File name: Pandora125s1_Cordoba_20210109_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141425.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210109_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210109T121846.0Z 7679.513033 6 1 50.07 2 54.59 95.85 15.54 33.21 0.00 1 0.00 1 0 17 8.723e-03 5.018e-03 1.583e-03 4.715e-04 1.996619e-01 2.346859e-04 2.121682e-03 -6.000000e+00 4.959783e-03 229.21 -2.00 3.11 -2.00 318.09 0.00e+00 2.261865e-04 3.989082e-05 4.942012e-05 -6.000000e+00 2.226467e-04 288.08 -2.00 20.00 -2.00 317.17 0.00e+00 1.721 0.000 302.00 328.00 3 -5.4396e-01 6.3319e-04 1.8880e-02 -6.0000e+00 1.2347e-02 1.7601e-02 7.1722e-04 9.2641e-03 -6.0000e+00 1.3382e-02 -5.6898e-03 4.3395e-04 4.4944e-03 -6.0000e+00 7.9853e-03 -5.2973e-03 2.1610e-04 1.2982e-03 -6.0000e+00 3.4306e-03 1.4274e-01 1.5011e-03 1.3954e-05 1.4110e-05 -6.0000e+00 2.2773e-04 2.2592e-02 0.0000e+00 10 0 0 10 0 0 17.61 22.11 0.25 0.02259 0.03387 2182 434 1 5 0 22.892 27.67 20.04 22.11 -2814 -103 -1748 -2471 -3814 -1843 63 1249 1105 -445 -625 -1701 -817 -700 467 -1292 -3 -917 534 236 -378 216 506 238 432 727 165 628 -49 1715 891 2514 890 -709 -1120 -1260 -1318 -460 -744 -1174 -940 -1184 -684 -939 -313 -918 -399 -817 -364 338 591 615 1072 602 688 876 501 698 409 1169 944 1487 1399 823 -49 368 -258 482 892 132 293 -77 490 282 486 283 13 119 -2 -709 -855 -1748 -1579 -1000 -839 -446 -330 47 9 392 327 280 589 858 333 387 434 53 -232 -294 -622 -336 369 -273 -818 -676 -652 -457 185 11 59 -52 0 -134 169 356 169 284 -79 -417 -364 -3 64 608 691 407 1174 828 615 558 102 48 131 -205 -227 -178 320 -130 -124 -93 -420 -424 -327 -12 -204 -258 -379 -180 7 148 142 -58 -79 -230 -124 -120 88 -259 -1 -193 114 52 -84 47 114 57 108 184 42 146 -11 376 210 625 238 -184 -271 -318 -380 -158 -303 -536 -450 -585 -341 -467 -154 -448 -187 -391 -170 161 300 330 600 350 406 527 303 414 240 691 594 1009 1016 611 -34 243 -161 308 641 106 249 -67 410 223 347 191 8 74 -2 -559 -705 -1560 -1467 -983 -889 -500 -385 55 10 439 333 257 507 760 325 418 517 69 -298 -355 -737 -373 415 -337 -1084 -934 -884 -646 275 17 94 -79 0 -184 216 477 236 399 -121 -660 -574 -5 100 898 970 541 1528 1146 913 869 164 77 219 -365 -427 -344 631 -261 -245 -178 -773 -818 SS 20210109T122601.0Z 7679.518067 9 1 50.06 2 53.05 95.00 14.75 27.51 0.00 1 0.00 1 0 17 8.347e-03 5.052e-03 1.410e-03 4.458e-04 1.931473e-01 2.220938e-04 2.056546e-03 -6.000000e+00 4.745775e-03 229.21 -2.00 3.11 -2.00 317.96 0.00e+00 1.638100e-04 3.640782e-05 3.740989e-05 -6.000000e+00 2.130446e-04 288.08 -2.00 20.00 -2.00 317.04 0.00e+00 1.659 0.000 302.00 328.00 3 -5.6476e-01 5.9729e-04 1.8220e-02 -6.0000e+00 1.1814e-02 1.7872e-02 6.7601e-04 8.9505e-03 -6.0000e+00 1.2805e-02 -6.4031e-03 4.0541e-04 4.3469e-03 -6.0000e+00 7.6408e-03 -4.6051e-03 2.0033e-04 1.2392e-03 -6.0000e+00 3.2825e-03 1.5636e-01 1.5425e-03 1.3172e-05 1.3590e-05 -6.0000e+00 2.1791e-04 2.2821e-02 0.0000e+00 10 0 0 10 0 0 6.55 22.06 0.26 0.02282 0.03441 2278 453 1 5 0 21.925 27.67 20.00 22.06 -2403 -330 -1674 -2874 -2715 -2304 -840 1684 763 -141 -1282 -783 -613 -31 -105 -710 -295 -294 398 167 102 103 575 133 425 421 449 306 586 1250 1078 2183 1153 -746 -1358 -1272 -1640 -450 -721 -1138 -1189 -960 -1031 -718 -372 -893 -296 -753 -488 309 826 662 