 -7633 9404 1036 10452 -379 5566 141 7464 561 3248 1948 659 3673 -1140 3538 -2780 1863 -3144 6143 -6774 585 -665 1153 -2903 -670 -323 44 -56 -968 1891 -390 2180 -1577 1992 -1359 2616 -1289 1115 -964 -707 104 -1536 -512 -2254 -148 -375 -412 -1991 -910 -1817 580 -442 231 563 -128 487 -251 789 -547 -1 -637 491 -1066 1461 197 1091 399 823 1048 417 571 506 800 -247 562 -842 206 -481 332 -180 146 45 -635 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