File name: Pandora179s1_CornwallCT_20221227_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20260624T053626.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20221227_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20221227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221227T154451.9Z 8396.656156 169 1 48.41 2 67.08 162.69 92.75 107.40 0.00 1 0.00 1 0 17 7.721e-02 9.018e-03 2.478e-02 2.772e-03 4.268783e-01 1.376246e-03 5.082708e-03 -6.000000e+00 4.337896e-02 222.81 -2.00 3.52 -2.00 318.76 0.00e+00 1.002595e-03 3.022445e-04 2.723106e-04 -6.000000e+00 1.875089e-03 272.70 -2.00 20.00 -2.00 318.23 0.00e+00 2.548 0.000 302.00 328.00 3 5.0673e+00 3.7102e-03 3.2272e-02 -6.0000e+00 1.0692e-01 6.8204e-02 4.2714e-03 2.1680e-02 -6.0000e+00 1.1677e-01 -6.4478e-03 3.1794e-03 1.0877e-02 -6.0000e+00 6.9433e-02 -6.8150e-03 1.6945e-03 3.2997e-03 -6.0000e+00 2.9332e-02 1.6906e-04 -5.6341e-04 7.8471e-05 3.5873e-05 -6.0000e+00 2.1028e-03 3.6254e-03 0.0000e+00 11 8 0 10 0 0 99.93 22.66 0.22 0.00363 -0.00061 17 4 1 5 0 2847.070 25.90 19.99 22.66 1.85 16.0 908.38 -15236 -17071 -16971 4205 -26117 -31576 -362 -46274 19689 4974 -23497 -28596 -22354 -10250 6578 686 4695 5868 -4313 10194 2316 10720 10428 -1043 1844 5643 -3397 -1823 -4197 -3518 9322 -318 8270 9786 -6164 4829 -7155 -5975 708 1800 -4636 1477 -401 842 -1192 250 -2009 2291 1799 -579 1391 -2028 371 558 1785 3309 -785 -1006 -741 1750 396 1593 1460 2274 340 -2966 919 -227 -141 -216 1754 947 992 -458 -827 -440 1028 -1502 -523 -451 -2942 -1048 -1571 -2739 -59 720 -49 460 -75 -537 1158 -63 766 1375 1359 738 535 598 582 -883 440 -733 -889 -804 -544 27 -86 -1070 -797 67 326 287 81 384 -334 559 -125 -413 418 -514 -18 -622 151 405 127 1286 90 1261 170 479 12 -169 614 -553 -394 185 85 58 -182 229 -100 -542 -230 -444 -590 -629 134 -1021 -1228 -11 -2270 610 194 -1256 -1683 -1432 -703 458 55 395 522 -453 971 246 1045 1041 -125 230 716 -481 -245 -548 -457 1168 -50 1332 1665 -1187 803 -1436 -1376 185 555 -1600 511 -148 312 -453 94 -775 846 672 -227 573 -947 182 293 970 1710 -433 -556 -399 962 211 904 919 1554 245 -2104 593 -147 -97 -159 1401 800 836 -375 -627 -317 664 -962 -353 -348 -2508 -983 -1517 -2815 -63 771 -56 535 -88 -608 1263 -64 719 1340 1344 825 642 764 798 -1221 563 -908 -1021 -935 -680 36 -112 -1492 -1126 102 508 462 128 598 -486 798 -179 -617 628 -819 -28 -975 227 613 184 1754 125 1678 249 729 19 -275 1022 -975 -705 344 163 113 -354 428 -178 -967 -400 SS 20221227T161542.6Z 8396.677577 185 1 12.26 2 65.74 170.27 87.45 112.31 0.00 1 0.00 1 0 17 6.277e-02 7.898e-03 2.752e-02 4.000e-03 4.037933e-01 1.977109e-03 4.840640e-03 -6.000000e+00 3.526674e-02 222.81 -2.00 3.52 -2.00 318.32 0.00e+00 1.036946e-03 3.793558e-04 1.432389e-04 -6.000000e+00 1.524422e-03 272.70 -2.00 20.00 -2.00 317.78 0.00e+00 2.417 0.000 302.00 328.00 3 4.5112e+00 5.2769e-03 3.0516e-02 -6.0000e+00 8.6925e-02 5.7870e-02 6.0133e-03 2.0341e-02 -6.0000e+00 9.4931e-02 -1.5082e-02 4.1445e-03 1.0260e-02 -6.0000e+00 5.6448e-02 6.1471e-05 2.1932e-03 3.0869e-03 -6.0000e+00 2.3846e-02 3.4542e-04 -7.6831e-04 1.1308e-04 3.3451e-05 -6.0000e+00 1.7096e-03 3.6670e-03 0.0000e+00 12 9 1 12 1 1 99.86 22.66 0.29 0.00367 -0.00211 5 6 1 5 0 2015.360 25.90 