File name: Pandora125s1_Cordoba_20210101_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142925.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210101_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210101T094521.1Z 7671.406494 194 1 50.16 2 84.86 113.87 74.21 310.19 0.00 1 0.00 1 0 33 1.368e-01 1.346e-01 3.664e-03 3.590e-03 1.096261e-01 1.924977e-03 2.997930e-03 -6.000000e+00 7.757186e-02 229.20 -2.00 3.11 -2.00 311.69 0.00e+00 1.532860e-03 9.814998e-05 2.960227e-04 -6.000000e+00 3.476113e-03 287.68 -2.00 20.00 -2.00 311.44 0.00e+00 9.604 0.007 302.00 328.00 3 -5.1100e+00 4.8107e-03 9.1746e-02 -6.0000e+00 1.9312e-01 1.5117e+00 5.2475e-03 1.1880e-02 -6.0000e+00 2.0935e-01 -2.1099e-01 3.1054e-03 4.1415e-03 -6.0000e+00 1.2498e-01 3.6590e-02 1.3230e-03 1.3234e-03 -6.0000e+00 5.3298e-02 9.1648e-03 -1.6048e-03 9.2533e-05 5.2648e-05 -6.0000e+00 3.5410e-03 0.0000e+00 0.0000e+00 12 9 9 12 8 8 36.27 22.37 0.69 0.00000 -0.01206 2305 459 1 5 0 21.664 27.99 20.02 22.37 15050 21906 21404 13760 -2968 -16013 -20158 -13066 -5802 -1941 -7305 -13688 -11699 -3745 5163 10233 11795 9106 9025 9068 9593 6123 3120 2844 5184 6290 4355 -2157 -13943 -22174 -23197 -21001 -18561 -16373 -23928 -32642 -30425 -18863 -3550 10820 19261 20993 22282 21024 19975 17408 14248 7644 2177 -3537 -3122 243 4186 6407 7295 6273 6770 6205 2071 914 1136 5667 11772 16850 15795 6218 -6787 -14509 -14398 -3610 5510 9801 10433 7026 723 -10069 -22994 -33511 -34881 -26847 -16276 -8208 -3030 -167 5818 12460 18077 21167 21043 17854 9575 91 -13178 -20961 -19904 -12454 -4290 4886 10714 9776 2852 -6479 -12872 -10980 -2228 3266 7515 10309 13876 17188 21815 21161 16952 8261 -2706 -10894 -13967 -10077 -3511 4203 8470 7756 4369 769 -5933 -12070 -18926 -21546 -16968 -11296 -8562 -6872 -7250 -4791 1676 5963 8707 10428 11605 9468 6057 1972 -460 11908 17370 17034 11268 -2451 -13114 -16728 -10763 -4841 -1651 -6266 -11652 -9977 -3200 4388 8788 10029 7793 7904 7955 8412 5379 2723 2498 4532 5618 3902 -1919 -12498 -19762 -20919 -18987 -16916 -14897 -21689 -29338 -28073 -17372 -3270 9931 17581 19784 20854 19835 18627 16320 13260 7327 2066 -3372 -2960 231 3953 6213 7073 6099 6538 5938 2001 897 1120 5581 11570 16411 15825 6195 -6752 -14325 -14262 -3560 5588 9909 10485 7062 725 -10063 -23587 -34346 -35450 -27288 -16412 -8522 -3146 -173 5967 12778 18440 22236 22137 18729 10044 94 -13688 -22291 -21102 -13122 -4521 5107 11190 10499 3055 -6959 -13795 -11731 -2360 3586 8160 11211 14919 18555 23195 23420 18532 8988 -2943 -11770 -15129 -11234 -3907 4662 9339 8556 4828 839 -6746 -13731 -21472 -24316 -18958 -12517 -9507 -7861 -8281 -5443 1870 6685 9706 12120 13413 10945 6982 2278 -528 SS 20210101T095541.1Z 7671.413670 197 1 50.11 2 82.84 112.61 75.84 308.49 0.00 1 0.00 1 7 257 1.402e-01 1.403e-01 2.148e-03 2.134e-03 1.079053e-01 1.162606e-03 2.987206e-03 -6.000000e+00 7.949447e-02 229.20 -2.00 3.11 -2.00 311.30 0.00e+00 1.374469e-03 5.590654e-05 2.335082e-04 -6.000000e+00 3.562273e-03 287.68 -2.00 20.00 -2.00 311.14 0.00e+00 7.379 0.003 302.00 328.00 3 -3.8705e+00 2.9005e-03 7.0522e-02 -6.0000e+00 1.9791e-01 1.3454e+00 3.1520e-03 1.0590e-02 -6.0000e+00 2.1454e-01 -1.5152e-01 1.8744e-03 4.0587e-03 -6.0000e+00 1.2808e-01 5.2298e-02 8.0241e-04 1.1232e-03 -6.0000e+00 