1010 459 794 839 762 636 635 982 966 1323 1442 825 -4 303 -333 490 864 210 261 -83 404 384 383 463 -110 289 -5 -816 -859 -1762 -1483 -1007 -817 -486 -332 -24 118 234 378 195 677 801 337 312 505 95 -351 -193 -663 -421 244 -212 -916 -682 -671 -387 199 43 88 -112 24 -80 174 364 178 259 -4 -479 -287 -54 105 628 646 414 1213 859 579 586 17 81 83 -150 -248 -121 294 -151 -166 -102 -432 -388 -300 -42 -210 -339 -286 -242 -96 212 105 -19 -174 -112 -98 -6 -21 -150 -63 -65 90 39 24 24 137 33 111 112 119 75 134 287 264 566 319 -200 -341 -332 -491 -160 -304 -537 -590 -489 -532 -368 -189 -449 -142 -370 -234 151 428 363 579 273 479 515 470 385 379 594 620 917 1067 624 -3 203 -212 317 630 171 225 -73 343 308 277 316 -69 182 -4 -650 -714 -1585 -1387 -997 -872 -550 -390 -28 135 265 387 180 585 714 330 338 603 123 -452 -233 -786 -468 276 -262 -1219 -889 -913 -547 296 67 140 -171 36 -110 222 486 248 364 -7 -757 -450 -82 164 925 906 548 1574 1184 856 907 27 130 137 -265 -464 -232 577 -300 -325 -193 -789 -743 SS 20210109T123203.0Z 7679.522257 12 1 50.07 2 51.77 94.29 14.21 22.36 0.00 1 0.00 1 0 17 7.707e-03 5.021e-03 1.298e-03 4.282e-04 1.884486e-01 2.134845e-04 2.012574e-03 -6.000000e+00 4.381918e-03 229.21 -2.00 3.11 -2.00 317.85 0.00e+00 1.448020e-04 3.395187e-05 3.814405e-05 -6.000000e+00 1.967117e-04 288.08 -2.00 20.00 -2.00 316.93 0.00e+00 1.612 0.000 302.00 328.00 3 -5.8407e-01 5.7285e-04 1.7728e-02 -6.0000e+00 1.0908e-02 2.0692e-02 6.4756e-04 8.7404e-03 -6.0000e+00 1.1823e-02 -6.4546e-03 3.8620e-04 4.2459e-03 -6.0000e+00 7.0550e-03 -5.1465e-03 1.8976e-04 1.2100e-03 -6.0000e+00 3.0308e-03 1.6797e-01 1.5439e-03 1.2645e-05 1.3324e-05 -6.0000e+00 2.0121e-04 2.2874e-02 0.0000e+00 10 0 0 10 0 0 4.94 22.03 0.25 0.02287 0.03448 2373 472 1 5 0 21.041 27.67 20.02 22.03 -2123 -904 -1545 -2251 -2412 -636 117 641 1205 -110 -617 -1019 -835 -280 72 -713 -447 -250 74 311 -141 303 407 53 285 485 448 482 928 1589 1277 2057 1072 -702 -1164 -1333 -1249 -600 -828 -1104 -1194 -967 -960 -771 -352 -830 -561 -748 -496 288 674 613 1074 595 748 927 738 562 633 918 1099 1252 1511 854 -79 288 -348 458 729 238 172 -20 379 381 332 399 -81 270 -43 -727 -854 -1761 -1536 -949 -784 -480 -272 -40 85 177 445 106 729 760 346 304 515 61 -296 -193 -683 -350 188 -175 -930 -612 -739 -412 151 93 93 -36 11 -192 184 351 241 246 -51 -481 -297 -52 88 595 674 428 1150 877 557 567 13 134 101 -148 -293 -108 290 -96 -202 -126 -405 -384 -280 -123 -205 -279 -268 -69 14 86 174 -16 -87 -153 -141 -53 15 -157 -100 -57 17 75 -34 72 101 14 78 134 124 122 219 376 322 551 306 -194 -300 -359 -384 -220 -360 -536 -609 -506 -509 -406 -184 -428 -278 -377 -243 144 358 343 627 361 460 580 464 347 385 566 718 884 1136 655 -57 196 -224 301 539 197 142 -17 325 309 243 260 -52 172 -30 -584 -717 -1598 -1449 -948 -843 -547 -321 -48 98 201 459 99 634 682 341 331 618 79 -382 -234 -765 -390 213 -217 -1169 -799 -1009 -585 225 146 148 -56 17 -264 233 469 314 344 -78 -760 -467 -80 137 876 944 566 1492 1206 821 876 21 214 167 -260 -546 -206 565 -190 -394 -237 -738 -732 SS 20210109T123907.0Z 7679.527165 15 1 50.04 2 50.27 93.45 13.71 15.89 0.00 1 0.00 1 0 17 7.796e-03 5.046e-03 1.201e-03 4.130e-04 1.828141e-01 2.057906e-04 1.954033e-03 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