20.00 22.66 2.78 16.1 913.65 -30202 26230 -21192 19147 -24756 -12977 -18279 -14979 5846 2170 -19342 -19883 -5194 -16344 8256 -7382 8593 243 348 3463 -128 3350 3821 175 -123 6038 -4305 -696 -2474 1490 4530 -618 4114 3653 -5467 79 -4162 -4580 1678 1566 -1047 -732 0 -39 -2088 247 -2909 686 877 977 1359 -657 1462 784 1528 2264 809 -638 106 -323 1733 925 1545 1875 537 -1174 -94 421 -57 1450 715 120 -526 343 100 555 271 -654 -651 -179 -1558 -836 -1629 -2659 -631 -535 -45 -663 256 -281 738 639 -27 1537 1004 212 -145 886 117 -230 418 -1301 -799 -849 -301 -1364 -141 -669 -56 278 180 187 -310 322 124 569 256 281 620 267 -348 -248 -356 292 598 1160 558 1148 222 184 286 -279 -189 -347 -287 33 -270 370 -138 11 -368 -134 -355 -1513 866 -1202 712 -1293 -565 -872 -773 277 116 -1312 -1408 -365 -1540 726 -877 951 31 47 477 -19 474 548 28 -21 1016 -819 -123 -420 242 777 -126 891 851 -1248 18 -963 -1233 513 571 -411 -305 0 -17 -938 109 -1323 299 383 436 644 -347 761 439 888 1344 499 -399 64 -193 1037 600 1035 1368 409 -866 -65 284 -41 1167 605 107 -473 293 83 416 196 -461 -457 -143 -1360 -811 -1634 -2834 -667 -604 -54 -775 311 -332 800 671 -27 1541 1026 232 -180 1162 158 -310 550 -1587 -946 -1019 -369 -1788 -191 -918 -82 416 278 297 -484 492 184 791 355 405 909 413 -548 -382 -530 433 843 1627 752 1563 317 274 453 -443 -309 -594 -501 60 -485 672 -252 20 -645 -232 -604 SS 20221227T162014.9Z 8396.680728 188 1 48.52 2 65.60 171.41 86.68 113.05 0.00 1 0.00 1 0 17 1.644e-01 1.309e-02 5.034e-02 3.876e-03 4.130895e-01 1.921702e-03 4.917342e-03 -6.000000e+00 9.237041e-02 222.81 -2.00 3.52 -2.00 318.76 0.00e+00 4.097190e-04 4.179813e-04 2.877340e-04 -6.000000e+00 3.992496e-03 272.70 -2.00 20.00 -2.00 318.23 0.00e+00 2.405 0.000 302.00 328.00 3 5.7134e+00 5.1831e-03 3.0789e-02 -6.0000e+00 2.2768e-01 1.0072e-01 5.9674e-03 2.0890e-02 -6.0000e+00 2.4862e-01 -2.9111e-02 4.3833e-03 1.0527e-02 -6.0000e+00 1.4784e-01 4.3942e-03 2.3295e-03 3.0955e-03 -6.0000e+00 6.2470e-02 1.0155e-04 -5.1753e-04 1.1069e-04 3.4284e-05 -6.0000e+00 4.4769e-03 2.0960e-03 0.0000e+00 12 8 8 10 0 0 99.88 22.66 0.37 0.00210 -0.00179 15 4 1 5 0 3232.890 25.90 20.01 22.66 2.82 16.1 914.26 -13377 151504 -12450 18303 -11416 -40288 -9148 -56411 3830 28803 -45170 -31345 -31808 -8930 6254 12994 17704 6694 -7031 12769 -7691 14728 24683 -4625 10296 12249 -30 -2887 -1741 -4890 15302 4494 7861 17538 -6978 6317 -10096 -4771 4475 4129 -6832 2011 3983 1496 -1928 -1353 -3729 2847 2545 -778 146 -2399 56 -805 1824 6290 -3192 -1133 -555 1181 763 1592 1893 1301 1339 -5137 2074 -971 999 -767 2007 768 1183 -1222 -2414 -719 960 -1247 -1349 88 -3702 6 -1400 -3912 669 1308 234 847 309 -688 1854 -104 1446 1359 1580 1032 287 549 -93 -65 1033 -955 -1204 -1351 -545 239 -548 -1321 -603 -340 777 -74 -409 516 227 202 -257 -289 266 -242 -61 -416 145 802 -867 2472 -684 1769 546 558 35 -534 52 -712 -520 513 43 128 -30 256 63 -483 -433 -455 1234 -518 549 -416 -1838 -319 -3534 160 1022 -3196 -2006 -2345 -627 449 1007 1429 642 -820 1276 -970 1479 2286 -613 1262 1551 -4 -416 -234 -673 1872 689 1301 2818 -1379 1051 -2113 -1098 1135 1253 -2426 696 1404 551 -734 -514 -1447 1102 991 -320 59 -1091 27 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