5.4619e-02 2.1686e-02 -2.1034e-03 5.3906e-05 5.0849e-05 -6.0000e+00 3.6287e-03 0.0000e+00 0.0000e+00 12 11 11 12 8 8 35.51 22.41 0.65 0.00000 -0.01581 4393 874 1 5 0 11.344 27.99 20.00 22.41 13950 20914 20604 13719 -2050 -16431 -20162 -14030 -5485 -1668 -6029 -12974 -11329 -3617 4711 10752 11292 9356 9179 9191 9311 6092 2438 2684 4738 5629 4964 -1817 -12924 -21863 -24074 -21172 -17978 -15769 -23532 -33155 -30904 -19776 -4142 10492 18402 21268 21817 21653 19823 18001 14185 8212 2002 -3217 -3456 800 4224 6017 7513 6553 7065 5722 2516 629 1626 6124 12267 17273 16500 6897 -6337 -14579 -14662 -3944 5141 9986 10656 7251 1587 -9543 -22260 -33031 -35338 -27193 -16835 -8282 -2377 -4 5284 13027 18009 21391 21762 18623 10588 -601 -12967 -21470 -20395 -13330 -4461 5042 11305 10446 3655 -6270 -13379 -11870 -3412 3160 6907 10735 13984 18447 23156 23332 18540 9410 -1744 -11473 -13826 -10823 -3402 4540 8401 7937 4378 -707 -7513 -14051 -21295 -24317 -19420 -12792 -8460 -6827 -5965 -2943 4258 9623 12023 14012 14624 11753 6907 1873 -1904 12050 18091 17871 11909 -1778 -14597 -17996 -12518 -4900 -1492 -5405 -11865 -10374 -3318 4316 9863 10368 8567 8397 8412 8751 5729 2292 2525 4448 5288 4739 -1731 -12318 -20831 -22869 -20456 -17339 -15202 -22692 -31882 -29626 -18954 -4055 10233 17985 20701 21242 21558 19647 17800 14028 8101 1969 -3239 -3472 800 4205 6012 7663 6692 7163 5794 2547 633 1674 6291 12569 17557 16757 6978 -6592 -15074 -15142 -4046 5276 10463 11095 7549 1640 -9870 -22885 -34964 -37228 -28495 -17514 -8555 -2437 -4 5557 13533 18713 22103 22395 19718 11184 -635 -13654 -22452 -21851 -14201 -4708 5250 11705 10741 3867 -6675 -14248 -12591 -3591 3291 7391 11368 14651 19131 23582 23621 19311 9779 -1809 -11947 -14249 -11101 -3569 4725 8713 8204 4532 -732 -7770 -15136 -22886 -25956 -20355 -13118 -8526 -7070 -6062 -2942 4128 9239 11474 13272 14398 11613 6874 1879 -1912 SS 20210101T100542.7Z 7671.420633 200 1 27.35 2 80.86 111.41 77.47 306.88 0.00 1 0.00 1 7 257 1.542e-01 1.531e-01 2.456e-03 2.381e-03 6.981100e-02 1.341310e-03 3.187978e-03 -6.000000e+00 8.746847e-02 229.20 -2.00 3.11 -2.00 310.76 0.00e+00 2.106658e-03 5.872228e-05 1.285096e-04 -6.000000e+00 3.919606e-03 287.68 -2.00 20.00 -2.00 310.72 0.00e+00 5.971 0.002 302.00 328.00 3 -2.8744e+00 3.3445e-03 5.7348e-02 -6.0000e+00 2.1776e-01 1.2112e+00 3.5967e-03 1.1249e-02 -6.0000e+00 2.3606e-01 1.3402e-02 2.1587e-03 4.1843e-03 -6.0000e+00 1.4093e-01 6.8185e-02 9.5299e-04 7.1644e-04 -6.0000e+00 6.0098e-02 3.2380e-02 -1.8870e-03 5.8897e-05 5.2075e-05 -6.0000e+00 3.9927e-03 0.0000e+00 0.0000e+00 12 11 11 12 8 8 31.25 22.36 0.65 0.00000 -0.01418 3499 696 1 5 0 7.751 27.88 19.97 22.36 14243 20490 21182 13299 -1108 -16452 -18882 -13841 -4502 -1868 -5294 -13197 -11138 -3786 3672 10499 10463 8611 7546 8148 8585 6581 1966 3331 4170 5902 4197 -1769 -12353 -21575 -23600 -22142 -18736 -17308 -23541 -34393 -30727 -20145 -4008 10097 18601 20772 22130 22181 20164 18481 15055 9425 2461 -2738 -3658 1134 3171 6624 6623 7196 6618 5611 2864 1069 2656 7056 13766 17714 17672 7020 -5691 -15596 -14283 -4511 6154 10453 11360 8039 1771 -9020 -22621 -33082 -36608 -27454 -17875 -8418 -3059 954 5768 14016 19114 23459 23410 20332 11884 -731 -13622 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